Skip to main content
Log in

Effects of Different Moisture Contents on Physical Properties of PVA-Gelatin Films

  • ORIGINAL ARTICLE
  • Published:
Food Biophysics Aims and scope Submit manuscript

Abstract

In this work, it was investigated the effect of different moisture contents on PVA-gelatin films by means of dielectric properties, infrared spectroscopy, microwave response and gravimetric method. The films were elaborated from a blend of gelatin and PVA, with 0 and 25 % glycerol. The sorption isotherms were determined by gravimetric methods, at 25 °C. A capacimeter was used for dielectric measurements, and a device called SOLFAN setup was used for microwave measurements. The sorption isotherms were markedly affected by the glycerol content and relative humidity, due to the hygroscopic nature of the films. The dielectric constant and the microwave response signal were also strongly affected by the moisture and glycerol content in the films. Finally, Infrared spectra showed some changes in the amide peak positions, attributed to the modifications in the interactions between the macromolecules. The behaviors obtained in this work were explained on the basis the way the water enters in the film matrix.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. N. Gontard, S. Guilbert, Bio-packaging: technology and properties of edible and/or biodegradable material of agricultural origin. Boletim da SBCTA 30(1), 3–15 (1996)

    Google Scholar 

  2. P.J.A. Sobral, F.C. Menegalli, M.D. Hubinguer, M.A. Roques, Mechanical, water vapor barrier and thermal properties of gelatin based edible films. Food Hydrocolloids 15(4–6), 423–432 (2001)

    Article  CAS  Google Scholar 

  3. S. Rawdkuen, S. Sai-Ut, S. Benjakul, Properties of gelatin films from giant catfish skin and bovine bone: a comparative study. Eur. Food Res. Technol. 231(6), 907–916 (2010)

    Article  CAS  Google Scholar 

  4. J.G. Estaca, A.L. Lacey, M.E.L. Caballero, M.C.G. Guillen, P. Montero, Biodegradable gelatin–chitosan films incorporated with essential oils as antimicrobial agents for fish preservation. Food Microbiol. 27(7), 889–896 (2010)

    Article  Google Scholar 

  5. P. Bergo, W.M. Pontuschka, J.M. Prison, Dielectric properties and physical features of phosphate glasses containing iron oxide. Mater. Chem. Phys. 108(1), 142–146 (2008)

    Article  CAS  Google Scholar 

  6. M. Roussenova, J.P. Enrione, D. Calderon, A.J. Taylor, J. Ubbink, M.A. Alam, A nanostructural investigation of glassy gelatin oligomers: molecular organization and interactions with low molecular weight diluents. New J. Phys. 14, 1–18 (2012)

    Article  Google Scholar 

  7. I.C. Moraes, G.G.D. Silva, R.A. Carvalho, A.M.Q.B. Habitante, P. Bergo, P.J.A. Sobral, Influence of the degree of hydrolysis of poly(vinyl alcohol) on the physical properties of films based on blends of gelatin and poly(vinyl alcohol) plasticized with glycerol. Cienc. Tecnol. Aliment. 28(3), 738–745 (2008)

    Article  Google Scholar 

  8. P. Bergo, P.J.A. Sobral, Effects of plasticizer on physical properties of pigskin gelatin films. Food Hydrocolloids 21, 1285–1289 (2007)

    Article  CAS  Google Scholar 

  9. P. Bergo, P.J.A. Sobral, Microwave transmittance in gelatin-based films. Meas. Sci. Technol. 17, 1–4 (2006)

    Article  Google Scholar 

  10. S. Iwamoto, H. Kumagai, Y. Hayashi, O. Miyawaki, Conductance and relaxations of gelatin films in glassy and rubbery states. Int. J. Biol. Macromol. 26(5), 345–351 (1999)

    Article  CAS  Google Scholar 

  11. S. Sudo, Dielectric properties of the free water in hydroxypropyl cellulose. J. Phys. Chem. B 115(1), 2–6 (2011)

    Article  CAS  Google Scholar 

  12. S. Clerjon, J.D. Daudin, L.L. Damez, Water activity and dielectric properties of gels in the frequency range 200 MHz-6GHz. Food Chem. 82(1), 87–97 (2003)

    Article  CAS  Google Scholar 

  13. Y. Hayashi, N. Shinyashiki, S. Yagihara, Dynamical structure of water around biopolymers investigated by microwave dielectric measurements using time domain reflectometer method. J. Non-Cryst. Solids 305(1–3), 328–332 (2002)

    Article  CAS  Google Scholar 

  14. M.S. Venkatesh, G.S.V. Raghavan, An overview of microwave processing and dielectric properties of agri-foods materials. Biosyst. Eng. 88(1), 1–18 (2004)

    Article  Google Scholar 

  15. I. Yakimets, N. Wellner, A.C. Smith, R.H. Wilson, I. Farhat, J. Mitchell, Mechanical properties with respect to water content of gelatin films in glassy state. Polymer 46, 12577–12585 (2005)

    Article  CAS  Google Scholar 

  16. V.E. Khutorsky, S.B. Lang, Very strong influence of moisture on pyroelectric and dielectric properties of triglycine sulfate-gelatin films. J. Appl. Phys. 82(3), 1288–1292 (1997)

    Article  Google Scholar 

  17. R.A. Carvalho, C.R.F. Grosso, P.J.A. Sobral, Effects of chemical treatment on the mechanical properties, water vapour permeability and sorption isotherms of gelatin-based films. Packag. Technol. Sci. 21, 165–169 (2008)

    Article  CAS  Google Scholar 

  18. T.M.C. Maria, R.A. Carvalho, P.J.A. Sobral, A.M.B.Q. Habitante, J.S. Feria, The effect of the degree of hydrolysis of the PVA and the plasticizer concentration on the color, opacity, and thermal and mechanical properties of films based on PVA and gelatin blends. J. Food Eng. 87(2), 191–199 (2008)

    Article  CAS  Google Scholar 

  19. H. Mansur, A.N. Sadahira, A.N. Souza, A.P.A. Mansur, FTIR spectroscopy characterizations of poly (vinyl alcohol) hydrogel with different hydrolysis degree and chemically crosslinked with glutaraldehyde. Mater. Sci. Eng. C 28, 539–548 (2008)

    Article  CAS  Google Scholar 

  20. D.A. Prystupa, A.M. Donald, Infrared study of gelatin conformations in the gel and sol states. Polimers Gels Netw. 4, 87–110 (1996)

    Article  CAS  Google Scholar 

  21. V. Renugopalakrishnan, G. Chandrakasan, S. Moore, T.B. Hutson, C.V. Berney, R.S. Bhatvagar, Bound water in collagen. Evidence from Fourier transform infrared and Fourier transform infrared Photoacoustic spectroscopic study. Macromolecules 22, 4121–4124 (1989)

    Article  CAS  Google Scholar 

  22. A. Sionkowska, M. Wisniewski, J. Skopinska, C.J. Kennedy, T.J. Wess, Molecular interactions in collagen and chitosan blends. Biomaterials 25, 795–801 (2004)

    Article  CAS  Google Scholar 

Download references

Acknowledgments

To FAPESP for the fellowship of Bergo, P. (05/54688-7).

Declaration of Conflict Interest

The authors declare that they have no conflict of interest.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to P. Bergo.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Bergo, P., Moraes, I.C.F. & Sobral, P.J.A. Effects of Different Moisture Contents on Physical Properties of PVA-Gelatin Films. Food Biophysics 7, 354–361 (2012). https://doi.org/10.1007/s11483-012-9273-0

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11483-012-9273-0

Keywords

Navigation