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Integrating multivariate statistical analysis with GIS for geochemical assessment of groundwater quality in Shiwaliks of Punjab, India

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Abstract

The dependency of people on groundwater has increased in the past few decades due to tremendous increase in crop production, population and industrialization. Groundwater is the main source of irrigation in Shiwaliks of Punjab. In the present study the samples were collected from predetermined location as was located on satellite image on basis of spectral reflectance. Global positioning system was used to collect samples from specific locations. Principal components analysis (PCA) together with other factor analysis procedures consolidate a large number of observed variables into a smaller number of factors that can be more readily interpreted. In the present study, concentrations of different constituents were correlated based on underlying physical and chemical processes such as dissociation, ion exchange, weathering or carbonate equilibrium reactions. The PCA produced six significant components that explained 78% of the cumulative variance. The concentration of the few trace metals was found to be much higher indicating recharge due to precipitation as main transport mechanism of transport of heavy metals in groundwater which is also confirmed by PCA. Piper and other graphical methods were used to identify geochemical facies of groundwater samples and geochemical processes occurring in study area. The water in the study area has temporary hardness and is mainly of Ca–Mg–HCO3 type.

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References

  • American Public Health Association (APHA) (1995) Standard methods for the examination of water and waste water, 19th edn. American Public Health Association, Washington, DC

    Google Scholar 

  • Ashley RP, Lloyd JW (1978) An example of the use of factor analysis and cluster analysis in ground water chemistry interpretation. J Hydrol 39:355–364

    Article  Google Scholar 

  • Bhatt CM, Litoria PK, Sharma PK (2008) Geomorphic signatures of active tectonics in Bist Doab Interfluvial Tract of Punjab, NW India. J. Indian Soc. Remote Sens. 36:361–373

    Article  Google Scholar 

  • Burrough PA, McDonnell RA (1998) Principles of geographical information systems for land resources assessment. Oxford University Press, New York

    Google Scholar 

  • Chadha DK (1999) A proposed new diagram for geochemical classification of natural waters and interpretation of chemical data. J Hydrogeol 7:431–439

    Article  Google Scholar 

  • Dalton MG, Upchurch SB (1978) Interpretation of hydrochemical facies by factor analysis. Groundwater 16:228–233

    Google Scholar 

  • Datta PS, Bhattacharya SK, Tyagi SK (1996) 18O studies on recharge of phreatic aquifers and groundwater flow-paths of mixing in the Delhi area. J Hydrol 176:25–36

    Article  Google Scholar 

  • Davis JC (2002) Statistics and data analysis in geology. Wiley, Singapore

    Google Scholar 

  • Dawdy DR, Feth JH (1967) Applications of factor analysis in study of chemistry of groundwater quality, Mojave River Valley, California. Water Resour Res 3:505–510

    Article  Google Scholar 

  • Douglas EB, Leo WN (1977) Hydrogeochemical relationships using partial correlation coefficient. Water Resour Bull 13:843–846

    Google Scholar 

  • Farnham IM, Johannesson KH, Singh AK, Hodge VF, Stetzenbach KJ (2003) Factor analytical approaches for evaluating ground water trace element chemistry data. Anal Chim Acta 490(1):123–138

    Article  Google Scholar 

  • Fetter CW (1994) Applied hydrogeology, 3rd edn. Prentice–Hall, New York

    Google Scholar 

  • Freeze RA, Cherry JA (1979) Groundwater. Prentice–Hall, Englewood Cliffs, p 604

    Google Scholar 

  • Guan W, Chamberlain RH, Sabol BM, Doeringand PH (1999) Mapping submerged aquatic vegetation in the Caloosahatchee Estuary: evaluation of different interpolation methods. Mar Geod 22:69–91

    Article  Google Scholar 

  • Güler C, Thyne DG, McCray JE, Turner AK (2002) Evaluation of graphical and multivariate statistical methods for classification of water chemistry data. J Hydrogeol 10(4):455–474

    Article  Google Scholar 

  • Guo H, Wang Y (2004) Hydrogeochemical processes in shallow quaternary aquifers from the northern part of the Datong Basin, China. J App Geochem 19:19–27

    Article  Google Scholar 

  • Gupta SK, Deshpande RD (2004) Water for India in 2050: first-order assessment of available options. Curr Sci 86:1216–1223

    Google Scholar 

  • Handa BK (1986) Trace elements content of groundwater in the basaltic rocks in some parts of Indian Peninsula. In: Power KB, Thigale SS (eds) Hydrogeology of volcanic terranes. University of Poona, Pune, pp 83–104

