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On the Structure, Transformation and Deformation of Long-Period Stacking Ordered Phases in Mg-Y-Zn Alloys

  • Symposium: Processing-Microstructure-Property Relationships & Deformation Mechanisms of Magnesium Alloys
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Abstract

Ternary Mg-Y-Zn alloys have attracted considerable attention due to their unique microstructures and promising mechanical properties. The microstructure of these alloys contains predominantly intermetallic phases of 18R and/or 14H long-period stacking ordered (LPSO) structures, depending on the alloy processing conditions. Such 18R and/or 14H structures or similar LPSO structures are also found in other magnesium alloys such as Mg-Gd-Zn, Mg-Gd-Y-Zn, Mg-Dy-Zn, Mg-Ho-Zn, Mg-Er-Zn, Mg-Y-Cu, Mg-Y-Ni, and Mg-Y-Co. In addition, LPSO structures such as 24R and 10H have also been reported, even though they are less frequently observed. This paper provides a review of the current status on the characterization of the structure, thermal stability, transformation, and deformation of the LPSO structures using high-angle annular dark-field scanning transmission electron microscopy and electron diffraction. Unsolved issues on the LPSO structures are also highlighted and discussed.

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Notes

  1. By shuffles we mean the movement of atoms over just a few atomic distances in contrast to diffusion which involves the long-range movement of atoms.

References

  1. Z.P. Luo, S.Q. Zhang, Y.L. Tang and D.S. Zhao: J. Alloys Compd., 1994, vol. 209, pp. 275-278.

    Article  Google Scholar 

  2. M. Yamasaki, T. Anan, S. Yoshimoto and Y. Kawamura: Scripta Mater., 2005, vol. 53, pp. 799-803.

    Article  Google Scholar 

  3. M. Yamasaki, M. Sasaki, M. Nishijima, K. Hiraga and Y. Kawamura: Acta Mater., 2007, vol. 55, pp. 6798-6805.

    Article  Google Scholar 

  4. J.F. Nie, K. Oh-ishi, X. Gao and K. Hono: Acta Mater., 2008, vol. 56, pp. 6061-6076.

    Article  Google Scholar 

  5. K. Yamada, Y. Okubo, M. Shiono, H. Watanabe, S. Kamado and S. Kojima: Mater Trans., 2006, vol. 47, pp. 1066-1070.

    Article  Google Scholar 

  6. K. Amiya, T. Ohsuna and A. Inoue: Mater. Trans., 2003, vol. 44, pp. 2151-2156.

    Article  Google Scholar 

  7. M. Matsuura, K. Konno, M. Yoshida, M. Nishijima and K. Hiraga: Mater. Trans., 2006, vol. 47, pp. 1264-1267.

    Article  Google Scholar 

  8. S.B. Mi and Q.Q. Jin: Scripta Mater., 2013, vol. 68, pp. 635-638.

    Article  Google Scholar 

  9. E.M. Padezhnova, E.V. Melnik, R.A. Miliyevskiy, T.V. Dobatkina, and V.V. Kinzhibalo: Russ. Metall. (Engl. Transl.), 1982, vol. 4, pp. 185–88.

