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Structural and physical properties of \(\hbox {Sm}^{3+}\) doped magnesium zinc sulfophosphate glass

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Abstract

Samarium (\(\hbox {Sm}^{3+})\) doped magnesium zinc sulfophosphate glass system of composition (60–\(x)\hbox {P}_{2}\hbox {O}_{5}\)–20MgO–20ZnSO\(_{4}\)–\(x\hbox {Sm}_{2}\hbox {O}_{3}\) (\(x =\) 0.0, 0.5, 1.0, 1.5 and 2.0 mol%) were synthesized using melt-quenching technique. The structure and physical properties of prepared glass samples were characterized. The X-ray diffraction pattern verified their amorphous nature. The physical properties such as density, refractive index, molar volume, rare earth ion concentration, etc. were calculated. The decrease in the optical bandgap energy with increasing \(\hbox {Sm}_{2}\hbox {O}_{3}\) contents was attributed to the alteration in the glass network structures. Fourier transformed infrared spectra and Raman analyses manifested the depolymerization of \(\hbox {ZnSO}_{4}\) in the phosphate host matrix. The present findings may be beneficial for the advancement of functional glasses.

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Acknowledgements

We are grateful to UTM and Ministry of Education for the financial support through Vote 12H42, 13H50 (GUP) and 4F424 (FRGS).

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Authors and Affiliations

  1. Phosphor Research Group, Department of Physics, Faculty of Science, Universiti Teknologi Malaysia, 81310, Skudai, Malaysia

    F Ahmadi & R Hussin

  2. Advanced Optical Materials Research Group, Department of Physics, Faculty of Science, Universiti Teknologi Malaysia, 81310, Skudai, Malaysia

    S K Ghoshal

Authors
  1. F Ahmadi
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  2. R Hussin
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  3. S K Ghoshal
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Correspondence to F Ahmadi.

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Ahmadi, F., Hussin, R. & Ghoshal, S.K. Structural and physical properties of \(\hbox {Sm}^{3+}\) doped magnesium zinc sulfophosphate glass. Bull Mater Sci 40, 1097–1104 (2017). https://doi.org/10.1007/s12034-017-1462-5

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  • DOI: https://doi.org/10.1007/s12034-017-1462-5

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