Skip to main content
SpringerLink
Log in

Critical Phenomena and Estimation of Spontaneous Magnetization by Magnetic Entropy Analysis of La0.7Sr0.3Mn0.94Cu0.06O3

  • Published:
Metallurgical and Materials Transactions A Aims and scope Submit manuscript

Abstract

This paper presents a detailed study on the structural, magnetic, and critical behavior and magnetocaloric effect of La0.7Sr0.3Mn0.94Cu0.06O3 prepared by solid-state reaction method. X-ray diffraction patterns indicate that Cu-doped manganite crystallizes to a single phase with a rhombohedral structure. Critical components β, γ, and δ were determined by using modified Arrott plot, Kouvel–Fisher method, and critical isotherm analyses. These components are consistent with their corresponding values and were validated by Widom scaling law and scaling theory. The deduced critical exponents (β = 0.456, γ = 0.9912, and δ = 3.206) are also close to their corresponding theoretical values predicted by mean-field model, indicating that long-range interaction dominates the critical behavior of the LSMCO system. Spontaneous magnetization was determined by two methods. One method is based on magnetic entropy change under different magnetic fields, and the other method is based on classical extrapolation from the Arrott plot. The two methods are in excellent agreement, confirming the validity of the deduction of spontaneous magnetization using the magnetic entropy change.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10

Similar content being viewed by others

References

  1. E. Dagotto, T. Hotta, A. Moreo, Phys. Rep. 2001, 344, 1-153.

    Article  Google Scholar 

  2. P. T. Phong, L.V. Bau, L. C. Hoan, D. H. Manh, N. X. Phuc, In-Ja Lee, J. Alloys Compd. 2015, 645, 243-249.

    Article  Google Scholar 

  3. C. Zener, Phys. Rev. 1951, 81, 440-444.

    Article  Google Scholar 

  4. P. T. Phong, L. V. Bau, L. C. Hoan, D. H. Manh, N. X. Phuc, In-Ja Lee, J. Alloys. Compd. 2016, 656, 920-928.

    Article  Google Scholar 

  5. A. J. Millis, P.B. Littlewood, B.I. Shraiman, Phys. Rev. Lett. 1995, 74, 5144-147.

    Article  Google Scholar 

  6. MB Salamon, P Lin, SH Chun, Phys. Rev. Lett. 2002, 88, 197203 (4 pp).

    Article  Google Scholar 

  7. A. Urushibara, Y. Moritomo, T. Arima, A. Asamitsu, G. Kido, Y. Tokura, Phys. Rev. B 1995, 51, 14103-14109.

    Article  Google Scholar 

  8. K Cherif, S Zemni, J Dhahri, J Dhari, M Oumezzine, M Ghedira, H Vincent, J. Alloys. Compd. 2005, 396, 29-33.

    Article  Google Scholar 

  9. Z. Guo, J. Zhang, N. Zhang, W. Ding, H. Huang, Y. Du, Appl. Phys. Lett. 1997, 70, 904-905.

    Article  Google Scholar 

  10. V. S. Kolat, S. Atalay, T. Izgi, H. Gencer, N.T Bayri, Metall. Trans. A 2015, 46 (6), 2591–2597.

    Article  Google Scholar 

  11. MH Phan, S.-C. Yu, NH Hur, Appl. Phys. Lett. 2005, 86, 072504 (3 pp).

    Article  Google Scholar 

  12. S. G. Choi, H. -S. Lee, H. Choi, S. -W. Chung, H. -H. Park, J. Phys. D: Appl. Phys. 2013, 46, 425102 (6pp).

    Google Scholar 

  13. M. H. Phan, S. -B. Tian, S. -C. Yu, A. N. Ulyanov, J. Magn. Magn. Matter. 2003, 256, 306-310.

    Article  Google Scholar 

  14. F. Ayadi, Y. Regaigeg, W. Cheikhrouhou-Koubaa, M. Koubaa, A. Cheikhrouhou, H. Lecoq, S. Nowak, S. Ammar, L. Sicard, J. Magn. Magn. Matter. 2015, 381, 215-219.

    Article  Google Scholar 

  15. T. D. Thanh, L. H. Nguyen, D. H. Manh, N. V. Chien, P. T. Phong, N. V. Khiem, L. V. Hong, N. X. Phuc, Physica B 2012, 407, 145-152.

    Article  Google Scholar 

  16. V. P. S. Awana, E. Schmitt, E. Gmelin, A. Gupta, A. Sedky, A. V. Narlikar, O. F. de Lima, C. A. Cardoso, S. K. Malik, W. B. Yelon, J. Appl. Phys. 2000, 87, 5034-5036.

