Skip to main content
Log in

Thermodynamics and kinetics of in-situ formation of TiAl3/7075 composites

  • Published:
Journal of Wuhan University of Technology-Mater. Sci. Ed. Aims and scope Submit manuscript

Abstract

The thermodynamics and kinetics of the reaction between Titanium powder and 7075 aluminum alloy were investigated to assess the possibility of preparing TiAl3/7075 composites by in-situ synthesis method. Results show that Ti and Al melt can form TiAl3 spontaneously, which is considered as a reinforced phase of the matrix. Measurements such as XRD, SEM, and EDX were performed to characterize the as-synthesized samples, and results confirmed the formation of TiAl3 in aluminum matrix composites. The reactive kinetics was controlled by three main factors, which are the system temperature, particle size of Ti, and the thickness of external diffusion layer.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Y H F Su, Y C Chen, Y A Tsao. Workability of Spray-Formed 7075 Al Alloy Reinforced with SiCp at Elevated Temperatures [J]. Mater. Sci. Eng. A, 2004, 364:296–304

    Article  Google Scholar 

  2. N V R Kumar, E S Dwarakadasa. Effect of Matrix Strength on the Mechanical Properties of Al-Zn-Mg/SiCP Composites[J]. Composites Part A, 2000, 31: 1 139–1 145

    Google Scholar 

  3. D Z Wang, H X Peng, J Liu, et al. Wear Behaviour and Microstructural Changes of SiCw-Al Composite under Unlubricated Sliding Friction [J]. Wear, 1995, 184:187–192

    Article  CAS  Google Scholar 

  4. W S Lee, W C Sue, C F Lin. The Strain and Temperature Dependence of the Dynamic Impact Properties of 7075 Aluminum Alloy[J]. Compos. Sci. Technol., 2000, 60:1 975–1 983

    CAS  Google Scholar 

  5. N Cinca, M Barbosa, S Dosta, et al. Study of Ti Deposition onto Al Alloy by Cold Gas Spraying [J]. Surf Coat Technol., 2010, 20:1 096–1 102

    Google Scholar 

  6. E A Aguilara, C A León, A Contreras, et al. Wettability and Phase Formation in TiC/Al Alloy Assemblies [J]. Composites Part A, 2002, 33:1 425–1 428

    Google Scholar 

  7. W Lacom. Calorimetric Investigations in a Dispersion Strengthened 7075 Alloy[J]. Thermochim Acta, 1996, 27: 93–100

    Article  Google Scholar 

  8. A Kalkanl, S Yılmaz. Synthesis and Characterization of Aluminum Alloy 7075 Reinforced with Silicon Carbide Particulates [J]. Materials & Design, 2008, 29(4):775–780

    Article  Google Scholar 

  9. W Lacom, K Spiradek. Assessment of Thermal-Treatment Conditions for Age-Hardenable Particulate-Reinforced Aluminium Alloys by Calorimetric Methods [J]. Thermochim Acta, 1998, 310: 125–132

    Article  CAS  Google Scholar 

  10. Y Zhang, N Ma, X Li, et al. Study on Damping Capacity of Aluminum Composite Reinforced with in Situ TiAl3 Rod [J]. Materials & Design, 2008, 29(5):1 057–1 059

    Google Scholar 

  11. M Pekar. What Can Kinetics Learn from Rational Thermodynamics [J]. Chemical Engineering Science, 2004, 59(19): 4 103–4 112

    Article  CAS  Google Scholar 

  12. H Jones. Some Effects of Solidification Kinetics on Microstructure Formation in Aluminium-Base Alloys [J]. Materials Science and Engineering: A, 2005, 413–414: 165–173

    Article  Google Scholar 

  13. D Veeraraghavan, P Wang, V K Vasudevan. Kinetics and Thermodynamics of the αΓ Massive Transformation in a Ti-47.5 at% Al Alloy [J]. Acta Materialia, 1999, 47(11): 3 313–3 330

    Article  CAS  Google Scholar 

  14. Li Honggui. Metallurgical Principle[M]. Bei Jing: Press Science, 2005

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Hong Yan  (闫洪).

Additional information

Supported by the National Natural Science Foundation of China (Nos.51165032,51102131) and the Innovative Group of Science and Technology of College of Jiangxi Province (No.00008713)

Rights and permissions

Reprints and permissions

About this article

Cite this article

Yan, H., Ai, F. & Chen, X. Thermodynamics and kinetics of in-situ formation of TiAl3/7075 composites. J. Wuhan Univ. Technol.-Mat. Sci. Edit. 28, 598–603 (2013). https://doi.org/10.1007/s11595-013-0737-y

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11595-013-0737-y

Key words

Navigation