Abstract
Titanium alloy, Ti-15V-3Cr-3Al-3Sn was nitrided at different temperatures with low pressure plasma with 100% nitrogen, and nitrogen diluted with hydrogen and argon. The nitrided layers were characterized for hardness, structure, and composition. Nitrided samples show weight gain that depended on temperature and duration of nitriding. EDS results show that intake of nitrogen is significant at temperatures above 750 °C. Hydrogen dilution increases intake of nitrogen. Samples nitrided with hydrogen dilution have lower surface roughness and higher nitrogen concentration. Depth profiling by XPS shows the formation of nitride in the near-surface region and also that nitrogen concentration in the interior of the nitrided layers is higher at higher temperatures. Micro Raman shows that formation of nitride takes place at higher temperatures. XRD shows that the nitrided layers consist predominantly of alpha Ti and Ti2N. This is reflected in the hardness increase and hardness profile in the nitrided samples. The low intake of nitrogen by the alloy is attributed to the low solubility of nitrogen in beta alloy and low diffusion coefficient of nitrogen. Reciprocating wear studies showed a lower coefficient of friction and lower wear loss for nitrided samples compared to that of substrate.
Similar content being viewed by others
References
R. Boyer, G. Welsch, and E.W. Collings, Materials Properties Handbook: Titanium Alloys, ASM International, Materials Park, 2003
C. Leyens and M. Peters, Titanium and Titanium Alloys: Fundamentals and Applications, Wiley-VCH, Germany, 2003
K.G. Budinski, Tribological Properties of Titanium Alloys, Wear, 1992, 151, p 203–217
S.M. Johns, T. Bell, M. Samandi, and G.A. Collins, Wear Resistance of Plasma Immersion Ion Implanted Ti6A14V, Surf. Coat. Technol., 1996, 85, p 7–14
H. Dong and T. Bell, Designer Surfaces for Titanium Components, Ind. Lubr. Tribol., 1998, 50(6), p 282–289
H. Dong and T. Bell, Ti-2003 Science and Technology, Proceedings of the 10th World Conference on Titanium: Volume-II, G. Lutjering and J. Albrecht, Eds., Wiley-VCH, Germany, 2004
X. Liu, P.K. Chu, and C. Ding, Surface Modification of Titanium, Titanium Alloys, and Related Materials for Biomedical Applications, Mater. Sci. Eng. R, 2004, 47, p 49–121
X. Qiu, J.R. Conrad, R.A. Dodd, and F.J. Worzala, Plasma Source Nitrogen Ion Implantation of Ti-6Al-4V, Metall. Trans. A, 1990, 21A, p 1663–1667
B.Y. Tang, P.K. Chu, S.Y. Wang, K.W. Chow, and X.F. Wang, Methane and Nitrogen Plasma Immersion Ion Implantation of Titanium Metal, Surf. Coat. Technol., 1998, 103-104, p 248–251
S.Y. Wang, P.K. Chu, B.Y. Tang, X.C. Zeng, Y.B. Chen, and X.F. Wang, Radio Frequency Plasma Nitriding and Nitrogen Plasma Immersion Ion Implantation of Ti6Al4V, Surf. Coat. Technol., 1997, 93, p 309–313
E.S. Metin and O.T. Inal, Microstructure and Microhardness Evaluations in Ion Nitrided Titanium, Mater. Sci. Eng. A, 1991, 145, p 65–77
C. Lugmair, R. Kullmer, A. Gebeshuber, C. Mitterer, M. Stoiber, H. Patrovsky, and M. Adley, Ti-2003 Science and Technology, Proceedings of the 10 th world conference on Titanium: Volume-II, G. Lutjering and J. Albrecht, Eds., Wiley-VCH, Germany, 2004
U. Huchel and S. Stramke, Ti-2003 Science and Technology, Proceedings of the 10th world conference on Titanium: Volume-II, G. Lutjering and J. Albrecht, Eds., Wiley-VCH, Germany, 2004
K.N. Strafford and J.M. Towell, The Interaction of Titanium and Titanium Alloys with Nitrogen at Elevated Temperatures. I. The Kinetics and Mechanism of the Titanium-Nitrogen Reaction, Oxid. Met., 1976, 10, p 41–67