    Article  Google Scholar 

  17. DNH Nam, LV Bau, NV Khie, NV Dai, LV Hong, NX Phuc, RS Newrock, P Nordblad, Phys. Rew. B 2006, 73, 184430 (6 pp).

    Article  Google Scholar 

  18. Y. D Zhang, T. -L Phan, D. S Yang, S. C Yu, Curr. Appl. Phys. 2012, 12, 803-807.

    Article  Google Scholar 

  19. T. -L. Phan, T. D. Thanh, S. C. Yu, J. Alloys Compd. 2014, 615, 5247-5251.

    Article  Google Scholar 

  20. P. T. Phong, N. V. Dang, L. V. Bau, N. M. An, In-Ja Lee, J. Alloys Compd. 2017, 698, 451-459.

    Article  Google Scholar 

  21. JL García-Munoz, C Frontera, P Beran, N Bellido, J Hernández-Velasco, C Ritter (2010) Phys. Rev. B 81:11.

    Article  Google Scholar 

  22. L. Haupt, R. Helmolt, U. Sondermann, K.Bamer, Phys. Lett. A 1992, 165, 473-479.

    Article  Google Scholar 

  23. W. E. Pickett, Rev. Mod. Phys. 1989, 61, 433-512.

    Article  Google Scholar 

  24. MS Kim, JB Yang, PE Parris, Q Cai, XD Zhou, WJ James, WB Yelon, D Buddhikot, SK Malik (2005) J. Appl. Phys. 97:3.

    Google Scholar 

  25. A. G. Belous, O. I. Vyunov, O. Z. Yanchevskii, A. I. Tovstolytkin,V. O. Golub, Inorg. Mater. 2006, 42, 286-293.

    Article  Google Scholar 

  26. MS Kim, JB Yang, J Medvedeva,WB Yelon, PE Parris, WJ James (2008) J. Phys.: Condens. Matter 20:7.

    Google Scholar 

  27. M. -H. Phan, H. –X. Peng, S. –C. Yu, N. D. Tho, N. Chau, J. Magn. Magn. Mater. 2005, 285, 199-203.

    Article  Google Scholar 

  28. N. Chau, P. Q. Niem, H. N. Nhat, N. H. Luong, N. D. Tho, Physica B 2003, 327, 214-217.

    Article  Google Scholar 

  29. M. –H. Phan, S. – C. Yu, J. Magn. Magn. Mater. 2007, 308, 325-340.

    Article  Google Scholar 

  30. S. Mandal, J. Panda, T.K. Nath, J. Alloys Compd. 2015, 653, 453-459.

    Article  Google Scholar 

  31. Y.Motome, N. Furulawa, J. Phys. Soc. Jpn. 2001, 70, 1487-1490.

    Article  Google Scholar 

  32. K. Ghosh, C. J. Lobb, R. L. Greene, S. G. Karabashev, D. A. Shulyatev, A. A. Arsenov, Y. Mukovskii, Phys. Rev. Lett. 1998, 81, 4740-4743.

    Article  Google Scholar 

  33. B Padmanabhan, HL Bhat, S Elizabeth, S Rößler, UK Rößler, K Dörr, KH Müller (2007) Phys. Rev. B:75:7.

    Article  Google Scholar 

  34. L. Chen, J. H. He, Y. Mei, Y. Z. Cao, W. W. Xia, H. F. Xu, Z. W. Zhu, Z. A. Xu, Physica B 404 (2009) 1879-1882.

    Article  Google Scholar 

  35. M. Ziese, J. Phys. Condens. Matter 2001, 13, 2919-2934.

    Article  Google Scholar 

  36. D Kim, BL Zink, F Hellman, JMD Coey (2002) Phys. Rev. B 65:7.

    Google Scholar 

  37. R. A. Young, the Rietveld Method, 1st ed, Oxford University Press, New York, 1993, pp 12-24.

    Google Scholar 

  38. A. Belkahla, K. Cherif, J. Dhahri, E. K. Hlil, J. Alloys Compd. 2017, 715, 266 -274.

    Article  Google Scholar 

  39. P. T. Phong, L. T. Duy, L. V. Bau, N. V. Dang, D. H. Manh, In-Ja Lee, J Electroceram. 2016, 36, 58-64.

    Article  Google Scholar 

  40. A. Arrott and J. E. Noakes, Phys. Rev. Lett. 1967, 19, 786-789.

    Article  Google Scholar 

  41. B. K. Banerjee, Phys. Lett. 1964, 12, 16-17.

    Article  Google Scholar 

  42. L Zhang, H Han, M Ge, H Du, C Jin, W Wei, J Fan, C Zhang, L Pi, Y Zhang (2016) Sci. Rep. https://doi.org/10.1038/srep22397.

    Google Scholar 

  43. J Fan, L Ling, B Hong, L Zhang, L Pi, Y Zhang (2010) Phys. Rev. B 81:6.

    Google Scholar 

  44. J. S. Kouvel and M. E. Fisher, Phys. Rev. 1964, 136, A1626-A1632.

    Article  Google Scholar 

  45. M. Seeger, S. N. Kaul, H. Kronmuller, R. Reisser, Phys. Rev. B 1995, 51, 12585-12594.

    Article  Google Scholar 

  46. D Kim, B Revaz, BL Zink, F Hellman, JJ Rhyne, JE Mitchell (2002) Phys. Rev. Lett. 89:4.

    Google Scholar 

  47. N. V. Khiem, P. T. Phong, L. V. Bau, D. N. H. Nam, L. V. Hong, N. X. Phuc, J. Magn. Magn. Mater. 2009, 321, 2027-2031.

