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Electrochemical and thermodynamic studies to evaluate the inhibition effect of synthesized piperidine derivatives on the corrosion of mild steel in acidic medium

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Abstract

The inhibition ability of three newly synthesized piperidine sulphonamides toward the mild steel (MS) corrosion was investigated using mass loss and electrochemical techniques. The adsorption of all the piperidine sulphonamides on MS complies with the Langmuir isotherm model in all studied temperatures. Associated activation and adsorption thermodynamic parameters were computed and discussed. The polarization results indicated that all the studied inhibitors act as mixed type of corrosion inhibitors. The protective layer of organic compounds on MS surface was confirmed by scanning electron microscopy (SEM). The values of free energy of adsorption (ΔG ads) revealed that the inhibitors adsorbed on the MS surface via both chemisorption and physisorption mechanisms. The relationship between inhibition efficiency and molecular structures of inhibitors was discussed using quantum chemical parameters. The inhibition efficiencies obtained from mass loss and electrochemical measurements were in good agreement.

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References

  1. Vinod Kumar KP, Sankara Narayanan Pillai M (2011) Green corrosion inhibitor from seed extract of areca catechu for mild steel in hydrochloric acid medium. J Mater Sci 46:5208–5215

    Article  CAS  Google Scholar 

  2. Wang H, Fan H, Zheng J (2002) Corrosion inhibition of mild steel in hydrochloric acid solution by a mercapto-triazole compound. Mater Chem Phys 77:655–661

    Article  Google Scholar 

  3. Scattergood GL (1992) Corrosion inhibitors for crude oil refineries, corrosion, ASM handbook, 13. Macmillan, New York, p 1

    Google Scholar 

  4. Bentiss F, Traisnel M, Gengembre L, Lagrenee M (2000) Inhibition of acidic corrosion of mild steel by 3,5-diphenyl-4H-1,2,4-triazole. Appl Surf Sci 161:194–202

    Article  CAS  Google Scholar 

  5. Cruz J, Martinez R, Genesca J, Garcia-Ochoa E (2004) Experimental and theoretical study of 1-(2-ethylamino)-2-methylimidazoline as an inhibitor of carbon steel corrosion in acid media. J Electroanal Chem 566:111–121

    Article  CAS  Google Scholar 

  6. Abdennaby AMS, Abdulhady AI, Abu-Oribi ST, Saricimen H (1996) The inhibition action of 1(benzyl) 1-H-4,5-dibenzoyl-1,2,3-triazole on mild steel in hydrochloric acid media. Corros Sci 38:1791–1800

    Article  Google Scholar 

  7. Quraishi MA, Sharma HK (2002) 4-amino-3-butyl-5-mercapto-1,2,4-triazole: a new corrosion inhibitor for mild steel in sulphuric acid. Mater Chem Phys 78:18–21

    Article  CAS  Google Scholar 

  8. Garcia-Ochoa E, Genesca J (2004) Understanding the inhibiting properties of 3-amino-1,2,4-triazole from fractal analysis. Surf Coat Technol 184:322–330

    Article  CAS  Google Scholar 

  9. Li WH, He Q, Zhang ST, Pei CL, Hou BR (2008) Some new triazole derivatives as inhibitors for mild steel corrosion in acidic medium. J Appl Electrochem 38:289–295

    Article  CAS  Google Scholar 

  10. Chetouani A, Hammouti B, Benhadda T, Daoudi M (2005) Inhibitive action of bipyrazolic type organic compounds towards corrosion of pure iron in acidic media. Appl Surf Sci 249:375–385

    Article  CAS  Google Scholar 

  11. Moretti G, Quartarone G, Tassan A, Zingales A (1996) 5-amino- and 5-chloro-indole as mild steel corrosion inhibitors in 1 N sulphuric acid. Electrochim Acta 41:1971–1980

    Article  CAS  Google Scholar 

  12. Mahmoud SS, El Mahdy GA (1997) Role of imidazoline derivatives in corrosion inhibition of pure aluminum in hydrochloric acid solution. Corrosion 53:437–439

    Article  CAS  Google Scholar 

  13. Khaled KF, Babic-Samardzija K, Hackerman N (2004) Piperidines as corrosion inhibitors for iron in hydrochloric acid. J Appl Electrochem 34:697–704

    Article  CAS  Google Scholar 

  14. Xavier JR, Nallaiyan R (2012) Corrosion inhibitive properties and electrochemical adsorption behaviour of some piperidine derivatives on brass in natural sea water. J Solid State Electrochem 16:391–402

    Article  CAS  Google Scholar 

  15. Senthilkumar AN, Tharini K, Sethuraman MG (2011) Studies on a few substituted piperidin-4-one oximes as corrosion inhibitor for mild steel in HCl. J Mater Eng Perform 20:969–977

