Skip to main content
Log in

The Effect of Two Amine-Based Corrosion Inhibitors in Improving the Corrosion Resistance of Carbon Steel in Sea Water

  • Published:
Journal of Materials Engineering and Performance Aims and scope Submit manuscript

Abstract

This study investigates the effect of two amine-based corrosion inhibitors in reducing the corrosion rate (CR) of 1018 carbon steel in formulated sea water. For discussion purposes, the two inhibitors are named Inhibitor A (belongs to the alkyl pyridine benzyl chloride quaternary family of inhibitors) and Inhibitor B (belongs to the alkyl amines family of inhibitors). The two inhibitors are routinely considered for applications by Saudi Aramco, the world’s largest oil producing and processing company, for reducing its corrosion problems in carbon steel pipelines carrying oil and gas. The experimental apparatus was a circulating flow loop system inside an autoclave. The experimental work was performed at pH 8.2, 55 °C, and 1000 rpm. The inhibitors were evaluated at three different concentrations of 5, 10, and 15 ppm. The CR was determined using the weight loss method and electrochemical methods such potentiodynamic sweep and linear polarization resistance. The experimental results indicate that Inhibitor B reduced the CR more than that of Inhibitor A.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  1. M. Salasi, T. Shahrabi, and E. Roayaei, Effect of Inhibitor Concentration and Hydrodynamic Conditions on the Inhibitive Behaviour of Combinations of Sodium Silicate and HEDP for Corrosion Control in Carbon Steel Water Transmission Pipes, Anti Corros. Methods Mater., 2007, 54, p 82–92

    Article  Google Scholar 

  2. K. Bılkova and E. Gulbrandsen, Kinetic and Mechanistic Study of CO2 Corrosion Inhibition by Cetyl Trimethyl Ammonium Bromide, Electrochim. Acta, 2008, 53, p 5423–5433

    Article  Google Scholar 

  3. M.A. Deyab and S.S. Abd El-Rehim, Inhibitory Effect of Tungstate, Molybdate and Nitrite Ions on the Carbon Steel Pitting Corrosion in Alkaline Formation Water Containing Cl Ion, Electrochim. Acta, 2007, 53, p 1754–1760

    Article  Google Scholar 

  4. B. Ramesh Babu and K. Thangavel, The Effect of Isomers of Some Organic Compounds as Inhibitors for the Corrosion of Carbon Steel in Sulfuric Acid, Anti Corros. Methods Mater., 2005, 52, p 219–225

    Article  Google Scholar 

  5. E.E. Oguzie, A.I. Onuchukwu, P.C. Okafor, and E.E. Ebenso, Corrosion Inhibition and Adsorption Behaviour of Ocimum basilicum Extract on Aluminum, Pigment Resin Technol., 2006, 35, p 63

    Article  Google Scholar 

  6. H. Amar, T. Braisaz, D. Villemin, and B. Moreau, Thiomorpholin-4-ylmethyl-phosphonic Acid and Morpholin-4-methyl-phosphonic acid as Corrosion Inhibitors for Carbon Steel in Natural Seawater, Mater. Chem. Phys., 2008, 110, p 1–6

    Article  Google Scholar 

  7. A.A. Al-Sarawy, A.S. Fouda, and W.A. El-Dein, Some Thiazole Derivatives as Corrosion Inhibitors for Carbon Steel in Acidic Medium, Desalination, 2008, 229, p 279–293

    Article  Google Scholar 

  8. L. Herrag, B. Hammouti, S. Elkadiri, B. El Bali, M. Lachkar, and R. Ouarsal, Inhibition of Steel Corrosion in HCl Media by Phosphite Compound, Pigm. Resin Technol., 2008, 37, p 167–172

    Article  Google Scholar 

  9. M.S. Morad, The Inhibitory Effect of Bis-2,6-(3,5 Dimethylpyrazolyl) Pyridine on the Corrosion Behavior of Mild Steel in HCl Solution, Mater. Chem. Phys., 2008, 109, p 492–499

    Article  Google Scholar 

  10. P.H. Suegama, H.G. de Melo, A.A.C. Recco, A.P. Tschiptschin, and I.V. Aoki, Corrosion Behavior of Carbon Steel Protected with Single and Bi-Layer of Silane Films Filled with Silica Nanoparticles, Surf. Coat. Technol., 2008, 202, p 2850–2858

