Abstract
The microstructural evolution of a spray-formed and extruded hypereutectic aluminum-30 pct silicon-5 pct copper-2 pct magnesium alloy heated into the semisolid state has been investigated. Liquid is formed initially by a quaternary eutectic reaction and then by a ternary melt reaction. These reactions occur relatively quickly. However, the binary Al-Si eutectic melt reaction takes a significant time—around several hours depending on the temperature. The coarsening rate constants (K) for the growth of the silicon particles are approximately three to four orders of magnitude lower than those for the majority of metal spray-formed alloys. This may be associated with difficulties in addition or removal of atoms from the low index silicon facets. Where growth does occur, agglomeration of silicon particles may play a large role, especially at higher liquid contents. Electron backscatter diffraction (EBSD) gives evidence of agglomeration, and furthermore shows that high-angle silicon-silicon boundaries are not wetted with liquid.
Similar content being viewed by others
References
N. Tenekedjiev and J.E. Gruzleski: AFS Trans., 1989, vol. 97, pp. 127–36.
N. Tenekedjiev and J.E. Gruzleski: Cast Met., 1990, vol. 3, pp. 96–105.
W.J. Kyffin, W.M. Rainforth, and H. Jones: Mater. Sci. Technol., 2001, vol. 17, pp. 901–05.
P.S. Grant: Progr. Mater. Sci., 1995, vol. 39, pp. 497–545.
P.J. Ward, H.V. Atkinson, D.H. Kirkwood, and C.M. Sellars: Proc. 2nd Int. Conf. on Semi-Solid Processing of Alloys and Composites, S.B. Brown and M.C. Flemings, eds., TMS, Warrendale, PA, 1992, pp. 440–46.
E.J. Lavernia and Y. Wu: Spray Atomization and Deposition, John Wiley & Sons, Chichester, 1996.
P.J. Ward, H.V. Atkinson, P.R.G. Anderson, L.G. Elias, B. Garcia, L. Kahlen, and J.M. Rodriguez-Ibabe: Acta Metall. Mater., 1996, vol. 44, pp. 1717–27.
M.C. Flemings: Metall. Trans. A, 1991, vol. 22A, pp. 957–81.
H.V. Atkinson, P. Kapranos, and D.H. Kirkwood: Proc. 6th Int. Conf. on Semi-Solid Processing of Alloys and Composites, G.L. Chiarmetta and M. Rosso, eds., Turin, 2000, pp. 443–50.
D. Walukas, S. LeBeau, N. Prewitt, and R. Decker: Proc. 6th Int. Conf. on Semi-Solid Processing of Alloys and Composites, G.L. Chiarmetta and M. Rosso, eds., Turin, 2000, pp. 109–14.
S.C. Hogg, H.V. Atkinson, and P. Kapranos: Metall. Mater. Trans. A, 2004, vol. 35A, pp. 899–910.
F. Mondolfo: Aluminium Alloys, Structures and Properties, Butterworth and Co., London, 1976, p. 773.
S. Annavarapu and R.D. Doherty: Acta Metall. Mater., 1995, vol. 43, pp. 3207–30.
S. Takajo, W.A. Kaysser, and G. Petzow: Acta Metall. Mater., 1984, vol. 32, pp. 107–13.
R.P. Underhill, P.S. Grant, D.J. Bryant, and B. Cantor: J. Mater. Synthesis Processing, 1995, vol. 3, pp. 171–79
E. Manson-Whitton, I.C. Stone, J.R. Jones, P.S. Grant, and B. Cantor: Acta Mater., 2002, vol. 50, pp. 2517–35.
I.M. Lifshitz and V.V. Slyozov: J. Phys. Chem. Solids, 1961, vol. 19, pp. 35–50.
C. Wagner: Z. Elektrochem., 1961, vol. 65, pp. 581–91.
P.S. Grant, R.P. Underhill, W.T. Kim, K.P. Mingard, and B. Cantor: Proc. 2nd Int. Conf. on Spray Forming, J.V. Wood, ed., Osprey Metals, Red Jacket Works, Neath, United Kingdom, 1993, pp. 45–54.
J.L. Murray and A.J. McAlister: Bull. Alloy Phase Diagrams, 1984, vol. 4, pp. 74–90.
M. Petrescu: Z. Metallkd., 1970, vol. 61, pp. 14–18.
S.C. Hogg: Ph.D. Thesis, University of Sheffield, Sheffield, 2001.
S.C. Hogg, C.J.D. Hetherington, and H.V. Atkinson, Phil. Mag. Lett., 2000, vol. 80, pp. 477–82.
K.A. Jackson: Liquid Metals and Solidification, ASM, Cleveland, OH, 1958, p. 174.
H.A.H. Steen and A. Hellawell: Acta Metall., 1975, vol. 23, pp. 529–35.
R.-Y. Wang, W.-H. Lu, and L.M. Hogan: J. Cryst. Growth, 1999, vol. 207, pp. 43–54.
R.S. Wagner: Acta Met., 1960, vol. 8, pp. 57–60.
D.R. Hamilton and R.G. Siedensticker: J. Appl. Phys., 1960, vol. 32, pp. 1165–68.
C.S. Smith: Trans. Am. Inst. Min. Met. Eng., 1948, vol. 175, pp. 15–51.
V. de L. Davies and J.M. West: J. Inst. Met., 1963–64, vol. 92, pp. 175–80.
M. Gündüz and J.D. Hunt: Acta Metall., 1985, vol. 33, pp. 1651–72.
P. Keblinski, D. Wolf, S.R. Phillpot, and H.J. Gleiter: J. Mater. Res., 1998, vol. 13, pp. 2077–99.
P. Keblinski, D. Wolf, S.R. Phillpot, and H. Gleiter: Phys. Rev. Lett., 1996, vol. 77, pp. 2965–68.
V. Randle: The Role of the Coincidence Site Lattice in Grain Boundary Engineering, The Institute of Materials, London, 1996.
R.J. Jaccodine: J. Electrochem. Soc., 1963, vol. 110, pp. 524–27.
J.I. Lee, H.I. Lee, and M.I. Kim: Scripta Metall. Mater., 1995, vol. 32, pp. 1945–49.
Y.H. Ryoo, I.J. Kim, and K.H. Kim: Proc. 4th Int. Conf. on the Processing of Semi-Solid Alloys and Composites, D.H. Kirkwood and P. Kapranos, eds., The University of Sheffield, Sheffield, 1996, pp. 66–70.
A. Voigt, E. Wolf, and H.P. Strunk: Mater. Sci. Eng. B, 1998, vol. B54, pp. 202–06.
A. Garg, W.A.T. Clark, and J.P. Hirth: Phil. Mag. A, 1989, vol. 59, pp. 1205–20.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Hogg, S.C., Atkinson, H.V. Inhibited coarsening of a spray-formed and extruded hypereutectic aluminum-silicon alloy in the semisolid state. Metall Mater Trans A 36, 149–159 (2005). https://doi.org/10.1007/s11661-005-0147-7
Received:
Issue Date:
DOI: https://doi.org/10.1007/s11661-005-0147-7