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Nanoengineered Hypereutectoid Steel with Superior Hardness and Wear Resistance

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Abstract

Hypereutectoid SAE 52100 steel is extensively used in bearing applications. Microstructure modification in terms of dislocation martensite and carbide refinement was achieved for SAE 52100 steel through a simple duplex heat treatment. Refinement of prior austenite grains to less than 5 μm resulted in the conversion of conventional high-carbon twinned martensite to dislocation martensite. The concurrent refinement of austenite grains and carbide precipitates was accomplished by high-temperature austenitization followed by low-temperature tempering. This resulted in nanoscale nonstoichiometric ε-carbides within a heavily twinned martensitic structure. These nanoscale carbides acted as grain boundary pinning agents after their transformation to θ-carbides during the final austenitization process. The resulting microstructure was characterized by a fine dispersion of θ-carbides within dislocation martensite and showed roughly 24% increase in tensile strength and 30% better wear resistance compared to conventional structure.

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References

  1. H.K.D.H. Bhadeshia, Steels for Bearings, Prog. Mater Sci., 2012, 57(2), p 268–435

    Article  Google Scholar 

  2. J. Chakraborty, P.P. Chattopadhyay, D. Bhattacharjee, and I. Manna, Microstructural Refinement of Bainite and Martensite for Enhanced Strength and Toughness in High-Carbon Low-Alloy Steel, Metall. Mater. Trans. A Phys. Metall. Mater. Sci., 2010, 41(11), p 2871–2879

    Article  Google Scholar 

  3. G.E. Totten, Steel Heat Treatment, Taylor & Francis Group, Boca Raton, 2006, p 820

    Google Scholar 

  4. Y. Wang, F. Zhang, Z. Yang, B. Lv, and C. Zheng, Rolling Contact Fatigue Performances of Carburized And High-C Nanostructured Bainitic Steels, Materials (Basel), 2016, 9(12), p 1–12

    Article  Google Scholar 

  5. F. Khodabakhshi, M. Haghshenas, and B. Koohbor, Hardness–Strength Relationships in Fine and Ultra-Fine Grained Metals Processed Through Constrained Groove Pressing, Mater. Sci. Eng. A, 2015, 636, p 331–339

    Article  Google Scholar 

  6. T.T. Huang, R.B. Gou, W.J. Dan, and W.G. Zhang, Strain-Hardening Behaviors of Dual Phase Steels with Microstructure Features, Mater. Sci. Eng. A, 2016, 672(672), p 88–97

    Article  Google Scholar 

  7. J. Zhang, H. Di, Y. Deng, and R.D.K. Misra, Effect of Martensite Morphology and Volume Fraction on Strain Hardening and Fracture Behavior of Martensite–Ferrite Dual Phase Steel, Mater. Sci. Eng. A, 2015, 627, p 230–240

    Article  Google Scholar 

  8. M. Calcagnotto, Y. Adachi, D. Ponge, and D. Raabe, Deformation and Fracture Mechanisms in Fine- and Ultrafine-Grained Ferrite/Martensite Dual-Phase Steels and the Effect of Aging, Acta Mater., 2011, 59(2), p 658–670

    Article  Google Scholar 

  9. C.A. Stickels, Carbide Refining Heat Treatments for 52100 Bearing Steel, Metall. Trans., 1974, 5(4), p 865–874

    Article  Google Scholar 

  10. R.J. Kar, R.M. Horn, and V.F. Zackay, The Effect of Heat Treatment on Microstructure and Mechanical Properties in 52100 Steel, Metall. Trans. A, 1979, 10(November), p 1711–1717

    Article  Google Scholar 

  11. N. Luzginova, L. Zhao, and J. Sietsma, Evolution and Thermal Stability of Retained Austenite in SAE 52100 Bainitic Steel, Mater. Sci. Eng. A, 2007, 448(1–2), p 104–110

    Article  Google Scholar 

  12. A.T.W. Barrow, J.H. Kang, and P.E.J. Rivera-Díaz-Del-Castillo, The → η → θ Transition in 100Cr6 and Its Effect on Mechanical Properties, Acta Mater., 2012, 60(6–7), p 2805–2815

    Article  Google Scholar 

  13. J.J. Sun, Y.N. Liu, Y.T. Zhu, F.L. Lian, H.J. Liu, T. Jiang, S.W. Guo, W.Q. Liu, and X.B. Ren, Super-Strong Dislocation-Structured High-Carbon Martensite Steel, Sci. Rep., 2017, 7(1), p 1–7

