Abstract
Recent developments in light metal complex hydrides show that there is a potential for hydrogen storage using these hydrides in fuel cells for on-board vehicular and other applications. The search for new alloys promises to have practical significance with the realization that hydrogen as a fuel holds the key to filling energy needs and solving environmental problems. This review presents the U.S. Department of Energy FreedomCAR goals for hydrogen storage, storage capacities of important hydrides, and current developments in light-metal complex hydrides.
Similar content being viewed by others
References
www.eia.doe.gov/oiaf/1605/ggccebro/chapter1.html.
L. Schlapbach and A. Züttel, Nature, 414 (2001), p. 353.
A. Züttel, Mater. Today, (2003), p. 24.
B. Johnston, M.C. Mayo, and A. Khare, Technovation, 25 (2005), p. 569.
ww.gm.com/company/gmability/adv_tech/images/fact_sheets/hydrogen3.pdf.
www.bmwworld.com/hydrogen.
www.daimlerchrysler.com/dccom (search: hydrogen).
http://world.honda.com/FuelCell.
www.toyota.co.jp/en/tech/environment/fchv.
www.h2cars.biz.
H. Buchener and R. Povel, Int. J. Hydrogen Energy, 7 (1982), p. 259.
www.eere.energy.gov/vehiclesandfuels/about/partnership s/freedomcar/index.shtml.
G. Thomas (Presentation at the IPHE International Hydrogen Storage Conference, Lucca, Italy, 19–22 June 2005).
Y. Fukal, The Metal-Hydrogen System—Basic Bulk Properties (Berlin: Springer-Verlag, 1993).
L. Schlapbach, editor, Topics in Appl, Phys. Vol. 63: Hydrogen in Intemetallic Compounds I (Berlin: Springer, 1988).
R. Bowman, J. Alloys Compd., 356–357 (2003), p. 789.
www.panasonic.com/industrial/battery/oem/chem/nicmet.
M. Coleman et al., “Zirconium Iron Disproportionation during Hydriding Reactions in Nuclear Gettering Operation”, Adv. Mater. Energy Conv. II ed. D. Chandra, R.G. Bautista, and L. Schlapbach (Warrendale, PA, TMS, 2004), pp. 429–435.
F.E. Lynch, J. Less-Common Metals, 174 (1–2) (1991), pp. 943–958.
W.M. Mueller, J.P. Blackledge, and G.G. Libowitz, Metal Hydrides (New York: Academic, 1968).
L. Schlapbach, Topics in Appl. Phys., Vol. 63: Hydrogen in Intermetallic Compounds I: Electronic, Thermodynamics, and Crystallographic Properties, Preparation (Berlin: Springer Verlag 1988).
G. Sandrock, J. Alloys Compd., 293–295 (1999), p. 877.
K. Yvon, Chimia, 52 (10) (1998), p. 613.
DOE Hydrogen Program Annual Report (Washington, D.C.: U.S. DOE, 2004), pp. 195–214.
B. Bogdanovic and M. Schwickardi, J. Alloys Comp., 253-254 (1997), p. 1.
G. Sandrock et al., Appl. Phys. A, 80, (2005), pp. 687–690.
G. Sandrock and G. Thomas, Appl. Phys. A. 72, (2001), p. 153.
W. Luo and E. Ronnebro, J. Alloys Compd., 404–406 (2005), p. 392.
S.W. Lambert et al., J. Alloys Compd., 187 (1) (1992), p. 113.
D. Chandra et al., J. Alloys Compd., 199 (1–2) (1993), pp. 93–100.
A. Percheron-Guegan, C. Lartigue, and J.C. Archard, J. Less-Common Metals, 109 (1985), p. 287.
A. Sharma, “Effect of Thermal Cycling and Cold-Work on V0.995 C0.005 Hydrides” (M.S. Thesis, University of Nevada, Reno, NV, 1992).
Y. Nakamura, R.C. Bowman Jr., and E. Akiba, J. Alloys Compd., 373 (2004), p. 183.
B. Bogdanovic et al., J. Alloys Compd., 302 (2000), p. 36.
G.J. Thomas et al., J. Alloys Compd., (330–332) (2002), p. 702.
