Abstract
Lithium bis(oxalato)borate (LiBOB) salt-based nanocomposite gel polymer blend electrolyte (PVdF/PVC) membranes have been prepared by solution casting technique for various concentrations of TiO2. The effect of anatase structure of nanosized titanium dioxide in the plasticized PVC/PVdF + LiBOB matrix has been observed in the 2:1 salt filler ratio in the impedance measurements that the conductivity is increased one order of magnitude higher than the filler-free electrolyte (1:0 salt:filler ratio). The phase morphology of this electrolyte membrane represents the appearance of the free volume sites for ionic migration.
References
Balakrishnan PG, Ramesh R, Prem Kumar T (2006) J Power Sources 155:401
Gnanaraj JS, Levi MD, Gofer Y, Aurbach D, Schmidt M (2003) J Electrochem Soc 150:A445
Xu K (2004) Chem Rev 104:4303
Xu W, Angell CA (2003) Science 302:422
Meyer WH (1998) Adv Mater 10:439
Song JY, Wang YY, Wan CC (1999) J Power Sources 77:183
Scrosati B (2003) Chem Rec 1:171
Zhou J, Fedkiw P (2004) Solid State Ionics 166:275
Florjañczyk Z, Marcinek M, Wieczorek W, Langwald N (2004) Polish J Chem 78:1279
Manuel Stephan A (2006) Eur Polym J 42:21
Manuel Stephan A, Nahm KS (2006) Polymer 47:5952
Lischka U, Wietelmann U, Wegner M (1999) Ger Pat DE 19829030, C1
Xu W, Angell CA (2001) Electrochem Solid-State Lett 4:E1
Yu BT, Qiu WH, Li FS, Xu GX (2005) CN 200510011555.7
Yu BT, Qiu WH, Li FS, Xu GX (2006) Electrochem Solid-State Lett 9:A1
Holomb R, Xu W, Markusson H, Johansson P, Jacobsson P (2006) J Phys Chem A 110:11467
Jiang J, Dahn JR (2003) Electrochem Solid-State Lett 6:A180
Xu K, Lee U, Zhang S, Wood M, Jow TR (2003) Electrochem Solid-State Lett 6:A144
Zhang SS (2006) Electrochem Commun 9:1423
Wang H, Huang H, Wunder SL (2000) J Electrochem Soc 147:2853
Kim HS, Kum KS, Cho WI, Cho BW, Rhee HW (2003) J Power Sources 124:221
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Aravindan, V., Vickraman, P. A study on LiBOB-based nanocomposite gel polymer electrolytes (NCGPE) for Lithium-ion batteries. Ionics 13, 277–280 (2007). https://doi.org/10.1007/s11581-007-0106-y
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11581-007-0106-y