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Geochemical processes and multivariate statistical analysis for the assessment of groundwater quality in the Swarnamukhi River basin, Andhra Pradesh, India

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Abstract

With rapid increase of human population, swift growth of industries and intensive irrigation activities, groundwater quality is being increasingly endangered by agricultural chemicals and indiscriminate disposal of urban and industrial wastes. Hence, in water management, assessment of groundwater quality is as important as quantity especially in the arid and semi-arid regions. Evaluation of hydrogeochemical parameters and solute acquisition process controlling water chemical composition was studied by collecting 66 groundwater samples in pre-monsoon and post-monsoon seasons in the Swarnamukhi River basin, Andhra Pradesh, India. Geologically, the study area comprises granite and granitic gneisses, quartzite and alluvium. The total dissolved solids classification reveals that majority of the groundwater samples are desirable for drinking, and all are useful for irrigation purposes. Major ion chemistry reveals the ionic dominance pattern among cations and anions is in the order: Na > Ca > Mg > K and Cl > HCO3 > NO3 > SO4 > CO3 > F > PO4 in both the seasons. 85 and 89 % of samples are very hard water in pre- and post-monsoon, respectively which needs softening for domestic uses. 48 and 42 % and 34 and 41 % of the samples of the study area are found having sodium (200 mg/l) and nitrate content (50 mg/l) in pre- and post-monsoon seasons, respectively, more than permissible limits which is not good for human consumption. Natural and anthropogenic sources of the solutes have been categorized with the help of different ionic ratios, plots and correlation matrix. Potential salinity sources include deep saline upcoming and wastewater infiltration. Salinity mapping shows brackish to fresh brackish water predominance in the study area. The plot of major ion in the Piper diagram reveals that majority of samples belongs to mixed type followed by Na–Cl facies. Four principal components were extracted from chemical data to explain the major sources and processes responsible for chemical characteristics of groundwater. It shows that silicate weathering, agricultural runoff (fertilizer input), municipal wastewater infiltration play a vital role in the enrichment of ionic constituents. Average water quality index shows that majority of the samples are good to permissible for drinking purpose. Various irrigation indices show good to permissible use of groundwater in agricultural activities. As per the LSI and RSI values, groundwater of the area is considered very aggressive and substantial corrosion is possible.

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References

  • Abdesselam S, Halitim A, Jan A, Trolard F, Bourrié G (2013) Anthropogenic contamination of groundwater with nitrate in arid region: case study of southern Hodna (Algeria). Environ Earth Sci 70:2129–2141

    Article  Google Scholar 

  • Adams S, Titus R, Pietersen K, Tredoux G, Harris C (2001) Hydrochemical characteristics of aquifers near Sutherland in the Western Karoo, South Africa. Hydrogeology 241:91–103

    Article  Google Scholar 

  • Alam M, Rais S, Aslam M (2011) Hydrochemical investigation and quality assessment of ground water in rural areas of Delhi, India. Environ Earth Sci 66:97–110

    Article  Google Scholar 

  • Alaya M Ben, Saidi S, Zemni T, Zargouni F (2014) Suitability assessment of deep groundwater for drinking and irrigation use in the Djeffara aquifers (Northern Gabes, south-eastern Tunisia). Environ Earth Sci 71:3387–3421

    Article  Google Scholar 

  • APHA (2005) Standard methods for the examination of water and wastewater, 21st edn. American Public Health Association, Washington, DC

    Google Scholar 

  • Appelo CAJ, Postma D (1996) Geochemistry, groundwater and pollution. Balkema, Rotterdam

    Google Scholar 

  • Appelo CAJ, Postma D (1999) Geochemistry, groundwater and pollution, 4th edn. Balkema, Rotterdam 536

    Google Scholar 

  • ASTM (1998) Standard practice for calculation and adjustment of the Langelier saturation index for reverse osmosis. D 3739–D 3794

  • Bhupal KM, Reddy BR (2013) Analysis of ground water potential in Chandragiri mandal, Chittoor district, Andhra Pradesh. Adv Appl Sci Res 4(4):255–265

    Google Scholar 

  • CGWB (2013) Dynamic ground water resources of India. Ministry of Water Resources, Govt. of India, Central Ground Water Board

  • Davis SN, De Wiest RJM (1966) Hydrogeology. Wiley, New York, p 463

    Google Scholar 

  • Doneen LD (1964) Notes on water quality in agriculture, Published as a Water Science and Engineering Paper 4001, Department of Water Sciences and Engineering, University of California

