Abstract
Biocomposites from polyhydroxybutyrate (PHB) and some bio-fillers such as lignin (L), alpha cellulose (AC) and cellulose nanofibrils (CNFs) were prepared to investigate the effect of the bio-fillers on the properties of PHB by a solvent casting method. The thermal properties by thermogravimetry analysis (TGA–DTG and DTA) and differential scanning calorimetry (DSC) were determined; morphological characterization by scanning electron microscopy (SEM) and structural analysis by X-ray diffraction (XRD), and Fourier transform infrared spectroscopy (FTIR) of the biocomposites were performed. TGA curves showed that the highest values for T 10%, T 50% of the biocomposites were 278.2∘C for PHB+2%AC and 291.7∘C for PHB+2%CNFs; however, the best value for T 75% was obtained as 381.5∘C for PHB+2%L. According to DTG curves, the best results were found for PHB+0.5%L and PHB+0.5%CNFs. DTA showed an increase in temperature of maximum degradation with loading of lignin and CNFs. The addition of bio-fillers increases T c and T m for both first cooling/heating and second cooling/heating. T c and T m values for first cooling/healing were found to be lower as compared with second cooling/healing. Furthermore, the addition of bio-fillers acts as a nucleating agent in PHB and SEM pictures showed the porous structure in all biocomposites. SEM images revealed uniform distribution of the reinforcing particles in the polymer at low loadings (0.5 wt%), while higher loadings (2 wt%) of L and CNFs contributed to easy aggregation within the PHB matrix. In XRD studies, PHB in the range 5–55∘ shows 6 main peaks. XRD patterns of the PHB biocomposites revealed 3 main peaks at 13.57∘, 16.87∘ and 22.1∘, and the other peaks disappeared in the patterns. The largest and lowest values of X c were found for PHB+2%AC and PHB+2%CNFs, respectively.
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Liau C P, Ahmad M, Shameli K, Yunus W Z, Ibrahim N A, Zainuddin N and Then Y Y 2014 E-Sci. World J. Article ID 572726 (9 p)
El-Hadi A M 2014 Polym. Bull. 71 1449
Erkskea D, Viskerea I, Dzenea A, Tupureinaa V and Savenkovab L 2006 Proc. Estonian Acad. Sci. Chem. 55 70
Sridhar V, Lee I, Chun H H and Park H 2013 eXPRESS Polym. Lett. 7 320
Seoane I T, Manfredi L B and Cyras V P 2015 Proc. Mater. Sci. 8 807
Sudesh K and Doi Y 2005 in Bastioli C (ed) Handbook of biodegradable polymers (Shawbury: Rapra Technology Ltd) p 219
Sanchez-Garcia M D, Gimenez E and Lagaron J M 2008 J. Appl. Polym. Sci. 108 2787
Cyras V P, Vazquez A, Rozsa C, Fernandez G N, Torre L and Kenny J M 2000 J. Appl. Polym. Sci. 77 2889
Bucci D, Tavares L and Sell I 2005 Polym. Test. 24 564
Bordes P, Pollet E and Avérous L 2009 Prog. Polym. Sci. 34 125
Fernandes E G, Pietrini M and Chiellini E 2004 Biomacromolecules 5 1200
Singh S and Mohanty A K 2007 Compos. Sci. Technol. 67 1753
Tănasea E E, Popaa M E, Râpă M B and Popaa O 2015 Agric. Agric. Sci. Procedia 6 608
Chan R T H, Garvey C J, Marcal H, Russell R A, Holden P J and Foster J F R 2011 Int. J. Polym. Sci. Article ID 651549 (8 p)
Bhardwaj R, Mohanty A K, Drzal L T, Pourboghrat F and Misra M 2006 Biomacromolecules 7 2044
Christiana S J and Billington S L 2011 Compos. Part B: Eng. 42 1920
El-Hadi A M 2013 Colloid Polym. Sci. 291 743
Jiang L, Morelius E, Zhang J, Wolcott M and Holbery J 2008 J. Compos. Mater. 42 2629
Vila C, Campos A R, Cristovao C, Cunha A M, Santos V and Parajo J C 2000 Compos. Sci. Technol. 68 944
Ren H, Liu Z, Zhai H, Cao Y and Omori S 2015 BioResources 10 432
Azizi Samir M A S, Alloin F and Sanchez A 2004 Polymer 45 4149
Kiziltas A, Gardner D J, Han Y and Yang H 2011 Thermochimica 519 38
Rabiej M 2003 Fibers Text. East. Eur. 11 83
Rabiej S 1991 Eur. Polym. J. 27 947
Seggiania M, Cinelli P, Verstichelc S, Puccinia M, Vitoloa S, Anguillesia I and Lazzeria A 2015 Chem. Eng. Trans. 43 1813
Erceg M, Kovacic T and Klaric I 2005 Polym. Deg. Stab. 90 313
Ren H, Liu Z, Zhai Z M, Cao Y and Omori S 2015 BioResources 10 432
Hamada Y, Yoshida K, Asai R, Hayase S, Nokami T, Izumi S and Itoh T 2013 Green Chem. 15 1863
Goudarzi A, Lin L and Ko F K 2014 J. Nanotechnol. Eng. Med. 5 1
Lionetto F, Sole R, Cannoletta D, Vasapollo G and Maffezzoli A 2012 Materials 5 1910
Aydemir D, Kiziltas A, Kiziltas E E, Gardner D and Gunduz G 2015 Compos. Part B 68 414
Bloembergen S and Holden D A 1986 Macromolecules 19 2865
Padermshoke A, Katsumoto Y, Sato H, Ekgasit S, Noda I and Ozaki Y 2005 Spectrochim. Acta Part A: Mol. Biomol. Spectrosc. 61 541
Doi Y 1990 Microbial polyesters (New York: VHC Publishing) p 101
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UZUN, G., AYDEMIR, D. Biocomposites from polyhydroxybutyrate and bio-fillers by solvent casting method. Bull Mater Sci 40, 383–393 (2017). https://doi.org/10.1007/s12034-017-1371-7
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DOI: https://doi.org/10.1007/s12034-017-1371-7