C.M. Jensen et al., Int. J. Hydrogen Energy, 24 (1999), p. 461.
K.J. Gross, G. Sandrock, and G.J. Thomas, J. Alloys Compd., 330–332 (2002), p. 691.
K.J. Gross, G.J. Thomas, and C.M. Jensen, J. Alloys Compd., 330–332 (2002), p. 683.
G. Sandrock, K. Gross, and G. Thomas, J. Alloys Compd., 339 (2002), p. 299.
V.P. Balema and L. Balema, Phys. Chem. Chem. Phys., 7 (2005), p. 1310.
R.T. Walters and J.H. Scogin, J. Alloys Compd., 379 (2004), p. 135.
H.W. Brinks et al., J. Alloys Compd., 376 (2004), p. 215.
R.A. Zidan et al., J. Alloys Compd., 285 (1999), p. 119.
A. Zaluska, L. Zaluski, and J.O. Ström-Olsen, J. Alloys Compd., 290 (1999), p. 71.
A. Zaluska, L. Zaluski, and J.O. Ström-Olsen, J. Alloys Compd., 298 (2000), p. 125.
B. Bogdanovic et al., J. Alloys Compd., 350 (2003), p. 246.
W. Grochala and P.P. Edwards, Chem. Rev., 104 (2004), p. 1283.
H.W. Brinks et al., J. Alloys Compd., 351 (2003), p. 222.
J. Chen et al., J. Phys. Chem. B, 105 (2001), p. 11214.
D. Blanchard et al., Mater. Sci. Eng. B, 108 (2004), p. 54.
M. Resan et al., Int. J. Hydrogen Energy, 30 (2005), p. 1417.
A. Andreasen, T. Vegge, A.S. Pedersen, J. Solid State Chemistry, 178 (2005), pp. 3672.
G. Sandrock et al., J. Alloys Compd., 330–332 (2002), p. 696.
M. Fichtner, O. Fuhr, and O. Kircher, J. Alloys Compd., 356–357 (2003), p. 418.
H. Morioka et al., J. Alloys Compd., 353 (2003), p. 310.
J. Graetz et al., Phys. Rev. B, 71 (2005), p. 184115.
P. Chen et al., Nature, 420 (21) (2002), p. 302; J. Phys. Chem. B. 107 (2003), p. 10967.
K. Ohoyama et al., J. Phys. Soc. Japan, 74 (2005), p. 483.
E. Fakioglu, Y. Yurum, and T.N. Veziroglu, Int. J. Hydrogen Energy, 29 (2004), p. 1371.
C. Read, G. Ordaz, and S. Satyapal, WE-Heraeus Seminar on Hydrogen Storage with Novel Nanomaterials (23–27 October 2005), http://www.h-workshop.uni-konstanz.de/.
R. Zidan, D.K. Slattery, and J. Burns, Int. J. Hydrogen Energy, 16 (1991), p. 821.
Y. Chen et al., Int. J. Hydrogen Energy, in press.
C.X. Shang et al., Int. J. Hydrogen Energy, 29 (2004), p. 73.
R.A. Varin et al., J. Alloys Compd. 373 (2004), p. 270.
A. E. Finholt, A. C. Bond, and H. I. Schlesinger, J. Am. Chem., 69 (1947), p. 1199.
F.M. Brower et al., J. Am. Chem. Soc., 98 (1976), p. 2450.
J.W. Turley and H.W. Rinn, Inorg. Chem., 8 (1969), p. 18.
G. Sandrock et al., J. Alloys. Comp., (2005), in press.
J. Graetz and J.J. Reilly, J. Phys. B, 109 (2005), pp. 22181–22185.
J. Graetz and J. Reilly, J. Alloys and Comp., in press (2005).
G.C. Sienke et al., J. Chem. Phys., 47 (1967), p. 2759.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Chandra, D., Reilly, J.J. & Chellappa, R. Metal hydrides for vehicular applications: The state of the art. JOM 58, 26–32 (2006). https://doi.org/10.1007/s11837-006-0005-0
Issue Date:
DOI: https://doi.org/10.1007/s11837-006-0005-0