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Production, optimisation and engine characteristics of beef tallow biodiesel rendered from leather fleshing and slaughterhouse wastes

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Abstract

Presently, biodiesel is considered as an effective alternate fuel owing to its high sustainability and robustness. This paper concentrates on the biodiesel production from waste beef tallow rendered from subcutaneous and intramuscular wastes discarded from leather tanneries and slaughterhouses. The maximum fat content was estimated to be 92.5% and 3.05%, whereas maximum rendering efficiency was determined to be 92% and 75% for subcutaneous and intramuscular wastes, respectively. The rendered waste tallow was converted into biodiesel using ethanol as a solvent and l-valine amido ethyl methyl imidazolium bromide ([l-Vaemim]Br) as a novel ionic liquid catalyst. The most optimised reaction parameters are as follows: molar ratio of 1:7.5, catalyst concentration of 20 wt% of tallow, reaction temperature of 75 °C and reaction time of 160 min. Properties of the produced biodiesel have been tested in accordance with ASTM Standards, where the results were found to be within the permissible range. The engine characteristics of biodiesel exhibited increased heat release rate and maximum cylinder pressure, reduced emission levels than compared to ordinary diesel; in addition, its performance characteristics were similar to diesel, thereby making it a suitable replacement for existing fossil fuel.

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References

  1. Abbah EC, Nwandikom GI, Egwuonwu CC, Nwakuba NR (2016) Effect of reaction temperature on the yield of biodiesel from neem seed oil. American Journal of Energy Science 3(3):16–20

    Google Scholar 

  2. Abdul Malik MS, Shaiful AIM, Mohd Ismail MS, Mohd Jaafar MN, Mohamad Sahar A (2017) Combustion and emission characteristics of coconut-based biodiesel in a liquid fuel burner. Energies 10(4):458

    Article  Google Scholar 

  3. Ala’a H, Jamil F, Al-Haj L, Myint MTZ, Mahmoud E, Ahmad MN, Hasan AO, Rafiq S (2018) Biodiesel production over a catalyst prepared from biomass-derived waste date pits. Biotechnology Reports 20:00284

    Google Scholar 

  4. Alam P, Ahmade K (2013) Impact of solid waste on health and the environment. International Journal of Sustainable Development and Green Economics (IJSDGE) 2(1):165–168

    Google Scholar 

  5. Altun S, Yasşar F (2013) Biodiesel production from leather industry wastes as an alternative feedstock and its use in diesel engines. Energy Explor Exploit 31(5):759–770

    Article  Google Scholar 

  6. Anastopoulos G, Zannikou Y, Stournas S, Kalligeros S (2009) Transesterification of vegetable oils with ethanol and characterization of the key fuel properties of ethyl esters. Energies 2(2):362–376

    Article  Google Scholar 

  7. Bajpai D, Tyagi VK (2006) Biodiesel: source, production, composition, properties and its benefits. J Oleo Sci 55(10):487–502

    Article  Google Scholar 

  8. Barrios CC, Domínguez-Sáez A, Martín C, Álvarez P (2014) Effects of animal fat based biodiesel on a TDI diesel engine performance, combustion characteristics and particle number and size distribution emissions. Fuel 117:618–623

    Article  Google Scholar 

  9. Boudy F, Seers P (2009) Impact of physical properties of biodiesel on the injection process in a common-rail direct injection system. Energy Convers Manag 50(12):2905–2912

    Article  Google Scholar 

  10. Cunha A Jr, Feddern V, Marina C, Higarashi MM, de Abreu PG, Coldebella A (2013) Synthesis and characterization of ethylic bio–diesel from animal fat wastes. Fuel 105:228–234

  11. Da Silva HR, Quintella CM, Meira M (2017) Separation and identification of functional groups of molecules responsible for fluorescence of biodiesel using FTIR spectroscopy and principal component analysis. J Braz Chem Soc 28(12):2348–2356

    Google Scholar 

  12. Deepanraj B, Srinivas M, Arun N, Sankaranarayanan G, Abdul Salam P (2017) Comparison of jatropha and karanja biofuels on their combustion characteristics. Int J Green Energy 14(15):1231–1237

    Article  Google Scholar 

  13. Demirbas A (2007) Effects of moisture and hydrogen content on the heating value of fuels. Energy Sources, Part A: Recovery, Utilization, and Environmental Effects 29(7):649–655

    Article  Google Scholar 

  14. Demirbas A (2009) Biodiesel from waste cooking oil via base-catalytic and supercritical methanol transesterification. Energy Convers Manag 50(4):923–927

    Article  Google Scholar 

  15. Dharmadhikari HM, Kumar PR, Rao SS (2012) Performance and emissions of CI engine using blends of biodiesel and diesel at different injection pressures. International Journal of Applied Research in Mechanical Engineering 2(2):1–6

    Google Scholar 

  16. Dinh TTN, Blanton JR Jr, Riley DG, Chase CC Jr, Coleman SW, Phillips WA, Brooks JC, Miller MF, Thompson LD (2010) Intramuscular fat and fatty acid composition of longissimus muscle from divergent pure breeds of cattle. J Anim Sci 88(2):756–766

