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Numerical investigations on pesticide fate and transport in an unsaturated porous medium for a coupled water and pesticide management

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Abstract

The pesticides applied on the soil surface can be transported vertically downwards through the unsaturated porous system and lead to groundwater contamination. Proper agricultural management practices such as selection of appropriate irrigation techniques, choosing proper irrigation rates, and application of optimum pesticide dosages are necessary to prevent leaching of pesticides to greater depths thus preventing groundwater contamination. A simulation study is conducted based on the one-dimensional numerical model considering Richard’s equation for unsaturated water flow and solute transport which takes into account the effect of both adsorption and biodegradation with inhibitory effect to understand pesticide transport in an unsaturated porous medium. The study addresses the influence of irrigation rate, type of irrigation, and pesticide dosage on soil moisture and pesticide concentration distribution. The numerical results suggest that higher water application rates can carry the pesticides to greater depths. Pulsed irrigation can slightly reduce water losses through the root zone when compared to continuous irrigation. The comparison of the wetting patterns and the pesticide distribution obtained in continuous and pulsed irrigation helps to decide the use of a particular irrigation strategy in order to achieve suitable goals. In addition, the results from this study bring out better understanding of the effect of pesticide concentration and dosage on the resultant pesticide distribution in the unsaturated zone and the pesticide potential to cause groundwater contamination. The better analysis of outputs from this study can help in improving and designing better agricultural management strategies, carrying out risk assessment and bioremediation studies.

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References

  • Arias-Estévez M, López-Periago E, Martínez-Carballo E, Simal-Gándara J, Mejuto JC, García-Río L (2008) The mobility and degradation of pesticides in soils and the pollution of groundwater resources. Agric Ecosyst Environ 123:247–260

    Article  Google Scholar 

  • Berlin M, Suresh KG, Nambi IM (2013) Numerical modeling on fate and transport of nitrate in an unsaturated system under non-isothermal condition. Eur J Environ Civ Eng 17(5):350–373

    Article  Google Scholar 

  • Berlin M, Nambi IM, Kumar GS (2015) Experimental and numerical investigations on nitrogen species transport in unsaturated soil during various irrigation patterns. Sadhana 40:2429–2455. doi:10.1007/s12046-015-0420-4

    Article  Google Scholar 

  • Caviedes-Voullième D, Garcia-Navarro P, Murillo J (2013) Verification, conservation, stability and efficiency of a finite volume method for the 1D Richards equation. J Hydrol 480:69–84

    Article  Google Scholar 

  • Celia MA, Bouloutas ET, Zarba RL (1990) A general mass-conservative numerical solution for the unsaturated flow equation. Water Resour Res 26(7):1483–1496

    Article  Google Scholar 

  • Cote CM, Bristow KL, Charlesworth PB, Cook FJ, Thorburn PJ (2003) Analysis of soil wetting and solute transport in subsurface trickle irrigation. Irrig Sci 22:143–156

    Article  Google Scholar 

  • Di HJ, Aylmore LAG, Kookana RS (1998) Degradation rates of eight pesticides in surface and subsurface soils under laboratory and field conditions. Soil Sci 163:404–411

    Article  Google Scholar 

  • Elmaloglou S, Diamantopoulos E (2009) Effects of hysteresis on redistribution of soil moisture and deep percolation at continuous and pulse drip irrigation. Agric Water Manag 96(3):533–538

    Article  Google Scholar 

  • Fomsgaard IS (1995) Degradation of pesticides in subsurface soils, unsaturated zone—a review of methods and results. Int J Environ Anal Chem 58:231–245

    Article  Google Scholar 

  • French H, Van der Zee S, Leijnse A (2001) Transport and degradation of propylene glycol and potassium acetate in the unsaturated zone. J Contam Hydrol 49(1):23–48

    Article  Google Scholar 

  • Gaonkar OD, Suresh KG, Nambi IM (2016) Numerical modeling on fate and transport of coupled adsorption and biodegradation of pesticides in an unsaturated porous medium. ISH J Hydraul Eng. doi:10.1080/09715010.2016.1166073

    Google Scholar 

  • Gupta M, Garg NK, Joshi H, Sharma MP (2012) Persistence and mobility of 2, 4-D in unsaturated soil zone under winter wheat crop in sub-tropical region of India. Agric Ecosyst Environ 146(1):60–67

    Article  Google Scholar 

  • Horel A, Schiewer S, Misra D (2015) Effect of concentration gradients on biodegradation in bench-scale sand columns with HYDRUS modeling of hydrocarbon transport and degradation. Environ Sci Pollut Res 22(17):13251–13262

    Article  Google Scholar 

  • Hutson J, Wagenet R (1993) A pragmatic field-scale approach for modeling pesticides. J Environ Qual 22(3):494–499

    Article  Google Scholar 

  • Jarvis NJ, Stähli M, Bergström L, Johnsson H (1994) Simulation of dichlorprop and bentazon leaching in soils of contrasting texture using the MACRO model. J Environ Sci Health A29:1255–1277

    Google Scholar 

  • Jensen PH, Hansen HCB, Rasmussen J, Jacobsen OS (2004) Sorption-controlled degradation kinetics of MCPA in soil. Environ Sci Technol 38:6662–6668

    Article  Google Scholar 

  • Karpouzas DG, Walker A, Drennan DSH, Froud-Williams RJ (2001) The effect of initial concentration of carbofuran on the development and stability of its enhanced biodegradation in top-soil and sub-soil. Pest Manag Sci 57:72–81

    Article  Google Scholar 

  • Klaus J, Zehe E et al (2014) Controls of event-based pesticide leaching in natural soils: a systematic study based on replicated field scale irrigation experiments. J Hydrol 512:528–539

