Abstract
This work presents an investigation on the influence of the solder/under bump metallization (UBM) interfacial reaction to the tensile strength and fracture behavior of Sn-3.5Ag/Ni-P solder joints under different thermal aging conditions. The tensile strength of Sn-3.5Ag/Ni-P solder joints decreases with aging temperature and duration. Four types of failure modes have been identified. The failure modes shift from the bulk solder failure mode in the as-soldered condition toward the interfacial failure modes. Kirkendall voids do not appear to affect the tensile strength of the joint. The volume change of Ni-P phase transformation during the thermal aging process generates high tensile stress inside the Ni-P layer; this stress causes mudflat cracks on the remaining Ni-P coating and also leads to its delamination from the underlying Ni substrate. In general, interfacial reaction and the subsequent growth of Ni3Sn4 intermetallic compound (IMC) layer during solid-state reaction are the main reasons for the decrease of tensile strength of the solder joints. The current study finds there is an empirical linear relation between the solder joint strength and the Ni3Sn4 intermetallic compound (IMC) thickness. Therefore, the IMC thickness may be used as an indication of the joint strength.
Similar content being viewed by others
References
K.N. Tu and K. Zeng: Mater. Sci. Eng. R, 2001, vol. 34, pp. 1–58.
S. Ahat, M. Sheng, and L. Luo: J. Mater. Res., 2001, vol. 16, pp. 2914–21.
M. He, Z. Chen, and G.J. Qi: Acta Mater., 2004, vol. 52, pp. 2047–56.
K. Kishimoto, M. Omiya, and M. Amagai: Proc. 3rd Int. Symp. on Electronic Materials and Packaging, Cheju, Korea, IEEE, New York, NY, 2002, pp. 8–14.
H.T. Lee and M.H. Chen: Mater. Sci. Eng. A, 2002, vol. 333, pp. 24–34.
T.Y. Lee, W.J. Choi, K.N. Tu, and J.W. Jang: J. Mater. Res., 2002, vol. 17, pp. 291–301.
G.J. Qi, M. He, and Z. Chen: Proc. Yazawa Int. Symp., in Conjunction with the 2003 TMS Annual Meeting and Exhibition, San Diego, CA, TMS, Warrendale, PA, 2003, vol. 1, pp. 1173–83.
M. Amagai, M. Watanabe, M. Omiya, K. Kishimoto, and T. Shibuya: Microelectron. Reliab., 2002, vol. 42, pp. 951–66.
D.R. Frear and P.T. Vianco: Metall. Mater. Trans. A, 1994, vol. 25A, pp. 1509–23.
R.E. Pratt, E.I. Stromswold, and D.J. Quesnel: J. Electron. Mater., 1994, vol. 23, pp. 375–81.
R.E. Pratt, E.I. Stromswold, and D.J. Quesnel: IEEE Trans. Compon. Packaging, Part A, 1996, vol. 19, pp. 134–41.
D.R. Frear, F.M. Hosking, and P.T. Vianco: in Materials Developments in Microelectronic Packaging, P.J. Singh, ed., ASM INTERNATIONAL, Materials Park, OH, 1991, pp. 229–40.
S.W. Chen, S.W. Lee, and M.C. Yip: J. Electron. Mater., 2003, vol. 32, pp. 1284–89.
C.W. Hwang, K. Suganuma, M. Kiso, and S. Hashimoto: J. Mater. Res., 2003, vol. 18, pp. 2540–43.
S.J. Wang and C.Y. Liu: Scripta Mater., 2003, vol. 49, pp. 813–18.
K. Zeng and K.N. Tu: Mater. Sci. Eng. R, 2002, vol. 38, pp. 55–105.
Y.C. Chan, P.L. Tu, C.W. Tang, K.C. Hung, and J.K.L. Lai: IEEE Trans. Adv. Packaging, 2001, vol. 24, pp. 25–32.
J.W. Jang, P.G. Kim, K.N. Tu, D.R. Frear, and P. Thompson: J. Appl. Phys., 1999, vol. 85, pp. 8456–63.
S. Ahat, W. Huang, M. Sheng, and L. Luo: J. Electron. Mater., 2002, vol. 31, pp. 136–41.
K.C. Hung, Y.C. Chan, C.W. Tangand, and H.C. Ong: J. Mater. Res., 2000, vol. 15, pp. 2534–39.
Y. Chonan, T. Komiyama, J. Onuki, R. Urao, T. Kimura, and T. Nagano: Mater. Trans., 2002, vol. 43, pp. 1840–46.
Y. Chonan, T. Komiyama, J. Onuki, R. Urao, T. Kimura, and T. Nagano: Mater. Trans., 2002, vol. 43, pp. 1887–90.
J.K. Lin, A.D. Silva, D. Frear, Y. Guo, and J.W. Jang: Proc. 51st Electronic Components and Technology Conf., Orlando, FL, IEEE, New York, NY, 2001, pp. 455–62.
P.T. Vianco: Soldering Handbook, 3rd ed., American Welding Society, Miami, FL, 1999, pp. 214–17.
Y.W. Cheng and T.A. Siewert: J. Electron. Mater., 2003, vol. 32, pp. 535–40.
D.P. Yao and J.K. Shang: IEEE Trans. Compon. Packaging, Part B, 1996, vol. 19, pp. 154–65.
Y.D. Jeon, K.W. Paik, K.S. Bok, W.S. Choi, and C.L. Cho: J. Electron. Mater., 2002, vol. 31, pp. 520–28.
G.O. Mallory and J.B. Hajdu: Electroless Plating: Fundamentals and Applications, Reprint ed., AESF, Noyes/William Andrew Publishing, Norwich, NY, 1990, pp. 122–25.
S. Anhock, A. Ostmann, H. Oppermann, R. Aschenbrenner, and H. Reichl: Symp. on Advanced Packaging Materials, Braselton, GA, IEEE, New York, NY, pp. 256–61.
D. Goyal, T. Lane, P. Kinzie, C. Panichas, K.M. Chong, and O. Villalobos: Proc. 52nd Electronic Components and Technology Conf., San Diego, CA, 2002, pp. 732–39.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
He, M., Chen, Z. & Qi, G. Mechanical strength of thermally aged Sn-3.5Ag/Ni-P solder joints. Metall Mater Trans A 36, 65–75 (2005). https://doi.org/10.1007/s11661-005-0139-7
Received:
Issue Date:
DOI: https://doi.org/10.1007/s11661-005-0139-7