Skip to main content
SpringerLink
Log in

Experimental study of phase equilibria in the “FeO”-ZnO-(CaO + SiO2) system with CaO/SiO2 weight ratios of 0.33, 0.93, and 1.2 in equilibrium with metallic iron

  • Published:
Metallurgical and Materials Transactions B Aims and scope Submit manuscript

Abstract

The pseudoternary sections “FeO”-ZnO-(CaO + SiO2) with CaO/SiO2 weight ratios of 0.33, 0.93, and 1.2 in equilibrium with metallic iron have been experimentally investigated in the temperature range from 1000 °C to 1300 °C (1273 to 1573 K). The liquidus surfaces in these pseudoternary sections have been experimentally determined in the composition range from 0 to 33 wt pct ZnO and 30 to 70 wt pct (CaO + SiO2). The sections contain primary-phase fields of wustite (Fe x Zn1−x O1+y ), zincite (Zn z Fe1−z O), fayalite (Fe w Zn2−w SiO4), melilite (Ca2Zn u Fe1−u Si2O7), willemite (Zn v Fe2−v SiO4), dicalcium silicate (Ca2SiO4), pseudowollastonite and wollastonite (CaSiO3), and tridymite (SiO2). The phase equilibria involving the liquid phase and the solid solutions have also been measured.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. E., Jak B., Zhao, and P.C. Hayes Metall. Mater. Trans. B, 2002, vol. 33B, pp. 865–76.

    CAS  Google Scholar 

  2. E. Jak, B. Zhao, and P.C. Hayes: Metall. Mater. Trans. B, 2000, vol. 31B, pp. 1195–1201.

    Article  CAS  Google Scholar 

  3. C.W. Bale, A.D. Pelton, and W.T. Thompson: Facility for the Analysis of Chemical Thermodynamics (F*A*C*T), Ecole Polytechnique, Montreal, 2000.

    Google Scholar 

  4. E. Jak, N. Liu, P. Wu, A. Pelton, H.G. Lee, and P.C. Hayes: Proc. 6th Aus. IMM Extractive Metallurgy Conf., Brisbane, Aus. IMM, Parkville, Victoria, Australia, 1994, pp. 253–59.

    Google Scholar 

  5. E. Jak, N. Liu, H.G. Lee, and P.C. Hayes: Proc. 6th Aus. IMM Extractive Metallurgy Conf., Brisbane, Aus. IMM, Parvkille, Victoria, Australia, 1994, pp. 261–68.

    Google Scholar 

  6. E. Jak, N. Liu, H.G. Lee, and P.C. Hayes: Proc. Lead & Zinc ’95 Int. Symp., Sendai, Japan, Mining and Materials Processing Institute of Japan, Tokyo, Japan, 1995, pp. 747–51.

    Google Scholar 

  7. E. Jak, H.G. Lee, and P.C. Hayes: Kor. IMM J., 1995, vol. 1, pp. 1–8.

    CAS  Google Scholar 

  8. E. Jak, S. Degterov, P.C. Hayes, and A.D. Pelton: Proc. 5th Int. Symp. on Metallurgical Slags and Fluxes, ISS-AIME, Sydney, 5–8 Jan. 1997, ISS, Warrendale, PA, 1997, pp. 621–28.

    Google Scholar 

  9. E. Jak, B. Zhao, and P.C. Hayes: Proc. 5th Int. Symp. on Metallurgical Slags and Fluxes, ISS-AIME, Sydney, ISS, Warrendale, PA, 1997, pp. 719–26.

    Google Scholar 

  10. E. Jak, S. Degterov, P. Wu, P.C. Hayes, and A.D. Pelton: Metall. Mater. Trans. B, 1997, vol. 28B, pp. 1011–18.

    Article  CAS  Google Scholar 

  11. E. Jak, S. Degterov, P.C. Hayes, and A.D. Pelton: Can. Metal. Q., 1998, vol. 37 (1), pp. 41–47.

    Article  CAS  Google Scholar 

  12. E. Jak, S.A. Degterov, B. Zhao, A.D. Pelton, and P.C. Hayes: Proc. Zinc and Lead Processing Symp., Calgary, Canadian Institute of Mining, and Petroleum, Metallurgy, Quebec, Canada, Aug. 1998, pp. 313–333.