  • Eaton FM (1950) Significance of carbonate in irrigation waters. Soil Sci 69(2):123–133

    Article  Google Scholar 

  • Freeze RA, Cherry JA (1979) Groundwater. Prentice Hall, Engle wood Cliffs, p 604

    Google Scholar 

  • Ghabayen SMS, Mc Kee M, Kemblowski M (2006) Identification of salinity sources and missing data in the Gaza aquifer. J Hydrol 318:360–373

    Article  Google Scholar 

  • Gibbs RJ (1970) Mechanisms controlling world’s water chemistry. Science 170:1088–1090

    Article  Google Scholar 

  • Gillardet J, Dupre B, Louvat P, Allegre CJ (1999) Global silicate weathering and CO2 consumption rates deduced from the chemistry of large rivers. Chem Geol 159:3–10

    Article  Google Scholar 

  • Goff JP (2006) Macromineral physiology and application to the feeding of the dairy cow for prevention of milk fever and other periparturient mineral disorders. Anim Feed Sci Technol 126:237–257

    Article  Google Scholar 

  • Han G, Liu CQ (2004) Water geochemistry controlled by carbonate dissolution: a study of the river waters draining Karst-dominated terrain, Guizhou province, China. Chem Geol 204:1–21

    Article  Google Scholar 

  • Handa BK (1975) Environmental pollution, occurrence of high nitrate ion concentration in groundwater from some parts of India. Int Assoc Hydrogeol Congr de Montpellier 10:80–85

    Google Scholar 

  • Hounslow AW (1995) Water quality data: analysis and interpretation. CRC Lewis Publishers, Boca Raton, pp 86–87

    Google Scholar 

  • Iranmanesh A, Locke RA II, Wimmer BT (2014) Multivariate statistical evaluation of groundwater compliance data from the Illinois Basin—Decatur Project. Energy Proceedia 63:3182–3194

    Article  Google Scholar 

  • Jalali M (2009) Geochemistry characterization of groundwater in an agricultural area of Razan, Hamadan, Iran. Environ Geol 56:1479–1488

    Article  Google Scholar 

  • Jankowski J, Acworth RI (1997) Impact of debris- flow deposits on hydrogeochemical process and the development of dry land salinity in the Yass River catchment, New South Wales, Australia. Hydrogeol J 5:71–88

    Article  Google Scholar 

  • Jasmin I, Murali T, Mallikarjuna P (2010) Statistical analysis of groundwater table depths in upper Swarnamukhi River basin. J Water Resour Protect 2(6):577–584

    Article  Google Scholar 

  • Jiang Y, Wu Y, Groves C, Yuan D, Kambesis P (2009) Natural and anthropogenic factors affecting the groundwater quality in the Nandong karst underground river system in Yunan, China. J Contam Hydrol 109:49–61

    Article  Google Scholar 

  • Jianhua S, Qi F, Xiaohu W, Yonghong S, Haiyang X, Zongqiang C (2009) Major ion chemistry of groundwater in the extreme arid region northwest China. Environ Geol 57:1079–1087

    Article  Google Scholar 

  • Karanth KR (1997) Groundwater assessment, development and management. McGraw-Hill, New Delhi

    Google Scholar 

  • Kelly WP (1940) Permissible composition and concentration of irrigated waters. In: Proceeding of the ASCF 66, p 607

  • Khairy H, Janardhana MR (2013) Hydrogeochemical features of groundwater of semi-confined coastal aquifer in Amol-Ghaemshahr plain, Mazandaran Province, Northern Iran. Environ Monit Assess 185:9237–9264

    Article  Google Scholar 

  • Khashogji MS El, Maghraby MMS (2013) Evaluation of groundwater resources for drinking and agricultural purposes, Abar Al Mashi area, south Al Madinah Al Munawarah City, Saudi Arabia. Arab J Geosci 6:3929–3942

    Article  Google Scholar 

  • Kim KH, Yun ST, Mayer B, Lee JH, Kim TS, Kim HK (2015) Quantification of nitrate sources in groundwater using hydrochemical and dual isotopic data combined with a Bayesian mixing model. Agric Ecosyst Environ 199:369–381

    Article  Google Scholar 

  • Kumar M, Sharma B, Ramanathan AL, Rao MS, Kumar B (2009) Nutrient chemistry and salinity mapping of the Delhi aquifer, India : source identification perspective. Environ Geol 56:1171–1181

    Article  Google Scholar 

  • Kumar SK, Bharani R, Magesh NS, Godson PS, Chandrasekar N (2014) Hydrogeochemistry and groundwater quality appraisal of part of south Chennai coastal aquifers, Tamil Nadu, India using WQI and fuzzy logic method. Appl Water Sci 4:341–350