  10. Z.P. Luo and S.Q. Zhang: J. Mater. Sci. Lett., 2000, vol. 19, pp. 813-815.

    Article  Google Scholar 

  11. Y. Kawamura, K. Hayashi, A. Inoue and T. Masumoto: Mater. Trans., 2001, vol. 42, pp. 1172-1176.

    Article  Google Scholar 

  12. T. Itoi, T. Seimiya, Y. Kawamura and M. Hirohashi: Scripta Mater., 2004, vol. 51, pp. 107-111.

    Article  Google Scholar 

  13. M. Matsuda, S. Ii, Y. Kawamura, Y. Ikuhara and M. Nishida: Mater. Sci. Eng. A, 2005, vol. 393, pp. 269-274.

    Article  Google Scholar 

  14. E. Abe, Y. Kawamura, K. Hayashi and A. Inoue: Acta Mater., 2002, vol. 50, pp. 3845-3857.

    Article  Google Scholar 

  15. D.H. Ping, K. Hono, Y. Kawamura and A. Inoue: Phil. Mag. Lett., 2002, vol. 82, pp. 543-551.

    Article  Google Scholar 

  16. Y.M. Zhu, A.J. Morton and J.F. Nie: Acta Mater., 2010, vol. 58, pp. 2936-2947.

    Article  Google Scholar 

  17. S. Yoshimoto, M. Yamasaki and Y. Kawamura: Mater. Trans., 2006, vol. 47, pp. 959–65.

    Article  Google Scholar 

  18. J. Lee, K. Sato, T.J. Konno and K. Hiraga: Mater. Trans., 2009, vol. 50, pp. 222-225.

    Article  Google Scholar 

  19. A. Ono, E. Abe, T. Itoi, M. Hirohashi, M. Yamasaki and Y. Kawamura: Mater. Trans., 2008, vol. 49, pp. 990-994.

    Article  Google Scholar 

  20. J. Grobner, A. Kozlov, X.Y. Fang, J. Geng, J.F. Nie and R. Schmid-Fetzer: Acta Mater., 2012, vol 60, pp. 5948-5962.

    Article  Google Scholar 

  21. J.F. Nie: Metall. Mater. Trans. A, 2012, vol. 43, pp. 3891-3939.

    Article  Google Scholar 

  22. Y.M. Zhu, M. Wayland, A.J. Morton, K. Oh-ishi, K. Hono and J.F. Nie: Scripta Mater., 2009, vol. 60, pp. 980-983.

    Article  Google Scholar 

  23. H. Yokobayashi, K. Kishida, H. Inui, M. Yamasaki and Y. Kawamura: Acta Mater., 2011, vol. 59, pp. 7287-7299.

    Article  Google Scholar 

  24. D. Egusa and E. Abe: Acta Mater., 2012, vol. 60, pp. 166-178.

    Article  Google Scholar 

  25. J. E. Saal and C. Wolverton: Scripta Mater., 2012, vol. 67, pp. 798-801.

    Article  Google Scholar 

  26. H. Kimizuka, M. Fronzi and S. Ogata: Scripta Mater., 2013, vol. 69, pp. 594-597.

    Article  Google Scholar 

  27. K. Kishida, H. Yokobayashi and H. Inui: Phil. Mag., 2013, vol. 93, pp. 2826-2846.

    Article  Google Scholar 

  28. E. Abe, A. Ono, T. Itoi, M. Yamasaki and Y. Kawamura: Phil. Mag. Letts., 2011, vol. 91, pp. 690-696.

    Article  Google Scholar 

  29. Z. Leng, J.H. Zhang, M.L. Zhang, X.H. Liu, H.B. Zhan and R.Z. Wu: Mater. Sci. Eng. A, 2012, vol. 540, pp. 38-45.

    Article  Google Scholar 

  30. Y. Komura, M. Mitarai, I. Nakatani, H. Iba and T. Shimizu: Acta Cryst., 1970, vol. B26, pp. 666-668.

    Article  Google Scholar 

  31. Y. Komura, A. Nakaue and M. Mitarai: Acta Cryst., 1972, vol. B28, pp. 727-732.

    Article  Google Scholar 

  32. Y. Komura and Y. Kitano: Acta Cryst., 1977, vol. B33, pp. 2496-2501.

    Article  Google Scholar 

  33. K.H. Lieser and H. Witte: Z. Metallk., 1952, vol. 43, pp. 396-401.

    Google Scholar 

  34. Y.M. Zhu, A.J. Morton and J.F. Nie: Acta Mater., 2012, vol. 60, pp. 6562-6572.

    Article  Google Scholar 

  35. T. Kiguchi, Y. Ninomiya, K. Shimmi, K. Sato, and T.J. Konno: Mater. Trans., 2013, vol. 54, pp. 668–74.

    Article  Google Scholar 

  36. T. Furuhara and X.F. Gu: Mater. Trans., 2013, vol. 54, pp. 668-674.

    Article  Google Scholar 

  37. X.H. Shao, Z.Q. Yang and X.L. Ma: Acta Mater., 2010, vol. 58, pp. 4760-4771.

    Article  Google Scholar 

  38. K. Hagihara, N. Yokotani and Y. Umakoshi: Intermetallics, 2010, vol. 18, pp. 267-276.

    Article  Google Scholar 

  39. K. Hagihara, Y. Sugino, Y. Fukusumi, Y. Umakoshi and T. Nakano: Mater. Trans., 2011, vol. 52, pp. 1096-1103.

    Article  Google Scholar 

  40. K. Hagihara, Y. Fukusumi, M.Yamasaki, T. Nakano and Y. Kawamura: Mater. Trans., 2013, vol. 54, pp. 693-697.

    Article  Google Scholar 

  41. E. Onorbe, G. Garces, P. Perez and P. Adeva: J. Mater. Sci., 2012, vol. 47, pp. 1085-93.

    Article  Google Scholar 

  42. E. Orowan: Nature, 1942, vol. 149, pp. 643-644.

    Article  Google Scholar 

  43. B. Hess and C.S. Barrett: Trans. Am. Inst. Min. Met. Eng., 1949, vol. 185, pp. 599-606.

    Google Scholar 

  44. A.G. Crocker and J.S. Abell: Phil. Mag., 1976, vol. 33, pp. 305-310.

    Article  Google Scholar 

  45. L. Farber, I. Levin and M.W. Barsoum: Phil. Mag. Lett., 1999, vol. 79, pp. 163-70.

    Article  Google Scholar 

  46. M. Yamasaki, K. Hagihara, S. Inoue, J.P. Hadorn and Y. Kawamura: Acta Mater., 2013, vol. 61, pp. 2065-2076.

    Article  Google Scholar 

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Acknowledgments

The authors acknowledge gratefully the financial support from the Australian Research Council, the access to the facilities of the Monash Centre for Electron Microscopy and Yangxin Li and Ruiqi Chen for sample preparation.

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Correspondence to J. F. Nie.

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A.J. Morton has been a retired person, and work covered by this paper was done at Monash.

Manuscript submitted November 8, 2013.

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Nie, J.F., Zhu, Y.M. & Morton, A.J. On the Structure, Transformation and Deformation of Long-Period Stacking Ordered Phases in Mg-Y-Zn Alloys. Metall Mater Trans A 45, 3338–3348 (2014). https://doi.org/10.1007/s11661-014-2301-6

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  • DOI: https://doi.org/10.1007/s11661-014-2301-6

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