    Google Scholar 

  • Heinrich EWM (1948) Fluorite-rare earth mineral pegmatites of Chaffee and Fremont Counties, Colorado University of Michigan, Ann Arbor, Michigan. Am Mineral 33:64–75

    Google Scholar 

  • Hem JD (1985) Study and interpretation of the chemical characteristics of natural water. US Geological Survey Water Supply Paper 2254

  • Hounslow AW (1995) Water quality data analysis and interpretation. CRC Press, Boca Raton

    Google Scholar 

  • Jankowski J, Acworth RI (1997) Impact of debris-flow deposits on hydrogeochemical processes and the development of dryland salinity in the Yass River catchment, New South Wales, Australia. J Hydrogeol 5(4):71–88

    Article  Google Scholar 

  • Khan AU (1984) Report on quaternary geological and geomorphological mapping and study of fluvial processes in Satluj river basin in parts of Ropar and Hoshiarpur districts. Punjab Geological Survey of India, Northern Region, Lucknow

    Google Scholar 

  • Khan Y, Hussain SA, Hossain MS, Hossain SMG, Hallimuzzaman AHM (1998) An environmental assessment of trace metals in Ganges–Brahamputra–Meghna Estuary. J Remote Sens Environ 2:103–117

    Google Scholar 

  • Kister LR, Hardt WF (1966) Salinity of groundwater In: Western Pinal County, Arizona. Geological Survey Water Supply Paper 1919-E, US Govt. Printing Office, Washington, DC, pp 11–15

  • Kunwar PS, Malik A, Singh VK, Mohan D, Sinha S (2005) Chemometric analysis of groundwater quality data of alluvial aquifer of Gangetic plain, North India. Anal Chim Acta 550:82–91

    Article  Google Scholar 

  • Lawrence FW, Upchruch SB (1982) Identification of recharge areas using geochemical factor analysis. Groundwater 20:680–687

    Google Scholar 

  • Mahloch JL (1974) Multivariate techniques for water quality analysis. J Environ Eng Div Am Soc Civil Eng, 100, No. EE5:1119–1132

    Google Scholar 

  • Mathes SE, Rasmussen TC (2006) Combining multivariate statistical analysis with geographic information systems mapping: a tool for delineating groundwater contamination. J Hydrogeol 14:1493–1507

    Article  Google Scholar 

  • Matthess G (1982) The properties of groundwater. Wiley, New York

    Google Scholar 

  • Mazlum N, Ozer A, Mazlum S (1996) Interpretation of water quality data by principal components analysis. J Eng Environ Sci 23:19–26

    Google Scholar 

  • Mehrotra P, Mehrotra S (2000) Pollution of groundwater by manganese in Hindon–Yamuna Doab (Noida area) District, Ghaziabad. In: Proceedings of the international seminar on applied hydrogeochemistry, Annamalai University, pp 106–112

  • Meybeck M (1987) Global chemical weathering of surficial rocks estimated from river dissolved loads. Am J Sci 287:401–428

    Article  Google Scholar 

  • Miller DW (1985) Ground water quality. Wiley-Interscience, New York

    Google Scholar 

  • Mueller TG, Pusuluri NB, Mathias KK, Cornelius PL, Barnhisel RI, Shearer SA (2004) Map quality for ordinary kriging and inverse distance weighted interpolation. Soil Sci Soc Am J 68:2042–2047

    Article  Google Scholar 

  • Naidu AS, Mowatt TC, Somayajulu BKL, Sreeramachandra Rao K (1985) Characteristics of clay minerals in the bed loads of major rivers of India. In: Degens ET, Kempe S, Herrera R (eds) Transport of carbon and minerals in major world rivers, part 3, SCOPE/UNEP, Special issue 58, Mitt Geol Palaont Inst Univ Hamburg, Hamburg, pp 559–568

  • Noy-Meir I (1973) Data transformations in ecological ordination. I. Some advantages of non-centering. J Ecol 61:329–341

    Article  Google Scholar 

  • Piper AM (1944) A graphic procedure in the chemical interpretation of water analysis. Am Geophys Union Trans 25:914–923

    Google Scholar 

  • Praus P (2005) Water quality assessment using SVD-based principal component analysis of hydrological data. Water SA 31(4):417–422

    Google Scholar 

  • Rajmohan N, Elango L (2004) Identification and evolution of hydrogeochemical processes in the groundwater environment in an area of the Palar and Cheyyar River Basins, Southern India. Environ Geol 46:47–61

    Google Scholar 

  • Rama Rao NV (1982) Geochemical factors influencing the distribution of fluoride in the rocks, soil and water sources of Nalgonda district. AP thesis, Osmania University, Hyderabad

  • Rani VR (2007) Ground water information booklet Ropar district. CGWB, Ministry of Water Resources, Punjab

