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Synthesis and structures of two three-dimensional hybrid materials based on vanadium polyoxoanions and macrocyclic metal complexes

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Abstract

The reactions of transition metal macrocyclic complexes [ML](ClO4)2 (L = 1,8-diethyl-1,3,6,8,10,13-hexaazacyclotetradecane, M=Ni, Cu) with NH4VO3 gave two coordination polymers, formulated as [NiL]3[VO3]6·0.5H2O (1) and [CuL]3[VO3]6·2H2O (2). Single-crystal X-ray diffraction analyses indicated that the central Ni(II)/Cu(II) atom achieves a distorted six-coordinate octahedral coordination geometry by the coordination of four nitrogen atoms from L, plus two oxygen atoms from [VO4] tetrahedra. Six [VO4] tetrahedra form a hexanuclear [V6O18]6− ring by sharing six μ2-oxygen atoms. The [NiL]2+ and [CuL]2+ moieties bridge the [V6O18]6− rings to form three-dimensional frameworks with one-dimensional hexagonal channels.

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Acknowledgements

This work was financially supported by the NSFC (51772091).

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Authors and Affiliations

  1. Department of Biology and Chemistry, Hunan University of Science and Engineering, Yongzhou, 425199, Hunan, China

    Jia-Qi Kuang, Jia-Qing Zhuang, Jing Zhou, Xiao-Ling Wang & Guang-Chuan Ou

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  1. Jia-Qi Kuang
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  2. Jia-Qing Zhuang
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  3. Jing Zhou
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  4. Xiao-Ling Wang
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  5. Guang-Chuan Ou
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Correspondence to Guang-Chuan Ou.

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Kuang, JQ., Zhuang, JQ., Zhou, J. et al. Synthesis and structures of two three-dimensional hybrid materials based on vanadium polyoxoanions and macrocyclic metal complexes. Transit Met Chem 44, 263–268 (2019). https://doi.org/10.1007/s11243-018-0290-9

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