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Electroless Nickel Plating – A Review

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Abstract

The operating process, versatility and the increasing research interest in optimising the process and products technology in the electroless plating method of metal coating, particularly, the electroless nickel plating of metallic substrates such as mild steel, necessitates the writing of this review. It is also aimed at providing more literature information, both of the past and the present published research in this field. In this paper, electroless nickel plating is introduced. The various nickel plating solutions and baths’ operating parameters; main types of electroless nickel plating; the mechanism involved in the plating process; application of the nickel plating process to iron powders; advantages and disadvantages and the process’s other applications are reviewed. Electroless nickel plating produces an amorphous deposit in the as-plated condition. The deposit is not dependent on current distribution and hence it is almost uniform in thickness. Electroless nickel plating is far more difficult to remove chemically than conventional nickel deposits due to its superior corrosion resistance. The deposit has a good wettability and is generally hard. However, its bath control is more complex than with electroplating. The bath also has lower efficiency and higher operating costs, even without the use of electricity.

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References

  1. Schlesinger M (2010) Modern electroplating, 5th edn. John Wiley & Sons Inc

  2. Osifuye C O, Popoola A P I, Loto C A, Oloruntoba D T (2014) Int J Electrochem Sci 9:109

    Google Scholar 

  3. Loto C A (1989) Can Metall Q 28(3):259

    Article  CAS  Google Scholar 

  4. Paul S. Electroless plating, Plating, Inc. http://www.corrosion-doctors.org/metalcoatings/Electroless.htm (Retrieved: 11-04-2015)

  5. Wikipedia (2008) Electroless nickel plating. http:/en.wikipedia.org/wiki/Electroless_nickel_plating

  6. Electro Coatings Electroless Nickel Plating. http://www.electro-coatings.com/electroless-nickel-plating.php

  7. Palaniappa M, Seshadri S K (2008) Science direct, Wear 265:735

    CAS  Google Scholar 

  8. Sotskaya N V, Ryabinina E I, Kravchenko T A, Shikhaliev K S (2003) Prot Met 39(3):250

    Article  CAS  Google Scholar 

  9. Shusheng Z, Han K, Cheng L (2007) Surf Coat Technol 202:2807

    Google Scholar 

  10. Osifuye C O (2014) Electrochemical corrosion resistance of electroless plated mild steel, M.Tech Dissertation, Department of Chemical, Metallurgical & Materials Engineering, Tshwane University of Technology, Pretoria, South Africa

