Abstract
Corrosion protection coatings were developed based on a hybrid self-assembled nanophase particle process (HSNAP) for the localized corrosion resistance of modified 9Cr–1Mo steel in 0.05 M NaCl solution. The coating sol was prepared using silane-zirconia precursors and a polymeric crosslinking agent. Scanning electron microscopy and X-ray photoelectron spectroscopy were used to study the morphology and composition of the coated specimens, respectively. The thickness of the coatings was determined by a thickness gauge meter and Raman imaging analysis. The corrosion resistance of coated specimens was analyzed using electrochemical impedance spectroscopy, and it was observed that HSNAP-coated specimens showed superior resistance to localized corrosion than the as-received specimens in chloride medium.
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Zheludkevich, ML, Serra, R, Montemor, F, Salvado, I, Ferreira, M, “Corrosion Protective Properties of Nanostructured Sol-Gel Hybrid Coatings to AA2024-T3.” Surf. Coat. Technol., 200 3084–3094 (2006)
Peng, S, Zhao, W, Li, H, Zeng, Z, Xue, Q, Wu, X, “The Enhancement of Benzotriazole on Epoxy Functionalized Silica Sol-Gel Coating for Copper Protection.” App. Surf. Sci., 276 284–290 (2013)
Zheludkevich, ML, Salvado, I, Ferreira, MGS, “Sol–gel Coatings for Corrosion Protection of Metals.” J. Mater. Chem., 15 5099–5111 (2005)
Zheng, S, Li, J, “Inorganic–Organic Sol Gel Hybrid Coatings for Corrosion Protection of Metals.” J. Sol-Gel Sci. Technol., 54 174–187 (2010)
Zheludkevich, ML, Shchukin, DG, Yasakau, KA, Mohwald, H, Ferreira, MGS, “Anticorrosion Coatings with Self-Healing Effect Based on Nanocontainers Impregnated with Corrosion Inhibitor.” Chem. Mater., 19 402–411 (2007)
Hosseinalipour, SM, Ershad-langroudi, A, Nemati Hayati, A, Nabizade-Haghighi, AM, “Characterization of Sol-Gel Coated 316L Stainless Steel for Biomedical Applications.” Prog. Org. Coat., 67 371–374 (2010)
Donley, MS, Mantz, RA, Khramov, AN, Balbyshev, VN, Kasten, LS, Gaspar, DJ, “The Self-assembled Nanophase Particle (SNAP) Process: A Nanoscience Approach to Coatings.” Prog. Org. Coat., 47 401–415 (2003)
Voevodin, NN, Kurdziel, JW, Mantz, R, “Corrosion Protection for Aerospace Aluminum Alloys by Modified Self-assembled Nanophase Particle (MSNAP) Sol Gel.” Surf. Coat. Technol., 201 1080–1084 (2006)
Roussi, E, Tsetsekou, A, Tsiourvas, D, Karantonis, A, “Novel Hybrid Organo-Silicate Corrosion Resistant Coatings based on Hyperbranched Polymers.” Surf. Coat. Technol., 205 3235–3244 (2011)
Parsa, M, Hosseini, SMA, Jamalizadeh, E, Sahib, V, “Preparation and Corrosion Protective Properties of Titania-containing Modified Self-assembled Nanopahase Particle (TMSNAP) Sol–Gel on AA2024 Aluminium Alloy.” Mater. Corr., 64 9999–10010 (2013)
Arunchandran, C, Ramya, S, George, RP, Kamachi Mudali, U, “Self-healing Corrosion Resistive Coatings Based on Inhibitor Loaded TiO2 Nanocontainers.” J. Electro. Soc., 159 C552–C559 (2012)
Ramya, S, Arunchandran, C, George, RP, “Studies on Hybrid Sol-Gel Silica/PVP Coatings on Modified 9Cr-1Mo Steel.” Trans. Ind. Inst. Metals, 68 513–519 (2015)
