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Conducting polymers for corrosion protection: a review

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Abstract

Conducting polymers (CPs) such as polyaniline (PANI), polypyrrole (PPy), and polythiophene (PTh) are used for the corrosion protection of metals and metal alloys. Several groups have reported diverse views about the corrosion protection by CPs and hence various mechanisms have been suggested to explain anticorrosion properties of CPs. These include anodic protection, controlled inhibitor release as well as barrier protection mechanisms. Different approaches have been developed for the use of CPs in protective coatings (dopants, composites, blends). A judicious choice of synthesis parameters leads to an improvement in the anticorrosion properties of the coatings prepared by CPs for metals and their alloys. This article is prepared as a review of the application of CPs for corrosion protection of metal alloys.

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Acknowledgments

The corresponding author would like to thank Prof. S.T. Vagge, Head, Department of Metallurgy and Material Science, College of Engineering, Pune 411005 (MH) India for providing facilities, and Prof. Anil Sahasrabudhe, Director, College of Engineering, Pune 411005 (MH), India for his constant encouragement along with support from Alumni Association of COEP for granting ADFF Meta Fellowship, AICTE and UGC, New Delhi India and ISRO, Bangalore. Authors from North Dakota State University (NDSU) gratefully acknowledge the support from US Army Research Laboratory under Grant No. W911NF-09-2-0014, W911NF-10-2-0082, and W911NF-11-2-0027.

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  1. Department of Metallurgy and Materials Science, College of Engineering, Shivajinagar, Pune, 411005, MH, India

    Pravin P. Deshpande

  2. Department of Coatings and Polymeric Materials, North Dakota State University, 1735 NDSU Research Park Drive, NDSU Dept #2760, P.O. Box 6050, Fargo, ND, 58108-6050, USA

    Niteen G. Jadhav & Victoria J. Gelling

  3. Department of Chemistry, Aristotle University of Thessaloniki, 54 124, Thessaloniki, Greece

    Dimitra Sazou

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Deshpande, P.P., Jadhav, N.G., Gelling, V.J. et al. Conducting polymers for corrosion protection: a review. J Coat Technol Res 11, 473–494 (2014). https://doi.org/10.1007/s11998-014-9586-7

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