    Article  Google Scholar 

  • Krishna KR, Philip L (2008) Biodegradation of mixed pesticides by mixed pesticide enriched cultures. J Environ Sci Health Part B 44(1):18–30

    Article  Google Scholar 

  • Matthies M, Behrendt H (1991) Pesticide transport modelling in soil for risk assessment of groundwater contamination. Toxicol Environ Chem 31(1):357–365

    Article  Google Scholar 

  • Miller CT, Weber WJ (1986) Sorption of hydrophobic organic pollutants in saturated soil systems. J Contam Hydrol 1:243–261

    Article  Google Scholar 

  • Mills MS, Hill IR, Newcombe AC, Simmons ND, Vaughan PC, Verity AA (2001) Quantification of acetochlor degradation in the unsaturated zone using two novel in situ field techniques: comparisons with laboratory-generated data and implications for groundwater risk assessments. Pest Manag Sci 57:351–359

    Article  Google Scholar 

  • Mitchell RJ, Mayer AS (1998) A numerical model for transient-hysteretic flow and solute transport in unsaturated porous media. J Contam Hydrol 30:243–264

    Article  Google Scholar 

  • Ogata A, Banks RB (1961) A solution of the differential equation of longitudinal dispersion in porous media. No. 411-A

  • Ojha CSP, Hari Prasad KS, Ratha DN, Surampalli Y (2012) Virus transport through unsaturated zone: analysis and parameter identification. J Hazard Toxic Radioact Waste 16(2):96–105

    Article  Google Scholar 

  • Oron G (1981) Simulation of water flow in the soil under sub-surface trickle irrigation with water uptake by roots. Agric Water Manag 3(3):179–193

    Article  Google Scholar 

  • Park S, Bae W (2009) Modeling kinetics of ammonium oxidation and nitrite oxidation under simultaneous inhibition by free ammonia and free nitrous acid. Process Biochem 44(6):631–640

    Article  Google Scholar 

  • Philip JR (1957) Theory of infiltration. Soil Sci 83:345–358; 435–448

  • Phoon KK, Tan TS, Chong PC (2007) Numerical simulation of Richards’s equation in partially saturated porous media: under-relaxation and mass balance. Geotech Geol Eng 25(5):525–541

    Article  Google Scholar 

  • Rodriguez-Cruz MS, Jones JE, Bending GD (2006) Field-scale study of the variability in pesticide biodegradation with soil depth and its relationship with soil characteristics. Soil Biol Biochem 38:2910–2918

    Article  Google Scholar 

  • Šimunek J, van Genuchten MT, Šejna M (2005) The HYDRUS-1D software package for simulating the one-dimensional movement of water, heat, and multiple solutes in variably-saturated media. Version 3.0, HYDRUS Software Series 1, Department of Environmental Sciences, University of California Riverside, Riverside, CA, p 270

  • Suarez LA (2005) PRZM-3, a model for predicting pesticide and nitrogen fate in the crop root and unsaturated soil zones: user manual for release 3.12.2. US Environmental Protection Agency (EPA), Washington, DC

  • Tiktak A (2000) Application of pesticide leaching models to the Vredepeel dataset: II pesticide fate. Agric Water Manag 44:119–134

    Article  Google Scholar 

  • van Genuchten R (1980) Predicting the hydraulic conductivity of unsaturated soils. Soil Sci Soc Am J 44:892–898

    Article  Google Scholar 

  • van Genuchten MT, Naveira CC, Skaggs TH, Raoof A, Pontedeiro EM (2014) The use of numerical flow and transport models in environmental analyses. In: Teixeira WG et al (eds) Application of soil physics in environmental analyses: Measuring, Modelling and Data Integration. Springer International Publishing, Switzerland, pp 349–376

    Google Scholar 

  • Vanclooster M, Boesten AJ, Tiktak N, Jarvis JG, Kroes R, Munoz-Carpena R, Clothier BE, Green SR (2004) On the use of unsaturated flow and transport models in nutrient and pesticide management. In: Feddes R et al (eds) Unsaturated zone modelling: progress, challenges and applications. Kluwer Academic, Wageningen, pp 331–361

    Google Scholar 

  • Vasudevan M, Kumar GS, Nambi IM (2015) Numerical studies on kinetics of sorption and dissolution and their interactions for estimating mass removal of toluene from entrapped soil pores. Arab J Geosci 8(9):6895–6910

    Article  Google Scholar 

  • Warrick AW, Lomen DO, Yates SR (1985) A generalized solution to infiltration. Soil Sci Soc Am J 49:34–38

    Article  Google Scholar 

  • Weiner ER (2000) Ed Applications of environmental chemistry. A practical guide for environmental professionals. Lewis, Washington

    Book  Google Scholar 

Download references

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Authors and Affiliations

  1. EWRE Division, Department of Civil Engineering, Indian Institute of Technology Madras, Chennai, 600036, India

    Omkar D. Gaonkar

  2. Department of Ocean Engineering, Indian Institute of Technology Madras, Chennai, 600036, India

    G. Suresh Kumar

  3. Department of Civil Engineering, Indian Institute of Technology Madras, Chennai, 600036, India

    Indumathi M. Nambi

Authors
  1. Omkar D. Gaonkar
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  2. G. Suresh Kumar
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  3. Indumathi M. Nambi
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Correspondence to G. Suresh Kumar.

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Gaonkar, O.D., Kumar, G.S. & Nambi, I.M. Numerical investigations on pesticide fate and transport in an unsaturated porous medium for a coupled water and pesticide management. Environ Earth Sci 75, 1232 (2016). https://doi.org/10.1007/s12665-016-6014-6

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