Abstract
Both the consumption and production of crude stainless steel in China rank first in the world. In 2011, the nickel production in China amounted to 446 kilotons, with the proportion of electrolytic nickel and nickel pig iron (NPI) registering 41.5% and 56.5%, respectively. NPI is a low-cost feedstock for stainless steel production when used as a substitute for electrolytic nickel. The existing commercial NPI production processes such as blast furnace smelting, rotary kiln-electric furnace smelting, and Krupp-Renn (Nipon Yakin Oheyama) processes are discussed. As low-temperature (below 1300°C) reduction of nickeliferous laterite ores followed by magnetic separation could provide an alternative avenue without smelting at high temperature (~1500°C) for producing ferronickel with low cost, the fundamentals and recent developments of the low-temperature reduction of nickeliferous laterite ores are reviewed.
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References
R.R. Moskalyk and A.M. Alfantazi, Miner. Eng. 15, 593 (2002).
A.D. Dalvi, W.G. Bacon, and R. Osborne, Proc. PDAC 2004 Int. Convention, Trade Show & Investors Exchange (The Prospectors and Developers Association of Canada, Toronto, Canada, 2004), pp. 1–27.
M. Landers, M. Grafe, R. Gilkes, M. Saunders, and M. Wells, Aust. J. Earth Sci. 58, 745 (2011).
S. Gleeson, C. Butt, and M. Elias, SEG Newsl. 54, 11 (2003).
J. Golightly, Proc. Int. Laterite Symp. (Society of Mining Engineers, American Institute of Mining, Metallurgical, and Petroleum Engineers, New Orleans, LA, 1979), pp. 38–56.
A.E.M. Warner, C.M. Diaz, A.D. Dalvi, P.J. Mackey, and A.V. Tarasov, JOM 58 (4), 11 (2006).
B.A. Wills and T. Napier-Munn, Wills’ Mineral Processing Technology: An Introduction to the Practical Aspects of Ore Treatment and Mineral Recovery, 7th ed. (Burlington, MA: Butterworth-Heinemann, 2006).
B. Whittington and D. Muir, Miner. Process. Extr. Metall. Rev. 21, 527 (2000).
D.H. Rubisov and V.G. Papangelakis, Hydrometallurgy 58, 13 (2000).
K. Liu, Q.Y. Chen, H.P. Hu, Z.L. Yin, and B.K. Wu, Hydrometallurgy 104, 32 (2010).
X.-Y. Guo, W.-T. Shi, D. Li, and Q.-H. Tian, Trans. Nonferr. Metal. Soc. 21, 191 (2011).
X.J. Zhai, Y. Fu, X. Zhang, L.Z. Ma, and F. Xie, Hydrometallurgy 99, 189 (2009).
G. Senanayake, A. Senaputra, and M.J. Nicol, Hydrometallurgy 105, 60 (2010).
A.N. Nikoloski and M.J. Nicol, Hydrometallurgy 105, 54 (2010).
J. De Graaf, Hydrometallurgy 5, 47 (1979).
M.B. Mourao, C. Takano, N. Alonso-Falleiros, C.A.S. Giraldo, A. Pescarmona, A.B. da Veiga, and A.A.F. Schettino, Global Symposium on Recycling, Waste Treatment and Clean Technology, REWAS 2008 (Warrendale, PA: TMS, 2008), pp. 879–885.
M.A. Rhamdhani, J. Chen, T. Hidayat, E. Jak, and P. Hayes, European Metallurgical Conference 2009, vol. 3 (Clausthal-Zellerfeld, Germany: GDMB Informationsgesellschaft GmbH, 2009), pp. 899–914.
R.G. McDonald and B.I. Whittington, Hydrometallurgy 91, 35 (2008).
R.G. McDonald and B.I. Whittington, Hydrometallurgy 91, 56 (2008).
G.K. Das and J.A.B. De Lange, Hydrometallurgy 105, 264 (2011).
G. Li, M. Rao, T. Jiang, Q. Huang, and Z. Peng, Miner. Eng. 24, 859 (2011).
W. Luo, Q.M. Feng, L.M. Ou, G.F. Zhang, and Y. Chen, Miner. Eng. 23, 458 (2010).
W. Luo, Q.M. Feng, L.M. Ou, G.F. Zhang, and Y.P. Lu, Hydrometallurgy 96, 171 (2009).
K. Liu, Q. Chen, and H. Hu, Hydrometallurgy 98, 281 (2009).
J. Nayak, Trans. Indian Inst. Met. 38, 241 (1985).
C.T. Harris, J.G. Peacey, and C.A. Pickles (Paper presented at the Pyrometallurgy of Nickel and Cobalt 2009 Proceedings of the 48th Conference of Metallurgists, Sudbury, Ontario, Canada, 2009).
