Skip to main content
Log in

Variation of total aroma and polyphenol content of dark chocolate during three phase of conching

  • Original Article
  • Published:
Journal of Food Science and Technology Aims and scope Submit manuscript

Abstract

Variation in the volatiles, total polyphenol, theobromine and caffein was investigated both qualitatively and quantitatively for all phases of conching with GC/MS/SPME, HPLC, GC/O, and UV-visible spectrophotometry. The volatile compounds being identified during the three phases consisted of aldehydes, ketones, pyrazines, acids, alcohols and esters. The number and concentration of these compounds were observed to be 31–25,681 ppb, 44–34,838 ppb and 44–29,809 ppb in the dry, pasty, and liquid phases respectively. The odor of dark chocolate was described as nutty, sweet, caramel, green and chocolate using olfactometry. The percent decrease in the concentration of total polyphenol, caffein and theobromine was observed to be only 3.0, 11.0, and 32.0 respectively.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  • Afoakwa EO, Paterson A, Fowler M (2007) Factor influencing rheological and textural qualities in chovolate-review. Trends in Food Science& Technology 18:290–298

    Article  CAS  Google Scholar 

  • Akhtar Y, Yang Y, Isman MB, Plettner E (2010) Dialkoxybenzene and dialkoxy-allylbenzene feeding and oviposition deterrents against the cabbage looper, trichoplusia ni: potential insect behavior control agents. J Agric Food Chem 58:4983–4991

    Article  CAS  Google Scholar 

  • AOAC, 1990 Offical Methods of Analysis Vol 2. 15th edition Aspects of Official Analysis Chemistry, Inc. Arlington, VA

  • Arora A, Byrem TM, Nair MG, Strasburg GM (2000) Modulation of liposomal membrane fluidity by flavonoids and isoflavonoids. Arch Biochem Biophys 373:102–109

    Article  CAS  Google Scholar 

  • Awua PK (2002) Cocoa processing and chocolate manufacture in Ghana. David Jamieson and associates Pres. Inc, Essex, UK

    Google Scholar 

  • Beckett ST (2009) Industrial chocolate manufacture and use 4 th Ed. U.K, Wiley-Blackwell, York, p. 192

    Google Scholar 

  • Beckett ST (2000) The science of chocolate. Royal Society of Chemistry Paperbacks

  • Beckett ST (2003) Is the taste of British milk chocolate different? International J. Dairy Tech. 56(3):139–142

    Article  Google Scholar 

  • Benowitz NL (1990) Clinical pharmacology of caffeine. Annu Rev Med 41:277–288

    Article  CAS  Google Scholar 

  • Counet C, Callemien D, Ouwerx C, Collin S (2002) Use of gas chromotograpy-olfactometry to identify key odorant compound in dark chocolate. Comprasion of Sample before and After Conching J Agric Food Chem 5:2385–2391

    Google Scholar 

  • Frauendorfer F, Schieberle P (2006) Identification of the key aroma compound in cocoa powder based on molecular sensory correlations. Journal of agricultural and food chemistry. Vol. 54:5521–5529

    CAS  Google Scholar 

  • Hoskin J, Dimick P (1983) Role of nonenzymatic browning during the process of chcolate- a review. Process Biochem 11:92–104

    Google Scholar 

  • Keeney PG (1971) Various interactions in chocolate flavour. J Am Oil Chem Soc 49(10):567

    Article  Google Scholar 

  • Minifie BW (1989) Chocolate, cocoa and confectionery- science and technology. Chapman&Hall, London

    Book  Google Scholar 

  • Nehlig A, Daval JL, Debry G (1992) Caffeine and the central nervous system: mechanisms of action, biochemical, metabolic and psychostimulant effects. Brain Res Rev 17(2):139–170

    Article  CAS  Google Scholar 

  • Ramli N, Hassan O, Said M, Samsudin W, Idris NA (2006) Influence of roasting condition on volatile flavour of roasted Malaysian cocoa beans. J. Food Proc. Pres. 30(3):280–298

    Article  CAS  Google Scholar 

  • Reineccius G (2006) Flavour chemistry and technology, Second edn. CRC Pres, Boca Raton, USA

    Google Scholar 

  • Schnermann P, Schieberle P (1997) Evaluation of key odourants in milk chocolate and cocoa mass by aroma extract dilution analyses. J Agric Food Chem 45:867–872

    Article  CAS  Google Scholar 

  • Shamsuddin, S. B. and Dimick, P. S. 1986. Qualitative and quantitative measurement of cacao bean fermentation. In Dimmick, P.S., Proceeding of the symposium Cacao Biotechnology, pp. 55–78. The Pennsylvania State University.

  • Singleton VL, Rossi JA (1965) Colorimetry of total phenolics with phosphomolybdic-phosphotungstic acid reagents. Am J Enol Vitic 16:144–153

    CAS  Google Scholar 

  • Spiller GA (1998) Caffeine content of some cola beverages. In: Spiller G (ed) Caffeine. CRC Press LLC., Boca Raton, FL, p. 363

    Google Scholar 

  • Steinberg FM, Bearden MM, Keen CL (2003) Cocoa and chocolate flavonoids: implications for cardiovascular health. J Am Diet Assoc 103:215–223

    Article  Google Scholar 

  • Whitefield R (2005) Making chocolates in the factory. Kennefy’s Publications Ltd, London UK

    Google Scholar 

  • Wollgast J, Anklam E (2000) Food Res Int 33:449

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to F. Albak.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Albak, F., Tekin, A. Variation of total aroma and polyphenol content of dark chocolate during three phase of conching. J Food Sci Technol 53, 848–855 (2016). https://doi.org/10.1007/s13197-015-2036-4

Download citation

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s13197-015-2036-4

Keywords

Navigation