    Article  Google Scholar 

  17. Fillieres R, Benjelloun-Mlayah B, Delmas M (1995) Ethanolysis of rapeseed oil: quantitation of ethyl esters, mono-, di-, and triglycerides and glycerol by high-performance size-exclusion chromatography. J Am Oil Chem Soc 72(4):427–432

    Article  Google Scholar 

  18. Gog A, Roman M, Toşa M, Paizs C, Irimie FD (2012) Biodiesel production using enzymatic transesterification–current state and perspectives. Renew Energy 39(1):10–16

    Article  Google Scholar 

  19. Gude VG, Patil P, Martinez-Guerra E, Deng S, Nirmalakhandan N (2013) Microwave energy potential for biodiesel production. Sustainable Chem Processes 1(1):5

    Article  Google Scholar 

  20. Heywood JB (1998) Internal combustion engine fundamentals. McGraw Hill, New York

    Google Scholar 

  21. Johnson ER, Butterfield RM, Pryor WJ (1972) Studies of fat distribution in the bovine carcass. 1. The partition of fatty tissues between depots. Aust J Agric Res 23(2):381–388

    Article  Google Scholar 

  22. Kalyani KA, Pandey KK (2014) Waste to energy status in India: a short review. Renew Sust Energ Rev 31:113–120

    Article  Google Scholar 

  23. Kannan M, Karthikeyan R, Deepanraj B, Baskaran R (2014) Feasibility and performance study of turpentine fueled DI diesel engine operated under HCCI combustion mode. J Mech Sci Technol 28(2):729–737

    Article  Google Scholar 

  24. Knothe G (2006) Analyzing biodiesel: standards and other methods. J Am Oil Chem Soc 83(10):823–833

    Article  Google Scholar 

  25. Kumar MS, Kerihuel A, Bellettre J, Tazerout M (2006) Ethanol animal fat emulsions as a diesel engine fuel–part 2: engine test analysis. Fuel 85(17–18):2646–2652

    Article  Google Scholar 

  26. Kumar TS, Kumar PS, Annamalai K (2015) Experimental study on the performance and emission measures of direct injection diesel engine with kapok methyl ester and its blends. Renew Energy 74:903–909

    Article  Google Scholar 

  27. Mattos RAD, Bastos FA, Tubino M (2015) Correlation between the composition and flash point of diesel-biodiesel blends. J Braz Chem Soc 26(2):393–395

    Google Scholar 

  28. Meher LC, Sagar DV, Naik SN (2006) Technical aspects of biodiesel production by transesterification—a review. Renew Sust Energ Rev 10(3):248–268

    Article  Google Scholar 

  29. Moraes MSA, Krause LC, da Cunha ME, Faccini CS, de Menezes EW, Veses RC, Rodrigues MRA, Caramao EB (2008) Tallow biodiesel: properties evaluation and consumption tests in a diesel engine. Energy Fuel 22(3):1949–1954

    Article  Google Scholar 

  30. Noureddini H, Teoh BC, Clements LD (1992) Densities of vegetable oils and fatty acids. J Am Oil Chem Soc 69(12):1184–1188

    Article  Google Scholar 

  31. Raman LA, Deepanraj B, Rajakumar S, Sivasubramanian V (2019) Experimental investigation on performance, combustion and emission analysis of a direct injection diesel engine fuelled with rapeseed oil biodiesel. Fuel 246:69–74

    Article  Google Scholar 

  32. Ranjitha J, Vijayalakshmi S, Shalini P, Gokul Raghavendra S (2019) Effect of dominant fatty acid esters on emission characteristics of waste animal fat biodiesel in CI engine. Frontiers in Energy Research 7:1–13

    Article  Google Scholar 

  33. Selvam DJP, Vadivel K (2012) Performance and emission analysis of DI diesel engine fuelled with methyl esters of beef tallow and diesel blends. Procedia Eng 38:342–358

    Article  Google Scholar 

  34. Srinivasan GR, Palani S, Jambulingam R (2018) Optimised production of biodiesel synthesised from waste animal fat. Journal of Biofuels 9(1):17–24

    Article  Google Scholar 

  35. Srinivasan GR, Shankar V, Jambulingam R (2019) Experimental study on influence of dominant fatty acid esters in engine characteristics of waste beef tallow biodiesel. Energy Explor Exploit 37(3):1098–1124

    Article  Google Scholar 

  36. Williams MA (2005) Recovery of oils and fats from oilseeds and fatty materials. Bailey's Industrial Oil and Fat Products

  37. Woodgate S, Van Der Veen J (2004) The role of fat processing and rendering in the European Union animal production industry. Biotechnol Agron Soc Environ 8(4):283–294

    Google Scholar 

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Ranjitha, J., Gokul Raghavendra, S., Vijayalakshmi, S. et al. Production, optimisation and engine characteristics of beef tallow biodiesel rendered from leather fleshing and slaughterhouse wastes. Biomass Conv. Bioref. 10, 675–688 (2020). https://doi.org/10.1007/s13399-019-00501-6

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