Abstract
Cerium-doped Zinc Oxide nanoparticles were prepared with co-precipitation method. X-Ray diffraction (XRD) analysis shows sharp peaks conforming the crystalline nature of prepared particles. Crystallite size was found from XRD peaks. A Field Emission Scanning Electron Microscope (FESEM) was used to see the particles and hexagonal shape. Spectroscopic properties were studied using a Fourier Transform-Infra Red (FT-IR) spectrometer and Raman spectrometer. Optical properties were studied using a Diffuse Reflectance Ultraviolet Visible (DRS UV–VIS), spectrophotometer. Band gap of doped particles reduces as doping concentration increases. Reduced band gap of Cerium doped particles makes them a good catalyst. There are many organic dyes which are used as coloring agents by industries like textile, printing, etc. These industries release harm full pollutants into water bodies, which effect human and aquatic life. Prepared Cerium-doped ZnO nanoparticles have proved to photodegrade Methylene Blue. Undoped ZnO nanoparticles decolorized the solution in 210 min with 81.93% efficiency. Ce (0.03 wt%) doped ZnO nanoparticles decolorized the solution in 120 min with 92.62% efficiency.
Similar content being viewed by others
References
Daksh Daksh and Yadvendra Kumar Agrawal 2016 Rare Earth-Doped Zinc Oxide Nanostructures. Rev. Nanosci. Nanotechnol. 5: 1–27
Aisah N, Gustiono D, Fauzia V, Sugihartono I and Nuryadi R 2017 Synthesis and Enhanced Photocatalytic Activity of Ce-Doped Zinc Oxide Nanorods by Hydrothermal Method. IOP Conf. Series: Mater. Sci. Eng. 172: 012037
Clament Sagaya Selvam N, Judith Vijaya J and John Kennedy L 2014 Effect of Ce doping on structural, optical and photocatalytic properties of ZnO nano-structures. J. Nanosci. Nanotechnol. 14: 2317–2324
Behzad Shahmoradi, Soga K, Ananda S, Somashekar R and Byrappa K 2010 Modification of neodymium-doped ZnO hybrid nanoparticles under mild hydrothermal conditions. Nanoscale 2: 1160–1164
Phuruangrat A, Thongtem T, Satchawan S and Thongtem S 2018 Photocatalytic activity of rugby-like Nd-doped ZnO particles activated by ultraviolet. Dig. J. Nanomater. Biostruct. 13: 625–630
Theivarasu C and Indumathi T 2016 Effect of rare earth metal ion Ce3+ on the structural, optical and magnetic properties of ZnO nanoparticles synthesized by the co-precipitation method. J. Mater. Sci. Mater. Electron. https://doi.org/10.1007/s10854-016-5971-6
Richter H, Wang Z P and Ley L 1981 The one phonon Raman spectrum in microcrystalline silicon. Solid State Commun. 39: 625–629
Bilel Chouchene, Tahar Ben Chaabane, Lavinia Balan, Emilien Girot, Kevin Mozet, Ghouti Medjahdi and Raphaël Schneider 2016 High performance Ce-doped ZnO nanorods for sunlight-driven photocatalysis, Beilstein J. Nanotechnol. 7: 1338–1349
Bomilaa R, Srinivasana S, Venkatesanb A, Bharathc B and Perinbam K 2017 Structural, optical and antibacterial activity studies of Ce-doped ZnO nanoparticles prepared by wet-chemical method, Mater. Res. Innovat. 1433–075X
Chin Boon Onga, Law Yong Ngb and Abdul Wahab Mohammad 2018 A review of ZnO nanoparticles as solar photocatalysts: Synthesis, mechanisms and applications Renew. Sustain. Energy Rev. 81: 536–551
Labhane P K, Patle1 L B, Huse V R and Sonawane G H 2018 Synthesis of Ce doped ZnO nanoparticles coupled with graphene oxide as efficient photocatalyst for the degradation of dye under day light, 2nd International Conference on Condensed Matter and Applied Physics (ICC 2017) AIP Conf. Proc. 1953, 030008-1–030008-4
Xinyu Zhang, Jiaqian Qin, Yanan Xue, Pengfei Yu, Bing Zhang, Limin Wang and Riping Liu 2010 Effect of aspect ratio and surface defects on the photocatalytic activity of ZnO nanorods. Sci. Rep. 4: 4596
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Karidas, S., Veena, B.K., Pujari, N. et al. Photodegradation of Methylene Blue (MB) using Cerium-doped Zinc Oxide nanoparticles. Sādhanā 45, 128 (2020). https://doi.org/10.1007/s12046-020-01329-x
Received:
Revised:
Accepted:
Published:
DOI: https://doi.org/10.1007/s12046-020-01329-x