    Article  Google Scholar 

  11. J.Z. Ai, X.P. Guo, and Z.Y. Chen, The Adsorption Behavior and Corrosion Inhibition Mechanism of Anionic Inhibitor on Galvanic Electrode in 1% NaCl Solution, Appl. Surf. Sci., 2006, 253, p 683–688

    Article  Google Scholar 

  12. M. Sahin, G. Gece, F. Karcı, and S. Bilgic, Experimental and Theoretical Study of the Effect of Some Heterocyclic Compounds on the Corrosion of Low Carbon Steel in 3.5% NaCl Medium, J. Appl. Electrochem., 2008, 38, p 809–815

    Article  Google Scholar 

  13. G. Gao, C.H. Liang, and H. Wang, Synthesis of Tertiary Amines and Their Inhibitive Performance on Carbon Steel Corrosion, Corros. Sci., 2007, 49, p 1833–1846

    Article  Google Scholar 

  14. R. Tems and A.M. Al Zahrani, Cost of Corrosion in Oil Production and Refining, Saudi Aramco, J. Technol., 2006, p 2–14.

  15. R.O. Rihan and S. Nesic, Erosion-Corrosion of Mild Steel in Hot Caustic, Part I—Pure NaOH Solution, Corros. Sci., 2006, 48(9), p 2633–2659

    Article  Google Scholar 

  16. A.U. Malik, S. Ahmad, I. Andijani, and S. Al-Fouzan, Corrosion Behavior of Steels in Gulf Seawater Environment, Desalination, 1999, 123, p 205–213

    Article  Google Scholar 

  17. L.B. Zhao, R. Huang, M.X. Bai, D.Y. Wu, and Z.Q. Tian, Effect of Aromatic Amine–Metal Interaction on Surface Vibrational Raman Spectroscopy of Adsorbed Molecules Investigated by Density Functional Theory, J. Phys. Chem. C, 2011, 115, p 4174–4183

    Article  Google Scholar 

  18. G. Banerjee and S.N. Malhotra, Contribution to Adsorption of Aromatic Amines on Mild Steel Surface from HCl Solutions by Impedance, UV, and Raman Spectroscopy, Corrosion, 1992, 48, p 10–15

    Article  Google Scholar 

  19. N. Goudarzi, M. Reza Peikari, H. Reza Zahiri, and R. Mousavi, Adsorption and Corrosion Inhibition Behavior of Stainless Steel 316 by Aliphatic Amine Compounds in Acidic Solution, Arch. Metall. Mater., 2012, 57, p 845–851

    Google Scholar 

  20. K. Bouhrira, F. Ouahiba, D. Zerouali, B. Hammouti, M. Zertoubi, and N. Benchat, The Inhibitive Effect of 2-Phenyl-3-Nitroso-Imidazo [1,2-a] Pyridine on the Corrosion of Steel in 0.5 M HCl Acid Solution, J. Chem., 2010, 7, p S35–S42

    Google Scholar 

  21. ASTM Standards, Annual Book of ASTM Standards, Section 3, Vol. 03.02, ASTM International, West Conshohocken, PA, 1998, p 20

  22. R.O. Rihan and S. Nesic, Erosion-Corrosion of Mild Steel in Hot Caustic, Part I—Pure NaOH Solution, Corros. Sci., 2006, 48, p 2633–2659

    Article  Google Scholar 

  23. R.O. Rihan and S. Nesic, Erosion-Corrosion of Mild Steel in Hot Caustic, Part II—The Effect of Acid Cleaning, Corros. Sci., 2006, 48, p 2660–2675

    Article  Google Scholar 

  24. R.O. Rihan, Electrochemical Corrosion Behavior of X52 and X60 Steels in Carbon Dioxide Containing Saltwater Solution, Mater. Res., 2013, 16, p 227–236

    Article  Google Scholar 

Download references

Acknowledgment

The authors would like to acknowledge the Center for Engineering Research at King Fahd University of Petroleum & Minerals (KFUPM) for conducting the research, and Saudi Aramco for supporting this research. The authors would like to acknowledge Dr. Blair Bremberg at the Research Institute-KFUPM for editing the manuscript.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Rihan Rihan.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Rihan, R., Shawabkeh, R. & Al-Bakr, N. The Effect of Two Amine-Based Corrosion Inhibitors in Improving the Corrosion Resistance of Carbon Steel in Sea Water. J. of Materi Eng and Perform 23, 693–699 (2014). https://doi.org/10.1007/s11665-013-0790-x

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11665-013-0790-x

Keywords

Navigation