Abstract
Composite nanofibrous membranes based on poly (vinyl chloride) (PVC)–poly (methyl methacrylate) (PMMA) were prepared by electrospinning and then they were soaked in liquid electrolyte to form polymer electrolytes (PEs). The introduction of PMMA into the PVC matrix enhanced the compatibility between the polymer matrix and the liquid electrolyte. The composite nanofibrous membranes prepared by electrospinning involved a fully interconnected pore structure facilitating high electrolyte uptake and easy transport of ions. The ion conductivity of the PEs increased with the increase in PMMA content in the blend and the ion conductivity of the polymer electrolyte based on PVC–PMMA (5:5, w/w) blend was 1.36 × 10−3 S cm−1 at 25 °C. The polymer electrolyte based on PVC–PMMA (5:5, w/w) blend presented good electrochemical stability up to 5.0 V (vs. Li/Li+) and good interfacial stability with the lithium electrode. The promising results showed that nanofibrous PEs based on PVC–PMMA were of great potential application in polymer lithium-ion batteries.
Similar content being viewed by others
References
Tarascon JM, Armand M (2001) Nature 414:359–367
Stephan AM, Nahm KS (2006) Polymer 47:5952–5964
Rajendran S, Mahendran O, Kannan R (2002) Fuel 81:1077–1081
Ahmad Z, Al-Awadi NA, Al-Sagheer F (2007) Polym Degrad Stabil 92:1025–1033
Ramesh S, Winie T, Arof AK (2007) Eur Polym J 43:1963–1968
Rajendran S, Babu RS, Sivakumar P (2008) J Membr Sci 315:67–73
Vickraman P, Aravindan V, Selvambikai M, Shankarasubramanian N (2009) Ionics 15:433–437
Cazzanelli E, Mariotto G, Appetecchi GB, Croce F, Scrosati B (1995) Electrochim Acta 140:2379–2382
Nicotera I, Coppola L, Oliviero C, Castriota M, Cazzanelli E (2006) Solid State Ion 177:581–588
Ding YH, Zhang P, Long ZL, Jiang Y, Xu F, Di W (2009) J Membr Sci 329:56–59
Yee WA, Nguyen AC, Lee PS, Kotaki M, Liu Y, Tan BT, Mhaisalkar S, Lu XH (2008) Polymer 49:4196–4203
Li X, Cheruvally G, Kim JK, Choi JW, Ahn JH, Kim KW, Ahn HJ (2007) J Power Sources 167:491–498
Bansal D, Meyer B, Salomon M (2008) J Power Sources 178:848–851
Kim JK, Manuel J, Chauhan GS, Ahn JH, Ryu HS (2010) Electrochim Acta 55:1366–1372
Raghavan P, Zhao XH, Kim JK, Manuel J, Chauhan GS, Ahn JH, Nah C (2008) Electrochim Acta 54:228–234
Xiao QZ, Li ZH, Gao DS, Zhang HL (2009) J Membr Sci 326:260–264
Thirunakaran R, Renganathan NG, Sundaram V, Pitchumani S, Muniyandi N, Gangadharan R, Ramamoorthy P (1999) J Power Sources 81:752–758
Ramesh S, Liew CW, Morris E, Durairaj R (2010) Thermochimi Acta 511:140–146
Frenot A, Chronakis IS (2003) Curr Opin Colloid Interface Sci 8:64–75
Manesh KM, Santhosh P, Gopalan A, Lee KP (2007) Anal Biochem 360:189–195
Dong H, Nyame V, MacDiarmid AG, Jones WE (2004) J Polym Sci B: Polym Phys 42:3934–3942
Kim JR, Choi SW, Jo SM, Lee WS, Kim BC (2004) Electrochim Acta 50:69–75
Raghavan P, Zhao XH, Manuel J, Chauhan GS, Ahn JH, Ryub HS, Ahn HJ, Kim KW, Nah C (2010) Electrochim Acta 55:1347–1354
Cao JH, Zhu BK, Xu YY (2006) J Membr Sci 266:446–453
Cui ZY, Xu YY, Zhu LP, Wang JY, Xi ZY, Zhu BK (2008) J Membr Sci 325:957–963
Gopalan AI, Santhosh P, Manesh KM, Nho JH, Kim SH, Hwang CG, Lee KP (2008) J Membr Sci 325:683–690
Acknowledgement
This work was financially supported by the Key Laboratory of Environmentally Friendly Chemistry and Applications of Ministry of Education item (Grant No. 09B101).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Zhong, Z., Cao, Q., Wang, X. et al. PVC–PMMA composite electrospun membranes as polymer electrolytes for polymer lithium-ion batteries. Ionics 18, 47–53 (2012). https://doi.org/10.1007/s11581-011-0615-6
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11581-011-0615-6