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Vacuum Brazing of WC-8Co Cemented Carbides to Carbon Steel Using Pure Cu and Ag-28Cu as Filler Metal

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Abstract

The wetting and spreading behavior of commercial pure Cu and Ag-28Cu alloy on WC-8Co cemented carbide were investigated by the sessile drop technique. The contact angle of both systems obviously decreases with moderately increasing the wetting temperature. Vacuum brazing of the WC-8Co cemented carbide to SAE1045 steel using the pure Cu or Ag-28Cu as filler metal was further carried out based on the wetting results. The interfacial interactions and joint mechanical behavior involving microhardness, shear strength and fracture were analyzed and discussed. An obvious Fe-Cu-Co transition layer is detected at the WC-8Co/Cu interface, while no obvious reaction layer is observed at the whole WC-8Co/Ag-28Cu/SAE1045 brazing seam. The microhardness values of the two interlayers and the steel substrate near the two interlayers increase more or less, while those of WC-8Co cemented carbide substrates adjacent to the two interlayers decrease. The WC-8Co/SAE1045 joints using pure Cu and Ag-28Cu alloy as filler metals obtain average shear strength values of about 172 and 136 MPa, and both of the joint fractures occur in the interlayers.

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References

  1. H.O. Andren, Microstructures of Cemented Carbides, Mater. Des., 2001, 22(6), p 491–498

    Article  Google Scholar 

  2. K. Bonny, P. De Baets, Y. Perez, J. Vleugels, and B. Lauwers, Friction and Wear Characteristics of WC-Co Cemented Carbides in Dry Reciprocating Sliding Contact, Wear, 2010, 268(11), p 1504–1517

    Article  Google Scholar 

  3. A.M. Soleimanpour, P. Abachi, and A. Simchi, Microstructure and Mechanical Properties of WC–10Co Cemented Carbide Containing VC or (Ta, Nb)C and Fracture Toughness Evaluation Using Different Models, Int. J. Refract. Met. Hard. Mater., 2012, 31, p 141–146

    Article  Google Scholar 

  4. A.H. Li, J. Zhao, D. Wang, X.L. Gao, and H.W. Tang, Three-Point Bending Fatigue Behavior of WC-Co Cemented Carbides, Mater. Des., 2013, 45, p 271–278

    Article  Google Scholar 

  5. T.T. Shen, D.H. Xiao, X.Q. Ou, M. Song, Y.H. He, N. Lin, and D.F. Zhang, Effects of LaB6 Addition on the Microstructure and Mechanical Properties of Ultrafine Grained WC–10Co Alloys, J. Alloys Compd., 2011, 509(4), p 1236–1243

    Article  Google Scholar 

  6. H.S. Chen, K.Q. Feng, S.F. Wei, J. Xiong, Z.X. Guo, and H. Wang, Microstructure and Properties of WC-Co/3Cr13 Joints Brazed Using Ni Electroplated Interlayer, Int. J. Refract. Met. Hard. Mater., 2012, 33, p 70–74

    Article  Google Scholar 

  7. M. Uzkut, N.S. Sinan Koksal, and B.S. Unlu, The Determination of Element Diffusion in Connecting SAE 1040/WC Material by Brazing, J. Mater. Process. Technol., 2005, 169(3), p 409–413

    Article  Google Scholar 

  8. Q.Y. Zhai, C.K. Liang, J. Cheng, J.F. Xu, J.P. Liu, and Q.S. Xue, Vacuum Brazing of 25Cr3MoA/YG6 Using Cu-Based Microcrystalline Brazing Alloy, Acta Metall. Sin., 2008, 44, p 1136–1140

    Google Scholar 

  9. S.A.A. Akbari Mousavi, P. Sherafati, and M.M. Hoseinion, Investigation on Wettability and Metallurgical and Mechanical Properties of Cemented Carbide and Steel Brazed Joint, Adv. Mater. Res., 2012, 445, p 759–764

    Google Scholar 

  10. S. Yaoita, T. Watanabe, and T. Sasaki, Effects of Ni and Co Elements in Filler Metals in Ag Brazing of Cemented Carbide, Mater. Res. Innov., 2013, 17, p 142–147

    Article  Google Scholar 

  11. C. Jiang, H. Chen, Q.Y. Wang, and Y.X. Li, Effect of Brazing Temperature and Holding Time on Joint Properties of Induction Brazed WC-Co/Carbon Steel Using Ag-based Alloy, J. Mater. Process. Technol., 2016, 229, p 562–569

    Article  Google Scholar 

  12. W.B. Lee, B.D. Kwon, and S.B. Jung, Effect of Bonding Time on Joint Properties of Vacuum Brazed WC-Co Hard Metal/Carbon Steel Using Stacked Cu and Ni Alloy as Insert Metal, Mater. Sci. Technol., 2004, 20(11), p 1474–1478

    Article  Google Scholar 

  13. W.B. Lee, B.D. Kwon, and S.B. Jung, Effects of Cr3C2 on the Microstructure and Mechanical Properties of the Brazed Joints Between WC-Co and Carbon Steel, Int. J. Refract. Met. Hard. Mater., 2006, 24(3), p 215–221

