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Application of Magnetic ordered mesoporous carbon Nanocomposite for the Removal of Ponceau 4R Using Factorial Experimental Design

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Abstract

Nanocomposites of ordered mesoporous carbon with silica coated magnetite nanoparticles (Fe3O4@SiO2-CMK-8, MNCs) were synthesized by carbonizing sucrose inside the pores of the Kit-6 mesoporous silica and used to remove Ponceau 4R from aqueous solutions. The synthesized adsorbent was characterized by Fourier Transform Infrared (FT-IR) spectroscopy, X-ray diffraction (XRD), scanning electron microscope (SEM), and Transmission electron microscope (TEM). In order to survey the effective parameters on dye removal efficiency, the factorial design was applied. At the optimum conditions (pH: 2, adsorbent dosage: 0.1 g, contact time: 20 min and ionic strength: 0.05 mol L−1), the evaluation of four isotherm models was carried out and isotherm data were matched well with Freundlich model (R2 = 0.9988, n = 1.633). Kinetic studies showed that the adsorption of Ponceau 4R was better represented by the pseudo-second order kinetics (R2 > 0.999). Finally, the obtained results of real samples showed that the Fe3O4@SiO2-CMK-8 nanocomposite is an effective adsorbent for the rapid removal of Ponceau 4R from aqueous solutions.

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Acknowledgements

The authors are grateful to Rasht Branch, Islamic Azad University and the Guilan Science & Technology Park, Guilan, Iran for supporting this work.

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Authors and Affiliations

  1. Department of Chemistry, Arak Branch, Islamic Azad University, Arak, Iran

    Sanaz Toutounchi & Kazem Mahanpoor

  2. Department of Chemistry, Rasht Branch, Islamic Azad University, Rasht, Iran

    Shahab Shariati

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  1. Sanaz Toutounchi
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Correspondence to Shahab Shariati.

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Toutounchi, S., Shariati, S. & Mahanpoor, K. Application of Magnetic ordered mesoporous carbon Nanocomposite for the Removal of Ponceau 4R Using Factorial Experimental Design. Silicon 13, 1561–1573 (2021). https://doi.org/10.1007/s12633-020-00535-w

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