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Effect of nano additives (titanium and zirconium oxides) and diethyl ether on biodiesel-ethanol fuelled CI engine

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Abstract

The present work is dedicated to the comparative experimental study of biodiesel-ethanol blends in a compression ignition engine using TiO2 (Titanium oxide) nanoparticle, ZrO2 (Zirconium oxide) nanoparticle and DEE (Diethyl ether) additives. The test fuels used are a blend of biodiesel (80%) -ethanol (20%) (denoted as BE), a blend of BE with 25 ppm Titanium oxide nanoparticle (denoted as BE-Ti), a blend of BE with 25 ppm Zirconium oxide nanoparticle (denoted as BE-Zr) and a blend of BE with 50 ml Diethyl ether (denoted as BE-DEE). Addition of nanoparticles increases the oxidation rate, reduces the light-off temperature and creates large contact surface area with the base fuel thereby enhancing the combustion with minimal emissions. Experimental results shown that addition of Titanium nanoparticles increased NOx, HC and smoke with lowered BSFC and CO. Whereas addition of Zirconium nanoparticles increases BSFC and HC emissions with lowered CO, CO2 and smoke emissions in comparison with BE blends. DEE addition to BE blends improved the heat release rate and increased HC, CO emissions were observed with lowered BSFC, NOx and smoke. Simultaneous reduction of NOx and smoke indicates the effect of DEE on Low temperature combustion (LTC).

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References

  1. B. S. Chauhan, N. Kumar, H. M. Cho and H. C. Lim, A study on the performance and emission of a diesel engine fueled with Karanja biodiesel and its blends, Energy, 56 (2013) 1–7.

    Article  Google Scholar 

  2. M. N. Nabi, Md. M. Rahman and M. S. Akhter, Biodiesel from cotton seed oil and its effect on engine performance and exhaust emissions, Applied Thermal Engineering, 29 (2009) 2265–2270.

    Article  Google Scholar 

  3. H. An, W. M. Yang, A. Maghbouli, J. Li, S. K. Chou and K. J. Chua, Performance combustion and mission characteristics of biodiesel derived from waste cooking oils, Applied Energy, 112 (2013) 493–499.

    Article  Google Scholar 

  4. O. Ozener, L. Yuksek, A. T. Ergenc and M. Ozkan, Effects of soybean biodiesel on a DI diesel engine performance, emission and combustion characteristics, Fuel, 115 (2014) 875–883.

    Article  Google Scholar 

  5. P. Q. Tan, Z. Y. Hu, D. M. Lou and Z. J. Li, Exhaust emissions from a light-duty diesel engine with jatropha biodiesel fuel, Energy, 39 (2012) 356–362.

    Article  Google Scholar 

  6. P. S. Mehta, K. Anand and R. P. Sharma, Experimental investigations on combustion, performance and emissions characteristics of neat karanji biodiesel and its methanol blend in a diesel engine, Biomass and Bioenergy, 35 (2011) 533–541.

    Article  Google Scholar 

  7. A. M. Liaquat, H. H. Masjuki, M. A. Kalam, I. M. Rizwanul Fattah, M. A. Hazrat, M. Varman, M. Mofijur and M. Shahabuddin, Effect of coconut biodiesel blended fuels on engine performance and emission characteristics, Procedia Engineering, 56 (2013) 583–590.

    Article  Google Scholar 

  8. D. B. Hulwan and S. V. Joshi, Performance emission and combustion characteristic of a multi cylinder DI diesel engine running on diesel–ethanol–biodiesel blends of high ethanol content, Applied Energy, 88 (2011) 5042–5055.

    Article  Google Scholar 

  9. B. P. Singh, Performance and emission characteristics of conventional engine running on jatropha oil, Journal of Mechanical Science and Technology, 27 (8) (2013) 2569–2574.

    Article  Google Scholar 

  10. M. Prabhahar and K. Rajan, Performance and combustion characteristics of a diesel engine with titanium oxide coated piston using Pongamia methyl ester, Journal of Mechanical Science and Technology, 27 (5) (2013) 1519–1526.

    Article  Google Scholar 

  11. V. A. M. Selvam, R. B. Anand and M. Udayakumar, Effect of cerium oxide nanoparticle and carbon nanotube as fuelborne additives in dieseterol blends on the performance combustion and emission charactersistics of a variable compression ratio engine, Fuel, 130 (2014) 160–167.

    Article  Google Scholar 

  12. J.-Y. Jung, J. W. Lee and Y. T. Kang, CO2 absorption characteristics of nanoparticle suspensions in methanol, Journal of Mechanical Science and Technology, 26 (8) (2012) 2285–2290.

    Article  Google Scholar 

  13. K. Fangsuwannarak and K. Triratanasirichai, Improvements of palm biodiesel properties by using nano-TiO2 additive, exhaust emission and engine performance, The Romanian review precision mechanics, MECAHITECH’ 13, International Conference Bucharest, Romania, 43 (2013) 111–118.

    Google Scholar 

  14. V. Sajith, C. B. Sohban and G. P. Peterson, Experimental investigations on the effects of cerium oxide nanoparticle fuel additives on biodiesel, Advances in Mechanical Engineering, 36 (2010) 1–16.

