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Invited paper: Composition-dependent electrical properties of ternary AgxSb1−xTey thin films synthesized by cationic exchange reaction

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Abstract

Ternary silver antimony telluride (AgxSb1−xTey) thin films with tailored compositions were synthesized by a cationic exchange reaction of thermally evaporated antimony telluride thin films, as a simple and costeffective approach. The composition of AgxSb1−xTey thin films was controlled by the reaction time. Temperaturedependent electrical properties of the AgxSb1−xTey thin films demonstrated phase transition behavior from 323 K to 343 K. The composition-dependent thermoelectric properties (i.e., electrical resistivity (ρ), Seebeck coefficient (S) and power factor (S2ρ)) of the as-deposited Sb54Te46, the transformed AgxSb1−xTey and the annealed AgxSb1−xTey thin films were investigated as a function of temperature.

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References

  1. W. Heng, L. Jing-Feng, Z. Minmin, and S. Tao, Appl. Phys. Lett. 93, 202106 (2008).

    Article  Google Scholar 

  2. E. F. Hockings, J. Phys. Chem. Sol. 10, 341 (1959).

    Article  CAS  Google Scholar 

  3. V. Jovovic and J. Heremans, J. Elec. Mater. 38, 1504 (2009).

    Article  CAS  Google Scholar 

  4. D. T. Morelli, V. Jovovic, and J. P. Heremans, Phys. Rev. Lett. 101, 035901 (2008).

    Article  CAS  Google Scholar 

  5. T. Su, X. Jia, H. Ma, F. Yu, Y. Tian, G. Zuo, Y. Zheng, Y. Jiang, D. Dong, L. Deng, B. Qin, and S. Zheng, J. Appl. Phys. 105, 073713 (2009).

    Article  Google Scholar 

  6. T. Su, X. Jia, H. Ma, L. Zhou, J. Guo, and N. Dong, Phys. Lett. A, 372, 515 (2008).

    Article  CAS  Google Scholar 

  7. B. K. Min, B. S. Kim, I. H. Kim, J. K. Lee, M. H. Kim, M. W. Oh, S. D. Park, and H. W. Lee, Electron. Mater. Lett. 7, 255 (2011)

    Article  CAS  Google Scholar 

  8. K. Wojciechowski, J. Tobola, M. Schmidt, and R. Zybala, J. Phys. Chem. Sol. 69, 2748 (2008).

    Article  CAS  Google Scholar 

  9. S. N. Zhang, T. J. Zhu, S. H. Yang, C. Yu, and X. B. Zhao, Acta Mater. 58, 4160 (2010).

    Article  CAS  Google Scholar 

  10. J. P. Heremans, V. Jovovic, E. S. Toberer, A. Saramat, K. Kurosaki, A. Charoenphakdee, S. Yamanaka, and G. J. Snyder, Science, 321, 554 (2008).

    Article  CAS  Google Scholar 

  11. K. F. Hsu, S. Loo, F. Guo, W. Chen, J. S. Dyck, C. Uher, T. Hogan, E. K. Polychroniadis, and M. G. Kanatzidis, Science, 303, 818 (2004).

    Article  CAS  Google Scholar 

  12. G. J. Snyder and E. S. Toberer, Nature Mater. 7, 105 (2008).

    Article  CAS  Google Scholar 

  13. D. M. Rowe, CRC Handbook of Thermoelectrics, Boca Raton, CRC Press, Inc. (1995).

    Book  Google Scholar 

  14. B. Kim, I. Kim, J. Lee, B. Min, M. Oh, S. Park, H. Lee, and M. Kim, Electron. Mater. Lett. 6, 181 (2010).

    Article  CAS  Google Scholar 

  15. J. D. Sugar and D. L. Medlin, J. Alloys Comp. 478, 75 (2009).

    Article  CAS  Google Scholar 

  16. B. Poudel, Q. Hao, Y. Ma, Y. Lan, A. Minnich, B. Yu, X. Yan, D. Wang, A. Muto, D. Vashaee, X. Chen, J. Liu, M. S. Dresselhaus, G. Chen, and Z. Ren, Science, 320, 634 (2008).

    Article  CAS  Google Scholar 

  17. J. M. O. Zide, D. Vashaee, Z. X. Bian, G. Zeng, J. E. Bowers, A. Shakouri, and A. C. Gossard, Phys. Rev. B, 74, 205335 (2006).

    Article  Google Scholar 

  18. J. Martin, L. Wang, L. Chen, and G. S. Nolas, Phys. Rev. B, 79, 115311 (2009).

    Article  Google Scholar 

  19. D. Vashaee and A. Shakouri, Phys. Rev. Lett. 92, 106103 (2004).

    Article  Google Scholar 

  20. Y. S. Park, S. Y. Lee, S. M. Yoon, S. W. Jung, B. G. Yu, S. J. Lee, and S. G. Yoon, Appl. Phys. Lett. 91, 162107 (2007).

    Article  Google Scholar 

  21. M. L. Lee, L. P. Shi, Y. T. Tian, C. L. Gan, and X. S. Miao, phys. Stat. Sol. (a), 205, 340 (2008).

    Article  CAS  Google Scholar 

  22. M. Wuttig and N. Yamada, Nat. Mater. 6, 824 (2007).

    Article  CAS  Google Scholar 

  23. M. H. R. Lankhorst, B. W. S. M. M. Ketelaars, and R. A. M. Wolters, Nat. Mater. 4, 347 (2005).

    Article  CAS  Google Scholar 

  24. D. Yu, S. Brittman, J. S. Lee, A. L. Falk, and H. Park, Nano Lett. 8, 3429 (2008).

    Article  CAS  Google Scholar 

  25. C. Frei, J. Schenzel, F. Waibel, and D. Gunther, J. Anal. Atom. Spectrom. 23, 217 (2008).

    Article  CAS  Google Scholar 

  26. G. D. Moon, S. Ko, Y. Xia, and U. Jeong, ACS Nano 4, 2307 (2010).

    Article  CAS  Google Scholar 

  27. U. Jeong, P. H. C. Camargo, Y. H. Lee, and Y. Xia, J. Mater. Chem. 16, 3893 (2006).

    Article  CAS  Google Scholar 

  28. B. Zhang, Y. Jung, H.-S. Chung, L. V. Vugt, and R. Agarwal, Nano Lett. 10, 149 (2009).

    Article  Google Scholar 

  29. S. E. Wark, C.-H. Hsia, and D. H. Son, J. Am. Chem. Soc. 130, 9550 (2008).

    Article  CAS  Google Scholar 

  30. S. K. Mishra, S. Satpathy, and O. Jepsen, J. Phys.: Condensed Matter 9, 461 (1997).

    Article  CAS  Google Scholar 

  31. H. Zhang, C.-X. Liu, X.-L. Qi, X. Dai, Z. Fang, and S.-C. Zhang, Nat. Phys. 5, 438 (2009).

    Article  CAS  Google Scholar 

  32. R. Detemple, D. Wamwangi, M. Wuttig, and G. Bihlmayer, Appl. Phys. Lett. 83, 2572 (2003).

    Article  CAS  Google Scholar 

  33. V. Jovovic and J. P. Heremans, Phys. Rev. B 77, 245204 (2008).

    Article  Google Scholar 

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Correspondence to Yongho Choa or Nosang V. Myung.

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Jung, H., Park, H., Choa, Y. et al. Invited paper: Composition-dependent electrical properties of ternary AgxSb1−xTey thin films synthesized by cationic exchange reaction. Electron. Mater. Lett. 8, 219–224 (2012). https://doi.org/10.1007/s13391-012-2041-y

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