Arunchandran, C, Ramya, S, George, RP, Kamachi Mudali, U, “2-Mercaptobenzothiazole-loaded Hollow Mesoporous Silica-based Hybrid Coatings for Corrosion Protection of Modified 9Cr-1Mo Ferritic Steel.” Corrosion, 70 496–511 (2015)
KamachiMudali, U, Khatak, HS, Dayal, RK, Gnanamoorthy, JB, “Localized Corrosion Studies on Materials Proposed for a Safety-Grade Sodium-to-Air Decay-heat Removal System for Fast Breeder Reactors.” J. Mater. Eng. Perf., 2 135–140 (1993)
Modi, OP, Mungole, MN, Singh, KP, “Potentiodynamic Studies of Modified 9Cr-1Mo Ferritic steel in Sulfuric acid and Seawater.” Corr. Sci., 30 941–947 (1990)
Singh, VB, Upadhyay, BN, “The Electrochemical Behaviour of 9Cr-1Mo Steel in Concentrated Acid Solution Mixtures.” Corr. Sci., 40 705–713 (1998)
Pujar, MG, Dayal, RK, Khanna, AS, Kreutz, EW, “Effect of Laser Surface Melting on the Corrosion Resistance of Chromium-plated 9Cr-1Mo Ferritic Steel in an Acidic Medium.” J. Mater. Sci., 28 3089–3096 (1993)
Ruhi, G, Modi, OP, Singh, IB, “Corrosion Behaviour of Nanostructured Sol-Gel Alumina Coated 9Cr-1Mo Ferritic Steel in Chloride Bearing Environment.” Surf. Coat. Technol., 204 359–365 (2009)
Mahalakshmi, PV, Vanithakumari, SC, Gopal, J, Kamachi Mudali, U, Raj, B, “Enhancing Corrosion and Biofouling Resistance Through Superhydrophobic Surface Modification.” Curr. Sci., 101 1328–1336 (2011)
Finsgar, M, Fassbender, S, Nicolini, F, Milosev, I, “Polyethyleneimine as a Corrosion Inhibitor for ASTM 420 Stainless Steel in Near-neutral Saline Media.” Curr. Sci., 51 525–533 (2009)
Moulder, JF, Stickle, WF, Sobol, PE, Bomben, KD, Chastain, J, In: Chastain, J, King, RC, Jr, (eds.) Handbook of X-ray Photo-electron Spectroscopy, ULVAC-PHI Inc., Chigasaki, 1995
ASTM, “Standard Test Methods for Measuring Adhesion by Tape Test–Test Method B,” ASTM D3359-09e2, ASTM, West Conshohocken, PA.
He, X, Shi, X, “Self-repairing Coating for Corrosion Protection of Aluminum Alloys.” Prog. Org. Coat., 65 37–43 (2009)
Zheludkevich, ML, Serra, R, Montemor, MF, Yasakau, KA, Salvado, IMM, Ferreira, MGS, “Nanostructured Sol-Gel coatings Doped with Cerium Nitrate as Pre-treatments for AA2024-T3: Corrosion Protection Performance.” Electrochem. Acta, 51 208–217 (2005)
Lamaka, SV, Montemor, MF, Galio, AF, Zheludkevich, ML, Trindade, C, Dick, LF, Ferreira, MGS, “Novel Hybrid Sol–gel Coatings for Corrosion Protection of AZ31B Magnesium Alloy.” Electrochimica Acta, 53 4773–4783 (2008)
Fu, CJ, Zhan, ZW, Yu, M, Li, SM, Liu, JH, Dong, L, “Influence of Zr/Si Molar Ratio on Structure, Morphology and Corrosion Resistance of Organosilane Coatings Doped with Zirconium(IV) n-Propoxide.” Int. J. Electrochem. Sci., 9 2603–2619 (2014)
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Ramya, S., Arunchandran, C., George, R.P. et al. Impact of hybrid self-assembled nanophase particle-based sol–gel coatings on the localized corrosion behavior of modified 9Cr–1Mo steel in chloride medium. J Coat Technol Res 14, 129–140 (2017). https://doi.org/10.1007/s11998-016-9836-y
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DOI: https://doi.org/10.1007/s11998-016-9836-y