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Two 2D cobalt(II) coordination frameworks with unusual binodal network topology: synthesis, structures, and catalytic properties

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Abstract

Two coordination polymers, namely {[Co2(L1)2(btec)]∙4H2O}n (1) and [Co(L2)(btec)0.5(H2O)]n (2) [L1 = 1,3-bis(5,6-dimethylbenzimidazole)propane, btec = 1,2,4,5-benzenetetracarboxylate, L2 = 1,2-bis(5,6-dimethylbenzimidazole-1-ylmethyl)benzene], have been synthesized and characterized by physicochemical and spectroscopic methods as well as single-crystal diffraction. The cobalt(II) atoms display different environments with a tetrahedral geometry in 1 and trigonal–bipyramidal geometry in 2. Both complexes show 2D layer structures with a rare binodal (3,4)-connected topology structure, named 3,4L13. Their catalytic activities were tested for the degradation of congo red azo dye in a Fenton-like process.

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Authors and Affiliations

  1. College of Chemical Engineering, Hebei United University, Tangshan, 063009, Hebei, People’s Republic of China

    Jian Chen Geng, Shu Lin Xiao & Guang Hua Cui

  2. Qian’an College, Hebei United University, Tangshan, 063009, Hebei, People’s Republic of China

    Li Wei Liu

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  1. Jian Chen Geng
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  2. Li Wei Liu
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  3. Shu Lin Xiao
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  4. Guang Hua Cui
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Correspondence to Guang Hua Cui.

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Geng, J.C., Liu, L.W., Xiao, S.L. et al. Two 2D cobalt(II) coordination frameworks with unusual binodal network topology: synthesis, structures, and catalytic properties. Transition Met Chem 38, 143–148 (2013). https://doi.org/10.1007/s11243-012-9671-7

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  • DOI: https://doi.org/10.1007/s11243-012-9671-7

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