    Google Scholar 

  13. E. Jak, N. Liu, and P.C. Hayes: Metall. Mater. Trans. B, 1998, vol. 29B 3, pp. 541–53.

    Article  CAS  Google Scholar 

  14. E. Jak, B. Zhao, N. Liu, and P.C. Hayes: Metall. Mater. Trans. B, 1999, vol. 30B, pp. 21–27.

    Article  CAS  Google Scholar 

  15. E. Jak, S.A. Degterov, B. Zhao, A.D. Pelton, and P.C. Hayes: Metall. Mater. Trans. B, 2000, vol. 31B, pp. 621–30.

    Article  CAS  Google Scholar 

  16. M. Kudo, E. Jak, P.C. Hayes, K. Yamaguchi, and Y. Takeda: Metall. Mater. Trans. B, 2000, vol. 31B, pp. 15–24.

    Article  CAS  Google Scholar 

  17. E. Jak, B. Zhao, and P. Hayes: MINPREX, Int. Congr. on Mineral Processing and Extractive Metallurgy, Melbourne, Oct. 2000, The Australasian Institute of Mining and Metallurgy, Carlton, Victoria, Australia, 2000, pp. 479–84.

    Google Scholar 

  18. S.A. Degterov, E. Jak, P.C. Hayes, and A.D. Pelton: Metall. Mater. Trans. B, 2001, vol. 32B, pp. 643–57.

    CAS  Google Scholar 

  19. E. Jak, S.A. Degterov, A.D. Pelton, and P.C. Hayes: Metall. Mater. Trans. B, 2001, vol. 32B, pp. 793–800.

    CAS  Google Scholar 

  20. E. Jak and P. Hayes: Can. Metal. Q., 2002, vol. 41 (2), pp. 163–74.

    CAS  Google Scholar 

  21. S.P. Matthew, G.R. McKean, R.L. Player, and K.E. Ramus: in Lead-Zinc ’90, T.S. Mackey and R.D. Prengaman, eds., TMS, Warrendale, PA, 1990, pp. 889–901.

    Google Scholar 

  22. H.-J. Siegmund: in Lead-Zinc 2000, J.E. Dutrizac, J.A. Gonzales, D.M. Henke, S.E. James, and A.H.-J. Siegmund, eds., Pittsburgh, PA, 2000, TMS, Warrendale, PA, 2000, pp. 55–116.

    Google Scholar 

  23. T. Lehner and R. Lindgren: in Zinc ’85, Mining and Metallurgical Institute of Japan, Tokyo, Japan, 1985, pp. 185–200.

    Google Scholar 

  24. C.D. Chapman and P.M. Cowx: Steel Times, 1991, June, pp. 301–02.

  25. N.J. Themelis, J.G. Peacey, and Q. Jiao: HH Kellogg Int. Symp., N.J. Themelis and P.F. Duby, eds., TMS, Warrendale, PA, 1991, pp. 331–46.

    Google Scholar 

  26. A.F.S. Schoukens, G.M. Denton, and R.T. Jones: 3rd Int. Symp. on Recycling of Metals and Engineered Materials, TMS, Warrendale, PA, 1995, pp. 857–68.

    Google Scholar 

  27. S. Eriksson: in Zinc ’85, Mining and Metallurgical Institute of Japan, Tokyo, Japan, 1985, pp. 827–40.

    Google Scholar 

  28. Y. Hara, N. Ishiwata, H. Itaya, and T. Matsumoto: Iron Steel Inst. Jpn., 2000, vol. 40(3), pp. 231–37.

    CAS  Google Scholar 

  29. R-Q. Li, J.G. Peacey, and P.J. Hancock: in Howard Warner Int. Symp. on Injection in Pyrometallurgy, M. Nilmani and T. Lehner, eds., Melbourne, 1996, TMS, Warrendale, PA, 1996, pp. 107–21.

    Google Scholar 

  30. A.W. Richards: Can. Met. Q., 1981, vol. 20 (2), pp. 145–51.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. PYROSEARCH, Pyrometallurgy Research Centre, School of Engineering, The University of Queensland, 4072, St. Lucia, Queensland, Australia

    Evgueni Jak (Research Director), Baojun Zhao (Research Fellow) & Peter C. Hayes (Director)

Authors
  1. Evgueni Jak
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Baojun Zhao
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Peter C. Hayes
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Jak, E., Zhao, B. & Hayes, P.C. Experimental study of phase equilibria in the “FeO”-ZnO-(CaO + SiO2) system with CaO/SiO2 weight ratios of 0.33, 0.93, and 1.2 in equilibrium with metallic iron. Metall Mater Trans B 33, 877–890 (2002). https://doi.org/10.1007/s11663-002-0070-x

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11663-002-0070-x

Keywords

Search

Navigation