T. Norgate and S. Jahanshahi, Miner. Eng. 24, 698 (2011).
World Bureau of Metal Statistics, World Metal Statistics Yearbook, http://www.world-bureau.com/services.asp.
J. Johnson, B.K. Reck, T. Wang, and T.E. Graedel, Energy Policy 36, 181 (2008).
J. Kim, G. Dodbiba, H. Tanno, K. Okaya, S. Matsuo, and T. Fujita, Miner. Eng. 23, 282 (2010).
London Metal Exchange, Nickel Production and Consumption, 2011, http://www.lme.com/metals/non-ferrous/nickel/production-and-consumption.
Stainless Steel Council of China Special Steel Enterprises Association, http://www.cssc.org.cn/news_index4.php?col_id=61.
Y.P. Zhang, Y.S. Zhou, Z.Y. Li, and W.G. Li, Ferro-Alloys 38, 18 (2007).
X.J. Guo (Paper presented at the Pyrometallurgy of Nickel and Cobalt 2009 Proceedings of the 48th Conference of Metallurgists, Sudbury, Ontario, Canada, 2009).
C. Robert (Paper presented at the 3rd Euronickel Conference, Helsinki, Finland, 2012).
S. Liu, EP Patent 1,927,667 (2008).
S. Liu, EP Patent 1,927,666 (2008).
J.-M. Pang, P.-M. Guo, and P. Zhao, J. Iron Steel Res. 23, (2011).
J.-J. Liu, G.-R. Hu, and Z.-D. Peng, Rare Met. Cem. Carbides 39, 62 (2011).
X. Liu, X. Jiang, N. Lu, and L. Zhifang, Ferro-Alloys 205, 6 (2009).
National Development and Reform Commission (NDRC) of China, The National Development and Reform Commission, 2011. http://www.ndrc.gov.cn/zcfb/zcfbl/2011ling/t20110426_408008.htm.
C. Wang, F. Yin, Y. Chen, Z. Wang, and J. Wang, Chin. J. Nonferr. Met. 18, s1 (2008).
J. Chen and J. Tan, Ferro-Alloys 200, 13 (2008).
X.-M. Li, L. Tang, and S.-L. Liu, Ferro-Alloys 195, 24 (2007).
W.H. Dennis, Metallurgy of the Ferrous Metals (New York: Pitman Publishing, 1963).
R. Bergman, CIM Bull. 96, 127 (2003).
H. Tsuji, ISIJ Int. 52, 333 (2012).
T. Watanabe, S. Ono, H. Arai, and T. Matsumori, Int. J. Miner. Process. 19, 173 (1987).
T. Matsumori, T. Ishizuka, and T. Matsuda, CIM (Canada: Sudbury, 1997).
H. Tsuji, ISIJ Int. 52, 1000 (2012).
C. Southwestern Engineering and B. Zontelli, Feasibility of the Krupp-Renn Process for Treating the Lean Iron Ores of the Mesabi Range: A Digest (Washington, DC: U.S. Department of Commerce, Area Redevelopment Administration, 1964), p. 27.
M.G. King, JOM 57 (7), 35 (2005).
I. Maragkos, I.P. Giannopoulou, and D. Panias, Miner. Eng. 22, 196 (2009).
T. Norgate and S. Jahanshahi, Miner. Eng. 23, 65 (2010).
M. Gavin, Ore Geol. Rev. 38, 9 (2010).
D.Q. Zhu, Y. Cui, K. Vining, S. Hapugoda, J. Douglas, J. Pan, and G.L. Zheng, Int. J. Miner. Process. 106-109, 1 (2012).
G. Li, T. Shi, M. Rao, T. Jiang, and Y. Zhang, Miner. Eng. 32, 19 (2012).
G.-H. Li, M.-J. Rao, T. Jiang, Q.-Q. Huang, T.-M. Shi, and Y.-B. Zhang, Chin. J. Nonferr. Met. 21, 3137 (2011).
G.-H. Li, M.-J. Rao, T. Jiang, T.-M. Shi, and Q.-Q. Huang, Chin. J. Nonferr. Met. 22, 274 (2012).