    Article  CAS  Google Scholar 

  16. Harish KP, Mohana KN, Mallesha L, Prasanna Kumar BN (2013) Synthesis of novel 1-[5-(4-methoxy-phenyl)-[1,3,4]oxadiazol-2-yl]-piperazine derivatives and evaluation of their in vivo anticonvulsant activity. Eur J Med Chem 65:276–283

    Article  CAS  Google Scholar 

  17. Behpour M, Ghoreishi SM, Soltani N, Salavati-Niasari M (2009) The inhibitive effect of some bis-N,S-bidentate Schiff bases on corrosion behaviour of 304 stainless steel in hydrochloric acid solution. Corros Sci 51:1073–1082

    Article  CAS  Google Scholar 

  18. Quartarone G, Battilana M, Bonaldo L, Tortato T (2008) Investigation of the inhibition effect of indole-3-carboxylic acid on the copper corrosion in 0.5 M H2SO4. Corros Sci 50:3467–3474

    Article  CAS  Google Scholar 

  19. Khaled KF (2008) Adsorption and inhibitive properties of a new synthesized guanidine derivative on corrosion of copper in 0.5 M H2SO4. Appl Surf Sci 255:1811–1818

    Article  CAS  Google Scholar 

  20. Solmaz R, Kardas G, Ulha MC, Yazıcı B, Erbil M (2008) Investigation of adsorption and inhibitive effect of 2-mercaptothiazoline on corrosion of mild steel in hydrochloric acid media. Electrochim Acta 53:5941–5952

    Article  CAS  Google Scholar 

  21. Emregul KC, Duzgun E, Atakol O (2006) The application of some polydentate Schiff base compounds containing aminic nitrogens as corrosion inhibitors for mild steel in acidic media. Corros Sci 48:3243–3260

    Article  Google Scholar 

  22. Kedam M, Mattos OR, Takenouti H (1981) Reaction model for iron dissolution studied by electrode impedance I. Experimental results and reaction model. J Electrochem Soc 128:257–266

    Article  Google Scholar 

  23. Yadav DK, Maiti B, Quraishi MA (2010) Electrochemical and quantum chemical studies of 3,4-dihydropyrimidin-2 (1H)-ones as corrosion inhibitors for mild steel in hydrochloric acid solution. Corros Sci 52:3586–3598

    Article  CAS  Google Scholar 

  24. Bostan R, Varvara S, Gaina L, Muresan LM (2012) Evaluation of some phenothiazine derivatives as corrosion inhibitors for bronze in weakly acidic solution. Corros Sci 63:275–286

    Article  CAS  Google Scholar 

  25. Li W, He Q, Zhang S, Pei C, Hou B (2008) Some new triazole derivatives as inhibitors for mild steel corrosion in acidic medium. J Appl Electrochem 38:289–295

    Article  CAS  Google Scholar 

  26. Ashassi-Sorkhabi H, Shaabani B, Seifzadeh D (2005) Corrosion inhibition of mild steel by some Schiff base compounds in hydrochloric acid. Appl Surf Sci 239:154–164

    Article  CAS  Google Scholar 

  27. Musa AY, Kadhum AAH, Mohamad AB, Razak Daud A, Takriff MS, Kamarudin SK (2009) A comparative study of the corrosion inhibition of mild steel in sulphuric acid by 4,4-dimethyloxazolidine-2-thione. Corros Sci 51:2393–2399

    Article  CAS  Google Scholar 

  28. Musa AY, Mohamad AB, Kadhum AAH, Takriff MS, Tien LT (2011) Synergistic effect of potassium iodide with phthalazone on the corrosion inhibition of mild steel in 1.0 M HCl. Corros Sci 53:3672–3677

    Article  CAS  Google Scholar 

  29. Obi-Egbedi NO, Obot IB, Eseola AO (2010) Synthesis, characterization and corrosion inhibition efficiency of 2-(6-methylpyridin-2-yl)-1H-imidazo[4,5-f][1,10] phenanthroline on mild steel in sulphuric acid. Arab J Chem. doi:10.1016/j.arabjc.2010.10.025

    Google Scholar 

  30. Amin MA (2006) Weight loss, polarization, electrochemical impedance spectroscopy, SEM and EDX studies of the corrosion inhibition of copper in aerated NaCl solutions. J Appl Electrochem 36:215–226

    Article  CAS  Google Scholar 

  31. Fouda AS, Ellithy AS (2009) Inhibition effect of 4-phenylthiazole derivatives on corrosion of 304L stainless steel in HCl solution. Corros Sci 51:868–875

