Skip to main content
SpringerLink
Log in

Experimental Verification of the Decomposition of Y2O3 in Fe-Based ODS Alloys During Mechanical Alloying Process

  • Published:
Metals and Materials International Aims and scope Submit manuscript

Abstract

In this study, we investigated the state of Y2O3, as a major additive element in Fe-based ODS alloys, during mechanical alloying (MA) processes by thermodynamic approaches and experimental verification. For this purpose, we introduced Ti2O3 that formed different reaction products depending on the state of Y2O3 into the Fe-based ODS alloys. In addition, the reaction products of Ti2O3, Y, and Y2O3 powders were predicted approximately based on their formation enthalpy. The experimental results relating to the formation of Y-based complex oxides revealed that YTiO3 and Y2Ti2O7 were formed when Ti2O3 reacted with Y; in contrast, only Y2Ti2O7 was detected during the reaction between Ti2O3 and Y2O3. In the alloy of Fe–Cr–Y2O3 with Ti2O3, YTiO3 (formed by the reaction of Ti2O3 with Y) was detected after the MA and heat treatment processes were complete, even though Y2O3 was present in the system. Using these results, it was proved that Y2O3 decomposed into monoatomic Y and O during the MA process.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  1. A. Kimura, R. Kasada, A. Kohyama, H. Tanigawa, T. Hirose, K. Shiba, S. Jitsukawa, S. Ohtsuka, S. Ukai, M.A. Sokolov, R.L. Klueh, J. Nucl. Mater. 367–370, Part A (2007)

  2. R.L. Klueh, J.P. Shingledecker, R.W. Swindeman, D.T. Hoelzer, J. Nucl. Mater. 341, (2005)

  3. M.L. Flem, in Advanced Materials for Fuel Cladding in Sodium Fast Reactors, Presentation to 3rd MATGEN Summer School, Lerici, Italy, 2011

  4. P. Norajitra, R. Giniyatulin, T. Ihli, G. Janeschitz, P. Karditsas, W. Krauss, R. Kruessmann, V. Kuznetsov, D. Maisonnier, I. Mazul, C. Nardi, I. Ovchinnikov, S. Papastergiou, A. Pizzuto, P. Sardain, Nucl. Fusion 45, 11 (2005)

    Article  Google Scholar 

  5. T.R. Allen, J. Gan, J.I. Cole, M.K. Miller, J.T. Busby, S. Shutthanandan, S. Thevuthasan, J. Nucl. Mater. 375, 1 (2008)

    Article  Google Scholar 

  6. J.H. Lee, J.H. Kim, J. Kor. Powder Met. Inst. 20, 3 (2013)

    Google Scholar 

  7. S. Ukai, T. Okuda, M. Fujiwara, T. Kobayashi, S. Mizuta, H. Nakashima, J. Nucl. Sci. Technol. 39, 8 (2002)

    Article  Google Scholar 

  8. M. A. Sokolov, H. Tanigawa, G. R. Odette, K. Shiba, R. L. Klueh, J. Nucl. Mater., 367–370, Part A (2007)

  9. A. Kelly, R.B. Nicholson, Strengthening Methods in Crystals (Wiley, New York, 1972)

    Google Scholar 

  10. M.J. Alinger, Dissertation, University of California, Santa Barbara, 2004

  11. Z. Oksiuta, M. Lewandowska, K.J. Kurzydolwski, Mech. Mater., 67, (2013)

  12. H. Xu, Z. Lu, S. Ukai, N. Oono, C. Liu, J. Alloys Compd., 693, (2017)

  13. G.J. Zhang, Y.J. Sun, R.M. Niu, J. Sun, J.F. Wei, B.H. Zhao, L.X. Yang, Adv. Eng. Mater. 6, 12 (2004)

    Google Scholar 

  14. M. A. Auger, T. Leguey, A. Munoz, M. A. Monge, V. D. Castro, P. Fernandez, G. Garces, R. Pareja, J. Nucl. Mater., 417, (2011)

  15. I.S. Kim, B.Y. Choi, C.Y. Kang, T. Okuda, P.J. Maziasz, K. Miyahara, ISIJ Int. 43, (2003)

  16. M. A. Auger, V. D. Castro, T. Leguey, A. Munoz, R. Pareja, J. Nucle. Mater., 436, (2013)

  17. H. Sakasegawa, M. Tamura, S. Ohtsuka, S. Ukai, H. Tanigawa, A. Kohyama, M. Fujiwara, J. Alloys Compd., 452, (2008)

  18. P. Unifantowicz, T. Plocinski, C. A. Williams, R. Schaublin, N. Blanc, J. Nucl. Mater., 442, (2013)

  19. K. Oka, S. Ohnuki, S. Yamashita, N. Akasaka, S. Ohtsuka, H. Tagigawa, Mater. Trans., 48, (2007)

    Article  CAS  Google Scholar 

  20. Q. Tang, T. Hoshino, S. Ukai, B. Leng, S. Hayashi, Y. Wang, Mater. Trans. 51, 11 (2010)

    Article  Google Scholar 

  21. H. Sakasegawa, S. Ohtsuka, S. Ukai, H. Tanigawa, M. Fujiwara, H. Ogiwara, A. Kohyama, J.Nucl. Mater., 367-370, Part A (2007)

  22. M. A. Moghadasi, M. N-Ahmadabadi, F. Forghani, H. S. Kim, Sci. Rep., 6, (2016)

  23. M. J. Alinger, G. R. Odette, D. T. Hoelzer, Acta Mater., 57, (2009)

  24. D.J. Larson, P.J. Maziasz, I.-S. Kim, K. Miyahara, Scr. Mater. 44, 2 (2001)

    Article  Google Scholar 

  25. T. Liu, H. Shen, C. Wang, W. Chou, Prog. Nat. Sci. 23, (2013)

  26. Y. Kimura, S. Takaki, S. Suejima, R. Uemori, H. Tamehiro, ISIJ Int. 39, (1999)

  27. L. Barnard, N. Cunningham, G.R. Odette, I. Szlufarska, D. Morgan, Acta Mater. 91, (2015)

  28. P. He, T. Liu, A. Möslang, R. Lindau, R. Ziegler, J. Hoffmann, P. Kurinskiy, L. Commin, P. Vladimirov, S. Nikitenko, M. Silveir, Mater. Chem. Phys. 136, (2012)

Download references

Acknowledgements

This research was supported by the Technology Innovation Program (10048158, Development of 980 °C grade superalloys strengthened by multi-component nano-oxides for commercialization of core materials in the field of the defense industry) funded by the Ministry of Trade, Industry and Energy (MI, Korea). This research was also supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education of Korea (2016R1A6A1A03013422).

Author information

Authors and Affiliations

  1. Department of Materials Science and Engineering, Seoul National University of Science and Technology, Seoul, 01811, Republic of Korea

    Jong Min Byun

  2. Division of Materials Science and Engineering, Hanyang University, Seoul, 04763, Republic of Korea

    Chun Woong Park & Young Do Kim

  3. The Research Institute of Industrial Science, Hanyang University, Seoul, 04763, Republic of Korea

    Young Do Kim

Authors
  1. Jong Min Byun
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Chun Woong Park
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Young Do Kim
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Young Do Kim.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Byun, J.M., Park, C.W. & Do Kim, Y. Experimental Verification of the Decomposition of Y2O3 in Fe-Based ODS Alloys During Mechanical Alloying Process. Met. Mater. Int. 24, 1309–1314 (2018). https://doi.org/10.1007/s12540-018-0136-1

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12540-018-0136-1

Keywords

Search

Navigation