M. Jiang, T. Sun, Z. Liu, J. Kou, N. Liu, and S. Zhang, Int. J. Miner. Process. 123, 32 (2013).
D. Zhu, Z. Guolin, J. Pan, Q. Li, Y. An, J. Zhu, and Z. Liu, J. Cent. South Univ. (Sci Technol) 44, 1 (2013).
W. Liang, H. Wang, and J. Fu, J. Cent. South Univ. Sci. Technol. 42, 2173 (2011).
M. Jiang, T.-C. Sun, Z.-G. Liu, J. Kou, N. Liu, Y.-Y. Cao, and S.-Y. Zhang, Min. Metall. Eng. 32, 77 (2012).
Q. Li, Y. Cui, and D. Zhu (Paper presented at The Australasian Institute of Mining and Metallurgy 25th International Mineral Processing Congress (IMPC), Brisbane, Australia, 2010), pp. 1549–1556.
Q. Shi, G. Qiu, and X. Wang, Gold 30, 46 (2009).
D.-H. Huang, J.-L. Zhang, C.-C. Lin, and R. Mao, J. Univ. Sci. Technol. B. 33, 1442 (2011).
J. Canterford, Miner. Sci. Eng 7, 3 (1975).
M. Rao (Master’s Thesis, Central South University, 2010).
N. Brett, K. MacKenzie, J. Sharp, and Q. Rev, Chem. Soc. 24, 185 (1970).
A. Manceau, G. Calas, and A. Decarreau, Clay Miner. 20, 367 (1985).
M. Valix and W.H. Cheung, Miner. Eng. 15, 607 (2002).
F. O’Connor, W. Cheung, and M. Valix, Int. J. Miner. Process. 80, 88 (2006).
S. Li and K. Coley (Paper presented at the Fundamentals of Metallurgical Processing: The James M. Toguri Symposium as Held at the 39th Annual Conference of Metallurgists of CIM, Ottawa, Canada, 2000), pp. 179–192.
Y.F. Chang, X.J. Zhai, Y. Fu, L.Z. Ma, B.C. Li, and T.A. Zhang, Trans. Nonferr. Met. Soc. 18, 969 (2008).
J.H. Li, X.H. Li, Q.Y. Hu, Z.X. Wang, Y.Y. Zhou, J.C. Zheng, W.R. Liu, and L.J. Li, Hydrometallurgy 99, 84 (2009).
C.J. Hallett, Nickel-Cobalt 97: Proceedings of the Nickel Cobalt International Symposium (Montréal, Canada: CIM, 1997), pp. 299–312.
C. Pickels (Paper presented at the International Symposium on Nickel and Cobalt 2005, Calgary, Canada, 2005), pp. 285–304.
M.C.E. Bell and R. Sridhar, U.S. patent 4,049,444 (1977).
W.J. Crama and A.H. Baas, U.S. patent 4,490,174 (1984).
J. Lu, S. Liu, J. Shangguan, W. Du, F. Pan, and S. Yang, Miner. Eng. 49, 154 (2013).
S. Mrowec and K. Przybylski, Oxid. Met. 23, 107 (1985).
T. Shi (Master’s Thesis, Central South University, 2012).
R.M. German, P. Suri, and S.J. Park, J. Mater. Sci. 44, 1 (2009).
M. Valix and W.H. Cheung, Miner. Eng. 15, 523 (2002).
A. Nestoridis, I. Financial Mining, C. Shipping, Eds. (US, 1977), vol. 670224.
G. Li, M. Rao, T. Jiang, Y. Zhang, and Q. Li, Supplemental Proc.: Vol. 1: Materials Processing and Properties (Warrendale, PA: TMS, 2010), pp. 489–496.
C.M. Diaz, C.A. Landolt, A. Vahed, A.E.M. Warner, and J.C. Taylor, JOM 40, 28 (1988).
Acknowledgements
The authors wish to express their thanks to the Program for New Century Excellent Talents in University (NCET–11–0515) and the Fundamental Research Funds for the Central Universities and the Hunan Provincial Innovation Foundation for Postgraduate (CX2011B124) for financial support of this research. Special thanks go to Dr. Phillip J. Mackey (P.J. Mackey Technology Inc.) and Dr. Zhiwei Peng (Department of Materials Science and Engineering, Michigan Technological University) for helpful comments and suggestions.
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Rao, M., Li, G., Jiang, T. et al. Carbothermic Reduction of Nickeliferous Laterite Ores for Nickel Pig Iron Production in China: A Review. JOM 65, 1573–1583 (2013). https://doi.org/10.1007/s11837-013-0760-7
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DOI: https://doi.org/10.1007/s11837-013-0760-7