    Article  Google Scholar 

  • Latha PS, Rao KN (2012) An integrated approach to assess the quality of groundwater in a coastal aquifer of Andhra Pradesh, India. Environ Earth Sci 66:2143–2169

    Article  Google Scholar 

  • Metcalf and Eddy Inc. (2000) Integrated aquifer management plan: final report. Gaza Coastal Aquifer Management Program, USAID Contract No. 294-C-00-99-00038-00

  • Meybeck M (1987) Global chemical weathering of surficial rocks estimated from river dissolved loads. Am J Sci 287:401–428

    Article  Google Scholar 

  • Paliwal KV (1967) Effect of gypsum application on the quality of irrigation waters. Madras Agric J 59:646–647

    Google Scholar 

  • Piper AM (1944) A graphic procedure in the geochemical interpretation of water-analyses. Trans Am Geophys Union 25:914–923

    Article  Google Scholar 

  • Raju NJ (2007) Hydrogeochemical parameters for assessment of groundwater quality in the upper Gunjanaeru River basin, Cuddapah District, Andhra Pradesh, South India. Environ Geol 52:1067–1074

    Article  Google Scholar 

  • Raju NJ (2012) Evaluation of hydrogeochemical processes in the Pleistocene aquifers of Middle Ganga Plain, Uttar Pradesh, India. Environ Earth Sci 65:1291–1308

    Article  Google Scholar 

  • Raju NJ, Ram P, Dey S (2009) Groundwater quality in the lower Varuna River basin, Varanasi district, Uttar Pradesh. J Geol Soc India 73:178–192

    Article  Google Scholar 

  • Raju NJ, Shukla UK, Ram P (2011) Hydrogeochemistry for the assessment of groundwater quality in Varanasi: a fast-urbanizing center in Uttar Pradesh, India. Environ Monit Assess 173:279–300

    Article  Google Scholar 

  • Raju NJ, Dey S, Gossel W, Wycisk P (2012) Fluoride hazard and assessment of groundwater quality in the semi-arid Upper Panda River basin, Sonbhadra district, Uttar Pradesh, India. Hydrol Sci J 57:1433–1452

    Article  Google Scholar 

  • Raju NJ, Ram P, Gossel W (2014) Evaluation of groundwater vulnerability in the Lower Varuna Catchment Area, Uttar Pradesh, India using AVI Concept. J Geol Soc India 83:273–278

    Article  Google Scholar 

  • Raju NJ, Chaudhary A, Nazneen S, Singh S, Goyal A (2015) Hydrogeochemical investigation and quality assessment of groundwater for drinking and agricultural use in JNU, New Delhi, India. In: Raju NJ (ed) Management of natural resources in a changing environment. Springer, Berlin, pp 3–27. doi:10.1007/978-3-319-12559-6

    Google Scholar 

  • Rasouli F, Pouya AK, Cheraghi SAM (2012) Hydrogeochemistry and water quality assessment of the Kor-Sivand Basin, Fars province, Iran. Environ Monit Assess 184:4861–4877

    Article  Google Scholar 

  • Reddy MR, Raju NJ, Reddy YV, Reddy TVK (2000) Water resource development and management in the Cuddapah district, Andhra Pradesh, India. Environ Geol 39:342–352

    Article  Google Scholar 

  • Ryznar JW (1944) A new index for determining the amount of calcium carbonate scale formed by water. J Am Water Works Assoc 36(3):472–494

    Google Scholar 

  • Saini RK, Chakrapani GJ, Sen AK (2006) Geochemical studies of groundwater in Saharanpur, Uttar Pradesh. J Geol Soc India 68:50–58

    Google Scholar 

  • Saleh A, Al-Ruwaih F, Shehata M (1999) Hydrogeochemical processes operating within the main aquifers of Kuwait. J Arid Environ 42:195–209

    Article  Google Scholar 

  • Sami K (1992) Recharge mechanisms and geochemical processes in a semi-arid sedimentary basin, Eastern cape, South Africa. J Hydrol 139:27–48

    Article  Google Scholar 

  • Sawyer GN, Mc Cartly DL (1967) Chemistry of sanitary engineers, 2nd edn. McGraw Hill, New York 518

    Google Scholar 

  • Singh S, Raju NJ, Ramakrishna Ch (2015a) Evaluation of groundwater quality and its suitability for domestic and irrigation use in parts of the Chandauli-Varanasi region, Uttar Pradesh, India. J Water Resour Protect 7:482–497