    Article  Google Scholar 

  48. V Franco, A Conde, MD Kuzmin, JM Romero-Enrique (2009) J. Appl. Phys. 105: 3.

    Article  Google Scholar 

  49. M. Hazzez, N. Ihzaz, M. Boudard, M. Oumezzine, Physica B 2015, 468-469, 39-44.

    Article  Google Scholar 

  50. I Sfifir, N OuledNasser, H BenKhlifa, W Cheikhrouhou-Koubaa, M Koubaa, A Cheikhrouhou (2016) Ceram. Inter. 42:12956-12963.

    Article  Google Scholar 

  51. N Khan, P Mandal, K Mydeen, D Prabhakaran (2012) Phys. Rev. B 85:12.

    Article  Google Scholar 

  52. R Mnassri, N Chniba-Boudjada, A Cheikhrouhou (2015) J. Alloys Compd. 640:183-192.

    Article  Google Scholar 

  53. H. Oesterreicher and F. T. Parker, J. Appl. Phys. 1984, 55, 4334-4438.

    Article  Google Scholar 

  54. V Franco, R CaballeroFlores, A Conde, KE Knipling, MA Willard (2011) J. Appl. Phys 109:3.

    Google Scholar 

  55. QY Dong, HW Zhang, JR Sun, BG Shen, V Franco (2008) J. Appl. Phys. 103:3.

    Google Scholar 

  56. T. –L. Phan, Q. T. Tran, P. Q. Thanh, P. D. H. Yen, T. D. Thanh, S. C. Yu, Solid State Commun. 2014, 184, 40-46.

    Article  Google Scholar 

  57. CM Bonilla, J Herrero-Albillos, F Bartolome, LM Garcia, M Parra-Borderias, V Franco (2010) Phys. Rev. B 81:7.

    Article  Google Scholar 

  58. V Franco, JS Blazquez, A Conde (2006) Appl. Phys. Lett. 89:3.

    Article  Google Scholar 

  59. L. Xu, J. Fan, Y. Zhu, Y. Shi, L. Zhang, L. Pi, Y. Zhang, D. Shi, Mater. Res. Bull. 2016, 73, 187-191.

    Article  Google Scholar 

  60. A. M. Tishin, Y. I. Spichin, The Magnetocaloric Effect and its Applications, 2nd ed., IOP Publishing, London, 2003, pp 45-47.

    Book  Google Scholar 

  61. J. S. Amaral, N. J. O. Silva, V. S. Amaral, J. Magn. Magn. Mater. 2010, 322, 1569-1571.

    Article  Google Scholar 

Download references

Acknowledgments

This work was supported by the National Foundation for Science and Technology under Grant No. 103.02-2016.12. The authors are also thankful to the Ton Duc Thang University and Dongguk University-Gyeongju.

Author information

Authors and Affiliations

  1. Theoretical Physics Research Group, Ton Duc Thang University, Ho Chi Minh City, Vietnam

    P. T. Phong

  2. Faculty of Applied Sciences, Ton Duc Thang University, Ho Chi Minh City, Vietnam

    P. T. Phong

  3. Graduate University of Science and Technology, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Hanoi, Vietnam

    L. T. T. Ngan

  4. Department of Physics and Technology, Thai Nguyen University of Science, Thai Nguyen City, Vietnam

    L. T. T. Ngan & N. V. Dang

  5. Hong Duc University, 565 Quang Trung Street, Thanh Hoa City, Vietnam

    L. V. Bau & N. M. An

  6. Institute of Materials Science, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet Road, CauGiay District, Ha Noi, Vietnam

    L. T. H. Phong

  7. Department of Advanced Materials Chemistry, Dongguk University-Gyeongju, Dongdaero 123, Gyeongju-Si, Gyeongbuk, 38066, Korea

    In-Ja Lee

Authors
  1. P. T. Phong
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. L. T. T. Ngan
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. L. V. Bau
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. N. M. An
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. L. T. H. Phong
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. N. V. Dang
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. In-Ja Lee
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to P. T. Phong or In-Ja Lee.

Additional information

Manuscript submitted July 27, 2017.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Phong, P.T., Ngan, L.T.T., Bau, L.V. et al. Critical Phenomena and Estimation of Spontaneous Magnetization by Magnetic Entropy Analysis of La0.7Sr0.3Mn0.94Cu0.06O3 . Metall Mater Trans A 49, 385–394 (2018). https://doi.org/10.1007/s11661-017-4414-1

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11661-017-4414-1

Search

Navigation