K.N. Strafford and J.M. Towell, The Interaction of Titanium and Titanium Alloys with Nitrogen at Elevated Temperatures. II. The Nitridation Behaviour of Alloys Containing 5 wt.% Percent of Aluminium and Chromium, Oxid. Met., 1976, 10, p 69–84
E. Metin and O.T. Inal, Kinetics of Layer Growth and Multiphase Diffusion in Ion Nitrided Titanium, Metall. Trans. A, 1989, 20A, p 1819–1832
N.R. McDonald and G.R. Wallwork, The Reaction of Nitrogen with Titanium Between 800 and 1200°C, Oxid. Met., 1970, 2-3, p 263–283
A. Zhecheva, W. Sha, S. Malinov, and A. Long, Enhancing the Microstructure and Properties of Titanium Alloys Through Nitriding and Other Surface Engineering Methods, Surf. Coat. Technol., 2005, 200, p 2192–2220
A. Zhecheva, S. Malinov, and W. Sha, Titanium Alloys After Surface Gas Nitriding, Surf. Coat. Technol., 2006, 201, p 247–2467
W. Sha and S. Malinov, Titanium Alloys: Modelling of Microstructure, Properties and Applications, Woodhead Publishing Ltd., Cambridge, 2009
Prateek Kumar, P. Dilli Babu, L. Mohan, C. Anandan, and V.K. William Grips, Wear and Corrosion Behavior of Zr-Doped DLC on Ti-13Zr-13Nb Biomedical Alloy, J. Mater. Eng. Perform., 2012, doi: 10.1007/s11665-012-0230-3
S.L.R. da Silva, L.O. Kerber, L. Amaral, and C.A. dos Santos, X-Ray Diffraction Measurements of Plasma Nitrided Ti6Al4V, Surf. Coat. Technol., 1999, 116-119, p 342–346
F.M. El-Hossary, N.Z. Negm, S.M. Khalil, and M. Raaif, Surface Modification of Titanium by Radio Frequency Plasma Nitriding, Thin Solid films, 2006, 497, p 196–202
M.A.Z. Vasconcellos, R. Hinrichs, C.S. Javorsky, G. Giuriatti, and J.A.T. Borges da Costa, Micro-Raman Characterization of Plasma Nitrided Ti6Al4V-ELI, Surf. Coat. Technol., 2007, 202, p 275–279
C.P. Constable, J. Yarwood, and W.D. Munz, Raman Microscopic Studies of PVD Hard Coatings, Surf. Coat. Technol., 1999, 116-119, p 155–159
R. Chowdhury, R.D. Vispute, K. Jagannadham, and J. Narayan, Characteristics of Titanium Nitride Films Grown by Pulsed Laser Deposition, J. Mater. Res, 1996, 11(6), p 1458
Y.H. Cheng, B.K. Tay, S.P. Lau, H. Kupfer, and F. Richter, Substrate Bias Dependence of Raman Spectra for TiN Films Deposited by Filtered Cathodic Vacuum Arc, J Appl. Phys., 2002, 92(4), p 1845
N.C. Saha and H.G. Tompkins, Titanium Nitride Oxidation Chemistry: An X-Ray Photoelectron Spectroscopy Study, J. Appl. Phys., 1992, 72, p 3072
A. Gicquel, N. Laidani, P. Saillard, and J. Amouroux, Plasma and Nitrides: Application to the Nitriding of Titanium, Pure Appl. Chem., 1990, 62-69, p 1743–1750
E. Galvanetto, F.P. Galliano, F. Borgioli, U. Bardi, and A. Lavacchi, XRD and XPS Study on Reactive Plasma Sprayed Ti-Ti Nitride Coatings, Thin Solid Films, 2001, 384, p 223–229
Acknowledgments
The study was carried under the 11th five-year plan projects on enhancement of knowledge base in aerospace materials project SIP-SED-05 funded by CSIR-NAL. The authors would like to thank Director, NAL for permission to publish this research; and Head, SED for constant encouragement. The authors would like to thank Mr. Siju, Mr. NT. Manikandanath, Mr. Praveen, and Mr. Muniprakash for various characterizations.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Anandan, C., Babu, P.D. & Mohan, L. Effect of Gas Composition on Nitriding and Wear Behavior of Nitrided Titanium Alloy Ti-15V-3Cr-3Al-3Sn. J. of Materi Eng and Perform 22, 2623–2633 (2013). https://doi.org/10.1007/s11665-013-0540-0
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11665-013-0540-0