    Article  Google Scholar 

  14. T. Iamboliev, S. Valkanov, and S. Atanasova, Microstructure Embrittlement of Hard Metal-Steel Joint Obtained under Induction Heating Diffusion Bonding, Int. J. Refract. Met. Hard. Mater., 2013, 37, p 90–97

    Article  Google Scholar 

  15. K.Q. Feng, H.S. Chen, J. Xiong, and Z.X. Guo, Investigation on Diffusion Bonding of Functionally Graded WC-Co/Ni Composite and Stainless Steel, Mater. Des., 2013, 46, p 622–626

    Article  Google Scholar 

  16. M.I. Barrena, J.M. Gomez de Salazar, and L. Matesanz, Ni–Cu Alloy for Diffusion Bonding Cermet/Steel in Air, Mater. Lett., 2009, 63(24), p 2142–2145

    Article  Google Scholar 

  17. P.Q. Xu, J.W. Ren, P.L. Zhang, H.Y. Gong, and S.L. Yang, Analysis of Formation and Interfacial WC Dissolution Behavior of WC-Co/Invar Laser-TIG Welded Joints, J. Mater. Eng. Perform., 2013, 22(2), p 613–623

    Article  Google Scholar 

  18. D.R. Zhou, H.C. Cui, P.Q. Xu, and F.G. Lu, Tungsten Carbide Grain Size Computation for WC-Co Dissimilar Welds, J. Mater. Eng. Perform., 2016, 25(6), p 2500–2510

    Article  Google Scholar 

  19. Y.G. Guo, B.X. Gao, G.W. Liu, T.T. Zhou, and G.J. Qiao, Effect of Temperature on the Microstructure and Bonding Strength of Partial Transient Liquid Phase Bonded WC-Co/40Cr Joints Using Ti/Ni/Ti Interlayers, Int. J. Refract. Met. Hard. Mater., 2015, 51, p 250–257

    Article  Google Scholar 

  20. P. Shen, X.H. Zheng, H.J. Liu, and Q.C. Jiang, Wetting of WC by a Zr-base Metallic Glass-Forming Alloy, Mater. Chem. Phys., 2013, 139(2), p 646–653

    Article  Google Scholar 

  21. Y.W. Zhao, Y.J. Wang, Y. Zhou, and P. Shen, Reactive Wetting and Infiltration of Polycrystalline WC by Molten Zr2Cu Alloy, Scr. Mater., 2011, 64(3), p 229–232

    Article  Google Scholar 

  22. G.W. Liu, F. Valenza, M.L. Muolo, and A. Passerone, SiC/SiC and SiC/Kovar Joining by Ni–Si and Mo Interlayers, J. Mater. Sci., 2010, 45(16), p 4299–4307

    Article  Google Scholar 

  23. H. Baker, and H. Okamoto, ASM Hand-Book, Volume 3 Alloy Phase Diagrams, ASM International, The Materials Information Society, Materials Park, OH, 1992

  24. V. Raghvan, Co-Cu-Fe (Cobalt-Copper-Iron), J. Phase Equilib. Diff., 2008, 29(6), p 518–519

    Article  Google Scholar 

  25. C.P. Wang, X.J. Liu, I. Ohnuma, R. Kainuma, and K. Ishida, Phase Equilibria in Fe–Cu–X (X: Co, Cr, Si, V) Ternary Systems, J. Phase Equilib., 2002, 23(3), p 236–245

    Article  Google Scholar 

  26. M.I. Barrena, J.M. Gomez de Salazar, and L. Matesanz, Interfacial Microstructure and Mechanical Strength of WC-Co/90MnCrV8 Cold Work Tool Steel Diffusion Bonded Joint with Cu/Ni Electroplated Interlayer, Mater. Des., 2010, 31, p 3389–3394

    Article  Google Scholar 

  27. S.H. Hashemian Rahaghi, R. Poursalehi, and R. Miresmaeili, Optical Properties of Ag-Cu Alloy Nanoparticles Synthesized by DC Arc Discharge in Liquid, Procedia Mater. Sci., 2015, 11, p 738–742

    Article  Google Scholar 

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Acknowledgments

This work is supported by the National Natural Science Foundation of China (51572112), the Natural Science Foundation of Jiangsu Province (BK20151340), the Six Talent Peaks Project of Jiangsu Province (2014-XCL-002), the Postdoctoral Science Foundation of China (2014M551512), the Innovation/Entrepreneurship Program of Jiangsu Province ([2013]477 and [2015]26), the Qing Lan Project ([2016]15), and the Research and Innovation Project for College Graduates of Jiangsu Province (KYLX15_1058).

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Correspondence to G. W. Liu or G. J. Qiao.

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Zhang, X.Z., Liu, G.W., Tao, J.N. et al. Vacuum Brazing of WC-8Co Cemented Carbides to Carbon Steel Using Pure Cu and Ag-28Cu as Filler Metal. J. of Materi Eng and Perform 26, 488–494 (2017). https://doi.org/10.1007/s11665-016-2424-6

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  • DOI: https://doi.org/10.1007/s11665-016-2424-6

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