Skip to main content
SpringerLink
Log in

K+-enhanced electrocatalytic CO2 reduction to multicarbon products in strong acid

  • Highlight
  • Published:
Rare Metals Aims and scope Submit manuscript

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1

References

  1. Li F, Thevenon A, Rosas-Hernández A, Wang Z, Li Y, Gabardo CM, Ozden A, Dinh CT, Li J, Wang Y, Edwards JP, Xu Y, McCallum C, Tao L, Liang ZQ, Luo M, Wang X, Li H, O’Brien CP, Tan CS, Nam DH, Quintero-Bermudez R, Zhuang TT, Li YC, Han Z, Britt RD, Sinton D, Agapie T, Peters JC, Sargent EH. Molecular tuning of CO2-to-ethylene conversion. Nature. 2020;577(7791):509.

    Article  CAS  Google Scholar 

  2. Huang JE, Li F, Ozden A, Rasouli AS, Arquer FG, Liu S, Zhang S, Luo M, Wang X, Lum Y, Xu Y, Bertens K, Miao RK, Dinh CT, Sinton D, Sargent EH. CO2 electrolysis to multicarbon products in strong acid. Science. 2021;372(6546):1074.

    Article  CAS  Google Scholar 

  3. Xu S, Carter EA. Theoretical insights into heterogeneous (photo)electrochemical CO2 reduction. Chem Rev. 2019;119(11):6331.

    Article  Google Scholar 

  4. Wang N, Yao K, Vomiero A, Wang Y, Liang H. Inhibiting carbonate formation using CO2–CO–C2+ tandems. SmartMat. 2021. https://doi.org/10.1002/smm2.1048.

    Article  Google Scholar 

  5. Yang CH, Nosheen F, Zhang ZC. Recent progress in structural modulation of metal nanomaterials for electrocatalytic CO2 reduction. Rare Met. 2021;40(6):1412.

    Article  CAS  Google Scholar 

  6. Gao Z, Wang C, Li J, Zhu Y, Zhang Z, Hu W. Conductive metal-organic frameworks for electrocatalysis: achievements, challenges, and opportunities. Acta Phys-Chim Sin. 2020;37(7):2010025.

    Article  Google Scholar 

  7. Ren S, Joulié D, Salvatore D, Torbensen K, Wang M, Robert M, Berlinguette CP. Molecular electrocatalysts can mediate fast, selective CO2 reduction in a flow cell. Science. 2019;365(6541):367.

    Article  CAS  Google Scholar 

  8. Li F, Li YC, Wang Z, Li J, Nam DH, Lum Y, Luo M, Wang X, Ozden A, Hung SF, Chen B, Wang Y, Wicks J, Xu Y, Li Y, Gabardo CM, Dinh CT, Wang Y, Zhuang TT, Sinton D, Sargent EH. Cooperative CO2-to-ethanol conversion via enriched intermediates at molecule-metal catalyst interfaces. Nat Catal. 2019;3:75.

    Article  Google Scholar 

  9. Wu Y, Jiang Z, Lu X, Liang Y, Wang H. Domino electroreduction of CO2 to methanol on a molecular catalyst. Nature. 2019;575:639.

    Article  CAS  Google Scholar 

  10. Zhu Y, Cui X, Liu H, Guo Z, Dang Y, Fan Z, Zhang Z, Hu W. Tandem catalysis in electrochemical CO2 reduction reaction. Nano Res. 2021. https://doi.org/10.1007/s12274-021-3448-2.

    Article  Google Scholar 

  11. Rabinowitz JA, Kanan MW. The future of low-temperature carbon dioxide electrolysis depends on solving one basic problem. Nat Commun. 2020;11:1.

    Google Scholar 

  12. Bondue CJ, Graf M, Goyal A, Koper MTM. Suppression of hydrogen evolution in acidic electrolytes by electrochemical CO2 reduction. J Am Chem Soc. 2021;143(1):279.

    Article  CAS  Google Scholar 

  13. García AFP, Dinh CT, Ozden A, Wicks J, McCallum C, Kirmani AR, Nam DH, Gabardo C, Seifitokaldani A, Wang X, Li YC, Li F, Edwards J, Richter LJ, Thorpe SJ, Sinton D, Sargent EH. CO2 electrolysis to multicarbon products at activities greater than 1 A cm-2. Science. 2020;367(678):661.

    Article  Google Scholar 

  14. Dinh CT, Burdyny T, Kibria MG, Seifitokaldani A, Gabardo CM, Arquer FPG, Kiani A, Edwards JP, Luna PD, Bushuyev OS, Zou C, Quintero-Bermudez R, Pang Y, Sinton D, Sargent EH. CO2 electroreduction to ethylene via hydroxide-mediated copper catalysis at an abrupt interface. Science. 2018;360(6390):783.

    Article  CAS  Google Scholar 

  15. Haas T, Krause R, Weber R, Demler M, Schmid G. Technical photosynthesis involving CO2 electrolysis and fermentation. Nat Catal. 2018;1:32.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Tianjin Key Laboratory of Molecular Optoelectronic Sciences, Department of Chemistry, School of Science, Tianjin University & Collaborative Innovation Center of Chemical Science and Engineering, Tianjin, 300072, China

    Jun-Jun Li & Zhi-Cheng Zhang

Authors
  1. Jun-Jun Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Zhi-Cheng Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Zhi-Cheng Zhang.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Li, JJ., Zhang, ZC. K+-enhanced electrocatalytic CO2 reduction to multicarbon products in strong acid. Rare Met. 41, 723–725 (2022). https://doi.org/10.1007/s12598-021-01862-6

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12598-021-01862-6

Search

Navigation