    Article  CAS  Google Scholar 

  32. Fragoza-Mar L, Xometl OO, Dominguez-Aguilar MA, Flores EA, Arellanes- Lozada P, Jimenez-Cruz F (2012) Corrosion inhibitor activity of 1,3-diketone malonates for mild steel in aqueous hydrochloric acid solution. Corros Sci 61:171–184

    Article  CAS  Google Scholar 

  33. Goulart CM, Esteves-Souza A, Martinez-Huitle CA, Rodrigues CJF, Maciel MAM, Echevarria A (2013) Experimental and theoretical evaluation of semicarbazones and thiosemicarbazones as organic corrosion inhibitors. Corros Sci 67:281–291

    Article  CAS  Google Scholar 

  34. Ateya BG, El-Anadouli BE, El-Nizamv FM (1984) The adsorption of thiourea on mild steel. Corros Sci 24:509–515

    Article  CAS  Google Scholar 

  35. Li XH, Deng SD, Fu H, Mu GN (2010) Synergistic inhibition effect of rare earth cerium (IV) ion and sodium oleate on the corrosion of cold rolled steel in phosphoric acid solution. Corros Sci 52:1167–1178

    Article  CAS  Google Scholar 

  36. Palomar-Pardave M, Romero-Romo M, Herrera-Hernández H, Abreu-Quijano MA, Likhanova NV, Uruchurtu J, Juárez-García JM (2012) Influence of the alkyl chain length of 2 amino 5 alkyl 1,3,4 thiadiazole compounds on the corrosion inhibition of steel immersed in sulfuric acid solutions. Corros Sci 54:231–243

    Article  CAS  Google Scholar 

  37. Ahamad I, Prasad R, Quraishi MA (2010) Adsorption and inhibitive properties of some new Mannich bases of isatin derivatives on corrosion of mild steel in acidic media. Corros Sci 52:1472–1481

    Article  CAS  Google Scholar 

  38. Fang J, Li J (2002) Quantum chemistry study on the relationship between molecular structure and corrosion inhibition efficiency of amides. J Mol Struct 593:179–185

    Article  CAS  Google Scholar 

  39. Singh AK, Khan S, Singh A, Quraishi SM, Quraishi MA, Ebenso EE (2012) Inhibitive effect of chloroquine towards corrosion of mild steel in hydrochloric acid solution. Res Chem Intermed. doi:10.1007/s11164-012-0677-8

    Google Scholar 

  40. Lukovits I, Kalman E, Zucchi F (2001) Corrosion inhibitors correlation between electronic structure and efficiency. Corrosion 57:3–8

    Article  CAS  Google Scholar 

  41. Zhan CG, Nichols JA, Dixon DA (2003) Ionization potential, electron affinity, electronegativity, hardness, and electron excitation energy: molecular properties from density functional theory orbital energies. J Phys Chem A 107:4184–4195

    Article  CAS  Google Scholar 

  42. Al-Sabagh AM, Nasser NM, Farag AA, Migahed MA, Eissa AMF, Mahmoud T (2013) Structure effect of some amine derivatives on corrosion inhibition efficiency for carbon steel in acidic media using electrochemical and quantum theory methods. Egypt J Pet 22:101–116

    Article  Google Scholar 

  43. Ebenso EE, Arslan T, Kandemirli K, Love I, Retlr C, Lu MS, Umoren SA (2010) Theoretical studies of some sulphonamides as corrosion inhibitors for mild steel in acidic medium. Int J Quantum Chem 110:2614–2636

    Article  CAS  Google Scholar 

  44. Zhao P, Liang Q, Li Y (2005) Electrochemical, SEM/EDS and quantum chemical study of phthalocyanines as corrosion inhibitors for mild steel in 1 mol/L HCl. Appl Surf Sci 252:1596–1607

    Article  CAS  Google Scholar 

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Acknowledgments

The authors would like to thank University of Mysore, Mysore, MHRD, and UGC, New Delhi for providing financial assistance through Institution of Excellence (IOE) scheme.

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Authors and Affiliations

  1. Department of Studies in Chemistry, University of Mysore, Manasagangotri, Mysore, 570 006, India

    C. B. Pradeep Kumar & K. N. Mohana

  2. Centre for Emerging Technologies, Jain University, Bangalore, 562 112, India

    H. B. Muralidhara

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  1. C. B. Pradeep Kumar
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  2. K. N. Mohana
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Correspondence to K. N. Mohana.

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Kumar, C.B.P., Mohana, K.N. & Muralidhara, H.B. Electrochemical and thermodynamic studies to evaluate the inhibition effect of synthesized piperidine derivatives on the corrosion of mild steel in acidic medium. Ionics 21, 263–281 (2015). https://doi.org/10.1007/s11581-014-1178-0

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