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Synthesis, structure, CMC values, thermodynamics of micellization, steady-state photolysis and biological activities of hexadecylamine cobalt(III) dimethyl glyoximato complexes

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Abstract

Metallosurfactant complexes of the type trans- [Co(DH)2(HA)X], where DH = Dimethyl glyoxime, HA = Hexadecyl amine and X = Cl−, Br−, I−, N3 −, NO2 − or SCN−, were synthesized and characterized by physico-chemical and spectroscopic methods. In addition, the single crystal X-ray structure of the ionic complex trans-[Co(DH)2(HA)2][Co(DH)2(I)2)] is presented. The critical micelle concentration values of the complexes in ethanol were obtained by measuring the absorption at 290 nm. Specific conductivity data (at 303–313 K) served for the evaluation of the thermodynamics of micellization \( \left( {\Updelta G^{0}_{{{\text{m}}}}, \Updelta H^{0}_{{{\text{m}}}}, \Updelta S^{0}_{\text{m}} } \right) \). Steady-state photolysis, cyclic voltammetry and biological activities of the complexes were studied. The compounds were tested for antimicrobial activity.

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  1. S. Caleb Noble Chandar

    Present address: P.G and Research Department of Chemistry, Voorhees College, Vellore, 632 001, Tamil Nadu, India

Authors and Affiliations

  1. SAS, Chemistry Division, VIT University, Vellore, 632 014, Tamil Nadu, India

    S. Caleb Noble Chandar & D. Sangeetha

  2. Department of Chemistry, Muthurangam Government Arts College, Vellore, 632 014, Tamil Nadu, India

    Arumugham M.N.

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  1. S. Caleb Noble Chandar
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  2. D. Sangeetha
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  3. Arumugham M.N.
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Correspondence to Arumugham M.N..

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Caleb Noble Chandar, S., Sangeetha, D. & M.N., A. Synthesis, structure, CMC values, thermodynamics of micellization, steady-state photolysis and biological activities of hexadecylamine cobalt(III) dimethyl glyoximato complexes. Transition Met Chem 36, 211–216 (2011). https://doi.org/10.1007/s11243-010-9456-9

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