    Google Scholar 

  • Reghunath R, Murthy TRS, Raghavan BR (2002) The utility of multivariate statistical techniques in hydrogeochemical studies: an example from Karnataka, India. Water Res 36:2437–2442

    Article  Google Scholar 

  • Romesburg HC (1984) Clustering analysis for researchers. Lifetime Learning Publications, Belmont, CA, USA

    Google Scholar 

  • Sandow MY (2009) The hydrochemical framework of surface water basins in southern Ghana. Environ Geol 57:789–796

    Article  Google Scholar 

  • Schoeller H (1965) Qualitative evaluation of groundwater resource. In: Methods and techniques of ground-water investigation and development. UNESCO, pp 54–83

  • Schroeder HA (1960) Relation between mortality from cardiovascular disease and treated water supplies. J Am Med Assoc 172:1902–1908

    Google Scholar 

  • Shanyengana MK, Seely MK, Sanderson RD (2004) Major-ion chemistry and groundwater salinization in ephemeral floodplains in some arid regions of Namibia. J Arid Env 57:71–83

    Article  Google Scholar 

  • Singh M, Ansari AA, Müller G, Singh IB (1997) Heavy metals in freshly deposited sediments of the Gomati River (a tributary of the Ganga River): effects of human activities. Environ Geol 29 (3/4)

  • Singh SK, Singh CK, Kewat SK, Gupta R, Mukherjee S (2009) Spatial–temporal monitoring of groundwater using multivariate statistical techniques in Bareilly district of Uttar Pradesh, India. J Hydrol Hydromech 57(1):45–54

    Google Scholar 

  • Singh SK, Singh CK, Mukherjee S (2010) Impact of land-use and land-cover change on groundwater quality in the Lower Shiwalik Hills: a remote sensing and GIS-based approach. Cent Eur J Geosci 2:124–131

    Article  Google Scholar 

  • Srinivasamoorthy K, Chidambaram S, Prasanna MV, Vasanthavihar M, Peter J, Anandhan P (2008) Identification of major sources controlling groundwater chemistry from a hard rock terrain—a case study from Mettur taluk, Salem district, Tamil Nadu, India. J Earth Syst Sci 117(1):49–58

    Google Scholar 

  • Subba Rao N (2002) Geochemistry of groundwater in parts of Guntur district, Andhra Pradesh, India. Environ Geol 41:552–562

    Article  Google Scholar 

  • Subramani T, Elango L, Damodarasamy SR (2005) Groundwater quality and its suitability for drinking and agricultural use in Chithar River Basin, Tamil Nadu, India. J Environ Geol 47:1099–1110

    Article  Google Scholar 

  • Suk H, Lee KK (1999) Characterization of a groundwater hydrochemical system through multivariate analysis: clustering into groundwater zones. Groundwater 37(3):358–366

    Google Scholar 

  • Tabachnick BG, Fidell LS (1996) Using multivariate statistics, 3rd edn. Harper Collins College Publishers, New York

    Google Scholar 

  • Tabios GQ, Salas JD (1985) A comparative analysis of techniques for spatial interpolation of precipitation. Water Resour Bull 21:365–380

    Google Scholar 

  • Thyne G, Güler C, Poeter E (2004) Sequential analysis of hydrochemical data for watershed characterization. Ground Water 42(5):711–723

    Article  Google Scholar 

  • Tomczak M (1998) Spatial interpolation and its uncertainty using automated anisotropic inverse distance weighting (IDW)—cross-validation/jackknife approach. J Geogr Inform Decis Anal 2:18–30

    Google Scholar 

  • Woocay A, Walton J (2008) Multivariate analyses of water chemistry: surface and ground water interactions. Ground Water 46(3):437–449

    Article  Google Scholar 

Download references

Acknowledgments

The author (C.K.S.) thanks Satpal Mittal Trust for providing financial support to carry out the research work and P.N. Singh of CGWB, Ministry of Water Resources, for his help, valuable suggestions and encouragement.

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Authors and Affiliations

  1. School of Environmental Sciences, Jawaharlal Nehru University, New Delhi, 110067, India

    Chander Kumar Singh, Satyanarayan Shashtri & Saumitra Mukherjee

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  1. Chander Kumar Singh
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  2. Satyanarayan Shashtri
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  3. Saumitra Mukherjee
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Correspondence to Saumitra Mukherjee.

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Singh, C.K., Shashtri, S. & Mukherjee, S. Integrating multivariate statistical analysis with GIS for geochemical assessment of groundwater quality in Shiwaliks of Punjab, India. Environ Earth Sci 62, 1387–1405 (2011). https://doi.org/10.1007/s12665-010-0625-0

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