Abstract
New R 2Ti3Ge4 (R=Dy, Ho and Er) intermetallic compounds have been synthesized and characterized by X-ray diffraction and low temperature ac magnetic susceptibility, electrical resistivity and thermoelectric power measurements were carried out. The compounds crystallize in the parent, Sm5Ge4-type orthorhombic structure (space group Pnma) and lanthanide contraction is observed as one moves along the rare-earth series. The changeover from paramagnetic to antiferromagnetic phase happens at low temperatures and the ordering temperature scales with the de Gennes factor. The electrical resistivity is metallic with a negative curvature above 100 K. Thermopower displays a weak maximum at temperatures less than 50 K signifying the possible phonon and magnon drag effects.
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Nirmala, R., Sankaranarayanan, V., Sethupathi, K. et al. Electrical transport and magnetic ordering in R 2Ti3Ge4 (R=Dy, Ho and Er) compounds. Pramana - J Phys 58, 1101–1104 (2002). https://doi.org/10.1007/s12043-002-0225-y
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DOI: https://doi.org/10.1007/s12043-002-0225-y