  11. Sahoo P, Kalyan S D (2011) Mater Des 32(4):1760

    Article  CAS  Google Scholar 

  12. Li L, An M (2008). J Alloys Compd 461:85

    Article  CAS  Google Scholar 

  13. Molla H R, Modarress H, Abdouss M (2012) J Coat Technol Res 9(2):183

    Article  CAS  Google Scholar 

  14. Bulasara V K, Thakuria H, Uppaluri R, Purkait M K (2011) Desalination 268:195

    Article  CAS  Google Scholar 

  15. Abdel-Salam H, Shoeib M A, Hady H, Abdel-Salam O F (2008) J Appl Electrochem 38:385

    Article  Google Scholar 

  16. Hari K K, John S, Srinivasan K N, Praveen J, Kavimani M, Ganesan P M (2006) Metall Matls Trans A 37A:1917

    Google Scholar 

  17. Brenner A, Riddell G E (1947) Proc Am Electroplaters Soc 34:156

    Google Scholar 

  18. Agarwala R C, Agarwala V (2003) Sadhana 28:475–493

    Article  CAS  Google Scholar 

  19. Tarozaite R (2005) CHEMIJA, T.H. I:8

    Google Scholar 

  20. Parker K (1992) Met Finish 79:29

    CAS  Google Scholar 

  21. Lo P H, Tsai W T, Lee J T, Hung M P (1994) Surf Coat Technol 67:27

    Article  CAS  Google Scholar 

  22. Far J P G, Noahani A A (1996) Trans IMF 74:221

    Google Scholar 

  23. Balaraju J H, Seshadri S K (1999) Met Finish 97:8

    Article  CAS  Google Scholar 

  24. Younan M M, Shoeib M (2002) Galvanotechnik 93:932

    CAS  Google Scholar 

  25. Keong K G, Sha W, Malinov S (2003) Surf Coat Technol 168:263

    Article  CAS  Google Scholar 

  26. Loto C A (1987) J Metals 39(8):36

    CAS  Google Scholar 

  27. Chen C-H, Chen B-H (2006) Chem Mater 18(13):2959

    Article  CAS  Google Scholar 

  28. Gabe D R (1978) Principles of Metal Surface-Treatment and Protection. Pergamon Press, p 73

  29. Burns R M, Bradley W W (1967) Protective Coatings for Metals. Reinhold Publishing Corporation, New York, pp 229–230

    Google Scholar 

  30. Park S H, Lee D N (1988) J Matls Sci 23:1643

    Article  CAS  Google Scholar 

  31. Minjer C H, Brenner A (1975) Plating 44:1297

    Google Scholar 

  32. Spencer LF (1974) Metal Fin 72:58

    Google Scholar 

  33. Loto C A (1982) A Sudy of Electroless Nickel Plating of Iron Powders. M.Sc. Dissertation, Brunel University, Uxbridge, Middx., London, UK

  34. Canning W (1978) The Canning Handbook on electroplating, 20th Edn, pp 425–429

  35. Hammond R A F (1972) Met Fin J 18:3

    Google Scholar 

  36. Fanner D A, Hammond R A F (1959) Trans Met Fin 36:32

    CAS  Google Scholar 

  37. Saubestre E B (1958) Plating 45:927

    CAS  Google Scholar 

  38. Roehl E J, Wesley W A (1950) Plating 37:142

    CAS  Google Scholar 

  39. Uhlig H H, Revie R W (1985) Corrosion and corrosion control: an introduction to corrosion science and engineering, 3rd edn. Wiley, New York

    Google Scholar 

  40. Brenner A, Riddell G E (1947) Proc Am Electroplaters Soc 34:156

    Google Scholar 

  41. Holbrook K A, Twish P J (1969) Plating 56:523

    CAS  Google Scholar 

  42. Mijner C H (1975) Electrodeposition & Surface Treatment 3(4):261

    Article  Google Scholar 

  43. Gonda V K, Shawki S, El-Tawil H (1972) Met Finish 5:77

    Google Scholar 

  44. Song Y W, Shan D Y, Han E H (2008) Electrochemic Acta 53:2135

    Article  CAS  Google Scholar 

  45. Ashassi-Sorkhabi A, Rafizadeh S H (2004) Surf Coat Technol 576:318

    Article  Google Scholar 

  46. Lee C K (2008) Surf Coat Technol 202(19):4868

    Article  CAS  Google Scholar 

  47. Ma H, Liu Z, Tian F, Huan S (2008) J Alloys Compd 450:348

    Article  CAS  Google Scholar 

  48. Balaraju J H, Rajam K S (2008) J Alloys Compd 459:311

    Article  CAS  Google Scholar 

  49. Chen C K, Feng H M, Liu H C, Hon M H (2002) Thin Solid Films 416:31

    Article  CAS  Google Scholar 

  50. Zhu X-y, Guo Z-C, Zhai D (2001) Chinese Surf Eng,14, 01 (http://209.85.227.132/translate_c?hl)

  51. Hong Z, Zi L, Qiang S (2008). Power Supply Techno 328 09 (http://209.85.227.132/translate_c?hl)

  52. Yin-Ray, Chen Y-M, Hu H (2004). Material Protection 37, 01 (http://209.85.227.132/translate_c?hl)

  53. Wu H, Li T-Ch, Li X (2008). Electroplating and Finishing, 30-10 (http://209.85.227.132/translate)

  54. Lobanova L L, Batalova E V, Khranilov Y P (2008) Russ J Appl Chem 81(2):202

    Article  CAS  Google Scholar 

  55. Yin X, Hong L, Chen B, Ko T M (2003) J Colloid Interf Sci Elsevier Sci 262(1):89

    Article  CAS  Google Scholar 

  56. Jothi S, Lian J, Wei S (2013) J Alloys Compd 571:183

    Article  Google Scholar 

  57. Guo R H, Jiang S X, Yuen C W M, Ng M C F, Lan J W, Zheng G H (2012) Fibers and Polymers 13(8):1037

    Article  CAS  Google Scholar 

  58. Chen Z, Xiaoda X, Chee C W, Subodh M (2003) Surf Coat Technol 167:170

    Article  CAS  Google Scholar 

  59. Braun F, Ana M T, Laura M C (2011) J Membrane Sci 382:252

    Article  CAS  Google Scholar 

  60. Wanin, Kohn (1979) Int J of P/M and Powder Techn 15:16

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Loto, C.A. Electroless Nickel Plating – A Review. Silicon 8, 177–186 (2016). https://doi.org/10.1007/s12633-015-9367-7

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