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Selective hydrogenation of maleic anhydride over Pd/Al2O3 catalysts prepared via colloid deposition

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Abstract

Pd/Al2O3 catalysts were prepared via colloid deposition and the performance of the catalysts was examined in the selective hydrogenation of maleic anhydride to succinic anhydride. When the reaction was carried on in a batch system with 1,4-dioxane as the solvent (353 K and 1.0 MPa), high conversion of maleic anhydride (>98%) and high selectivity (>99%) for succinic anhydride were observed after 5 h. The as-prepared Pd/Al2O3 catalyst also showed excellent performance in solvent-free system and fixed-bed systems. The maleic anhydride (MA) conversion was greater than 98%, and high selectivity (>99%) for succinic anhydride was obtained after 1600 h in a fixed bed reacter. The results showed that the activity of the Pd/Al2O3 catalysts was excellent due to its high active surface area.

Pd/Al2O3 catalysts were prepared via colloid deposition and the performance of the catalysts was examined in the selective hydrogenation of maleic anhydride (MA) to succinic anhydride (SA). The MA conversion was >98%, and selectivity for SA was >99%.

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Acknowledgements

This work was supported by the Technology Institute of Shanghai Huayi (Group) Company, Natural Science Foundation of Science and Technology Department of Jilin Province (20130101015JC), the Innovation Project of Frontiers of Science and New Interdiscipline of Jilin University (2012), the open subject of State Key Laboratory of Inorganic Synthesis and Preparative Chemistry (2012–15) and the National Science Foundation of China (Grant NO. 20973080).

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Authors and Affiliations

  1. Key Laboratory of Surface and Interface Chemistry of Jilin Province, College of Chemistry, Jilin University, Qianjin Road 2699, Changchun, 130012, PR China

    HONGJING YUAN, WEITAO HUO, DEQUAN CONG, WENXIANG ZHANG, SU LI & ZHENLU WANG

  2. Shanghai Huayi (Group) Company Technology Research Institute, Longwu Road 4600, Shanghai, 200241, PR China

    CHUNLEI ZHANG, CHUNLI NING, YONG TANG & YI ZHANG

  3. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Qianjin Road 2699, Changchun, 130012, PR China

    JIAHUAN LUO

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  1. HONGJING YUAN
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  10. SU LI
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Correspondence to ZHENLU WANG.

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YUAN, H., ZHANG, C., HUO, W. et al. Selective hydrogenation of maleic anhydride over Pd/Al2O3 catalysts prepared via colloid deposition. J Chem Sci 126, 141–145 (2014). https://doi.org/10.1007/s12039-013-0542-3

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  • DOI: https://doi.org/10.1007/s12039-013-0542-3

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