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Practical development and challenges of garnet-structured Li7La3Zr2O12 electrolytes for all-solid-state lithium-ion batteries: A review

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Abstract

All-solid-state Li-ion batteries (ASSLIBs) have been widely studied to achieve Li-ion batteries (LIBs) with high safety and energy density. Recent reviews and experimental papers have focused on methods that improve the ionic conductivity, stabilize the electrochemical performance, and enhance the electrolyte/electrode interfacial compatibility of several solid-state electrolytes (SSEs), including oxides, sulfides, composite and gel electrolytes, and so on. Garnet-structured Li7La3Zr2O12 (LLZO) is highly regarded an SSE with excellent application potential. However, this type of electrolyte also possesses a number of disadvantages, such as low ionic conductivity, unstable cubic phase, and poor interfacial compatibility with anodes/cathodes. The benefits of LLZO have urged many researchers to explore effective solutions to overcome its inherent limitations. Herein, we review recent developments on garnet-structured LLZO and provide comprehensive insights to guide the development of garnet-structured LLZO-type electrolytes. We not only systematically and comprehensively discuss the preparation, element doping, structure, stability, and interfacial improvement of LLZOs but also provide future perspectives for these materials. This review expands the current understanding on advanced solid garnet electrolytes and provides meaningful guidance for the commercialization of ASSLIBs.

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Acknowledgements

This work was financially supported by the National Natural Science Foundation of China (Nos. 21701083 and 51801078), the Zhenjiang Key Laboratory of Marine Power Equipment Performance (No. SS2018006), the Postgraduate Research & Practice Innovation Program of Jiangsu Province, China (Nos. SJCX19_0612 and KYCX20_3137), and the Project of Jiangsu University (High-Tech Ship) Collaborative Innovation Center (No. 2019, 1174871801-11).

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  1. School of Energy and Power, Jiangsu University of Science and Technology, Zhenjiang, 212003, China

    Zao-hong Zhang, Tao Wei, Jia-hao Lu, Qi-ming Xiong, Yue-han Ji, Zong-yuan Zhu & Liu-ting Zhang

  2. Institute of Mechanics and Energy, National Research Ogarev Mordovia State University, Saransk, 430000, Russia

    Qi-ming Xiong

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Zhang, Zh., Wei, T., Lu, Jh. et al. Practical development and challenges of garnet-structured Li7La3Zr2O12 electrolytes for all-solid-state lithium-ion batteries: A review. Int J Miner Metall Mater 28, 1565–1583 (2021). https://doi.org/10.1007/s12613-020-2239-1

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