    Article  Google Scholar 

  • Singh S, Raju NJ, Gossel W, Wycisk P (2015b) Assessment of pollution potential of leachate from the municipal solid waste disposal site and its impact on groundwater quality, Varanasi environs, India. Arab J Geosci (accepted)

  • Soltan ME (1999) Evaluation of groundwater quality in Dakhla oasis (Egyptian western desert). Environ Monit Assess 57:157–168

    Article  Google Scholar 

  • Srinivasamoorthy K, Gopinath M, Chidambaram S, Vasanthavigar M, Sarma VS (2014) Hydrochemical characterization and quality appraisal of groundwater from Pungar sub basin, Tamil Nadu, India. J King Saud Univ Sci 26:37–52

    Article  Google Scholar 

  • Stallard RF, Edmond JM (1983) Geochemistry of the Amazon. 2: the influence of the geology and weathering environment on the dissolved load. J Geophys Res 88:9671–9688

    Article  Google Scholar 

  • Stuyfzand PJ (1989) Nonpoint source of trace element in potable groundwater in Netherland. In: Proceedings of the 18th TWSA Water Working, Testing and Research Institute. KIWA, Nieuwegein

  • Szabolcs I, Darab C (1964) The influence of irrigation water of high sodium carbonate content of soils. In: Proceedings of 8th international congress of ISSS, Trans II, pp 803–812

  • Tchobanoglous G, Burton FL, Stensel HD (2003) Wastewater engineering: treatment and reuse, 4th edn. McGraw-Hill, New York

    Google Scholar 

  • Thivya C, Chidambaram S, Singaraja C, Thilagavathi R, Prasanna MV, Anandhan P, Jainab I (2013) A study on the significance of lithology in groundwater quality of Madurai district, Tamil Nadu (India). Environ Dev Sustain 15:1365–1387

    Article  Google Scholar 

  • Toumi N, Hussein BHM, Rafrafi S, El Kassas N (2015) Groundwater quality and hydrochemical properties of Al-Ula Region, Saudi Arabia. Environ Monit Assess 187:1–16

    Article  Google Scholar 

  • Vengosh A, Gill J, Davisson ML, Hudson GB (2002) A multiisotope (B, Sr, O, H, and C) and age dating study of groundwater from Salinas Valley, California: hydrochemistry, dynamics, and contamination process. Water Resour Res 38:1–17

    Article  Google Scholar 

  • US Salinity Laboratory (1954) Diagnosis and improvement of saline and alkali soils, Agricultural Handbook No. 60. USDA, p 160

  • Wilcox LV (1948) The quality of water for irrigation use, 40, US Department of Agriculture Technology Bulletin 962, Washington DC

  • World Health Organization (1997) Guideline for drinking water quality, 2nd edn. WHO, Geneva, Health criteria and other supporting information, pp 940–949

Download references

Acknowledgments

The author (NJR) is indebted to the University Grants Commission (UGC) for financial support (1) under Major Research Project [(F. No. 42-413/2013 (SR)] during 2013–2016; (2) under 21st Century Indo-US Research Initiative 2014 to Jawaharlal Nehru University, New Delhi and Mississippi State University, USA in the project “Clean Energy and Water Initiatives” [UGC No. F.194-1/2014(IC)]. NJR also appreciative to Jawaharlal Nehru University for providing UPOE II (ID 170) funds under holistic development program. The authors are thankful to Mr. N. Amarnath Reddy, Dr. D. Shankar and Dr. K. Prabhakar for their constant help and logistic support for sediment and water sample collection during field work of the project.

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Authors and Affiliations

  1. School of Environmental Sciences, Jawaharlal Nehru University, New Delhi, 110067, India

    Priyanka Patel & N. Janardhana Raju

  2. Department of Geology, S.V. University, Tirupati, 517502, Andhra Pradesh, India

    B. C. Sundara Raja Reddy & U. Suresh

  3. Institute for Geosciences, Martin Luther University, 06120, Halle (Saale), Germany

    Wolfgang Gossel & Peter Wycisk

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  1. Priyanka Patel
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  2. N. Janardhana Raju
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  3. B. C. Sundara Raja Reddy
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Correspondence to N. Janardhana Raju.

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Patel, P., Raju, N.J., Reddy, B.C.S.R. et al. Geochemical processes and multivariate statistical analysis for the assessment of groundwater quality in the Swarnamukhi River basin, Andhra Pradesh, India. Environ Earth Sci 75, 611 (2016). https://doi.org/10.1007/s12665-015-5108-x

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