    Article  Google Scholar 

  14. N.V. Luzginova, L. Zhao, and J. Sietsma, The Cementite Spheroidization Process in High-Carbon Steels with Different Chromium Contents, Metall. Mater. Trans., 2008, 39, p 513–521

    Article  Google Scholar 

  15. Y. Lu, H. Yu, and R.D. Sisson, The Effect of Carbon Content on the c/a Ratio of As-Quenched Martensite in Fe–C Alloys, Mater. Sci. Eng. A, 2017, 700(April), p 592–597

    Article  Google Scholar 

  16. D.E. Jiang and E.A. Carter, Carbon Dissolution and Diffusion in Ferrite and Austenite from First Principles, Phys. Rev. B Condens. Matter Mater. Phys., 2003, 67(21), p 1–11

    Article  Google Scholar 

  17. R. Hossain, F. Pahlevani, M.Z. Quadir, and V. Sahajwalla, Stability of Retained Austenite in High Carbon Steel Under Compressive Stress: An Investigation from Macro to Nano Scale, Sci. Rep., 2016, 6(October), p 1–11

    Google Scholar 

  18. X. Qiao, L. Han, W. Zhang, and J. Gu, Thermal Stability of Retained Austenite in High-Carbon Steels During Cryogenic and Tempering Treatments, ISIJ Int., 2016, 56(1), p 140–147

    Article  Google Scholar 

  19. J.M. Beswick, The Effect of Chromium in High Carbon Bearing Steels, Metall. Mater. Trans. A, 1987, 18, p 1897–1906

    Article  Google Scholar 

  20. S. Ghosh, S. Mula, and D. Kumar Mondal, Development of Ultrahigh Strength Cast-Grade Microalloyed Steel by Simple Innovative Heat Treatment Techniques for Industrial Applications, Mater. Sci. Eng. A, 2017, 700, p 67–680

    Article  Google Scholar 

  21. X.T. Deng, T.L. Fu, Z.D. Wang, R.D.K. Misra, and G.D. Wang, Epsilon Carbide Precipitation and Wear Behaviour of Low Alloy Wear Resistant Steels, Mater. Sci. Technol. (United Kingdom), 2016, 32(4), p 320–327

    Article  Google Scholar 

  22. W. Song, J. Von Appen, P. Choi, R. Dronskowski, D. Raabe, and W. Bleck, Atomic-Scale Investigation of ε and θ Precipitates in Bainite in 100Cr6 Bearing Steel by Atom Probe Tomography and Ab Initio Calculations, Acta Mater., 2013, 61(20), p 7582–7590

    Article  Google Scholar 

  23. A.T.W. Barrow and P.E.J. Rivera-Díaz-Del-Castillo, Nanoprecipitation in Bearing Steels, Acta Mater., 2011, 59(19), p 7155–7167

    Article  Google Scholar 

  24. J. Weissmüller, Alloy Effects in Nanostructures, Nanostruct. Mater., 1993, 3(1–6), p 261–272

    Article  Google Scholar 

  25. C.H. Young and H.K.D.H. Bhadeshia, Strength of Mixtures of Bainite and Martensite, Mater. Sci. Technol., 1994, 10(3), p 209–214

    Article  Google Scholar 

  26. S. Queyreau, G. Monnet, and B. Devincre, Orowan Strengthening and Forest Hardening Superposition Examined by Dislocation Dynamics Simulations, Acta Mater., 2010, 58(17), p 5586–5595

    Article  Google Scholar 

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Acknowledgments

The authors thank the Materials Research Facility at University of North Texas for access to the characterization equipment used in this study.

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Author notes

  1. Aditya V. Ayyagari

    Present address: Center for Nanoscale Materials, Argonne National Laboratory, Lemont, IL, 60439, USA

Authors and Affiliations

  1. Department of Materials Science and Engineering, University of North Texas, Denton, TX, 76203, USA

    Riyadh Salloom, Aditya V. Ayyagari & Sundeep Mukherjee

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  1. Riyadh Salloom
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  2. Aditya V. Ayyagari
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  3. Sundeep Mukherjee
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Correspondence to Sundeep Mukherjee.

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Salloom, R., Ayyagari, A.V. & Mukherjee, S. Nanoengineered Hypereutectoid Steel with Superior Hardness and Wear Resistance. J. of Materi Eng and Perform 28, 2202–2211 (2019). https://doi.org/10.1007/s11665-019-03995-3

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  • DOI: https://doi.org/10.1007/s11665-019-03995-3

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