    Google Scholar 

  15. D. Ganesh and G. Shankar, Effect of nanofluid additive on emission reduction in a biodiesel fuelled CI engine), International Conference on Electrical and Control Engineering (ICECE), IEEE (2011) 3453–3459.

    Google Scholar 

  16. N. Yilmaz, Performance and emission characteristics of a diesel engine fuelled with biodiesel–ethanol and biodiesel–methanol blends at elevated air temperatures, Fuel, 94 (2012) 440–443.

    Article  Google Scholar 

  17. G. R. Kannan, R. Karvembu and R. Anand, Effect of metal based additive on performance emission and combustion characteristics of diesel engine fuelled with biodiesel, Applied Energy, 11 (88) (2011) 3694–3703.

    Article  Google Scholar 

  18. H. Jung, D. B. Kittelson and M. R. Zachariah, The influence of a cerium additive on ultrafine diesel particle emissions and kinetics of oxidation, Combustion and Flame, 142 (2005) 276–288.

    Article  Google Scholar 

  19. G. A. Risha, S. F. Son, R. A. Yetter, V. Yang and B. C. Tappan, Combustion of nano-aluminum and liquid water, Proceedings of the Combustion Institute, 31 (2007) 2029–2036.

    Article  Google Scholar 

  20. G. Yanan and Q. Li, Combustion characteristics of fuel droplets with addition of nano and micron-sized aluminum particles, Combustion and Flame, 158 (2011) 354–368.

    Article  Google Scholar 

  21. H. An, W. M. Yang and J. Li, Effects of ethanol addition on biodiesel combustion: A modeling study, Applied Energy, 143 (2015) 176–188.

    Article  Google Scholar 

  22. N. Yilmaz and T. M. Sanchez, Analysis of operating a diesel engine on biodiesel-ethanol and biodiesel-methanol blends, Energy, 46 (2012) 126–129.

    Article  Google Scholar 

  23. D. K. Das, D. P. Kulkarni, R. S. Vajjha and D. Oliva, Application of aluminum oxide nanofluids in diesel electric generator as jacket water coolant, Applied Thermal Engineering, 28 (2008) 1774–1781.

    Article  Google Scholar 

  24. M. J. Kao, C. C. Ting, B. F. Lin and T. T. Tsung, Aqueous aluminum nanofluid combustion in diesel fuel, Journal of Testing and Evaluation, 36 (2) (2008) 186–190.

    Google Scholar 

  25. M. Guru, A. Keskin and D. Altiparmak, Influence of tall oil biodiesel with Mg and Mo based fuel additives on diesel engine performance and emission, Bioresource Technology, 99 (2008) 6434–6438.

    Article  Google Scholar 

  26. P. Tewari, E. Doijode, N. R. Banapurmath and V. S. Yaliwal, Experimental investigations on a diesel engine fuelled with multi walled carbon nanotubes blended biodiesel fuels, International Journal of Emerging Technology and Advanced Engineering, 3 (3) (2013) 72–76.

    Google Scholar 

  27. H. G. Kim and S.-H. Choi, The characteristics of biodiesel and oxygenated additives in a compression ignition engine, Journal of Mechanical Science and Technology, 27 (5) (2013) 1539–1543.

    Article  Google Scholar 

  28. I. Glassman, Combustion, Chapter 9, Third Ed., Academic Press. Orlando, USA (1996).

    Google Scholar 

  29. J. B. Heywood, Internal combustion engine fundamentals, McGraw Hill, New York, USA (1988) 339–342.

    Google Scholar 

  30. I. B. Askari, M. O. Sadegh and M. Ameri, Effect of heat storage and fuel price on energy management and economics of micro CCHP cogeneration systems, Journal of Mechanical Science and Technology, 28 (5) (2014) 2003–2014.

    Article  Google Scholar 

  31. Y. Shin and Y. Kim, Numerical modeling for flame dynamics and combustion processes in a two-sectional porous burner with a detailed chemistry, Journal of Mechanical Science and Technology, 28 (11) (2014) 4797–4805.

    Article  MathSciNet  Google Scholar 

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Correspondence to Harish Venu.

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Recommended by Associate Editor Jeong Park

Harish Venu received his Bachelors (B.E) and Masters degree (M.E) in Mechanical Engineering from the Mechanical Engineering Department of St. Joseph’s college of engineering and Anna University in 2011 and 2013, respectively. In July 2013, he started his Ph.D. program in Mechanical Engineering at Anna University, Chennai, India. His research interest includes biofuels, alternative fuels, nano additives, internal combustion engines and fuel cells.

Venkataramanan Madhavan received his Bachelors degree (B.E) in Madras University in 1998 and Masters degree (M.Tech) in School of Energy in 2000. He completed his doctorate in 2008 in area of Biomass Gasification. His research interests includes gasification, solar cells, alternative fuels and energy conservation.

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Venu, H., Madhavan, V. Effect of nano additives (titanium and zirconium oxides) and diethyl ether on biodiesel-ethanol fuelled CI engine. J Mech Sci Technol 30, 2361–2368 (2016). https://doi.org/10.1007/s12206-016-0446-5

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  • DOI: https://doi.org/10.1007/s12206-016-0446-5

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