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A novel polymeric catalyst for the one-pot synthesis of xanthene derivatives under solvent-free conditions

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Abstract

A simple, efficient, and environmentally benign route was developed for the preparation of 14-aryl or alkyl-14H-dibenzo[a,j]xanthene, 1,8-dioxo-octahydroxanthene and 12-aryl—8,9,10,12-tetrahydrobenzo[a]xanthene-11-ones from condensation of various aldehydes with (i) β-naphthol, (ii) cyclic 1,3-dicarbonyl compounds and (iii) β-naphthol and cyclic 1,3-dicarbonyl compounds, using novel polymeric catalyst [poly(AMPS-co-AA)] under solvent-free conditions. Use of easily available catalyst, shorter reaction times, better yields, simplicity of the reaction, heterogeneous system, and easy work-up are the advantages of the present method.

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Acknowledgments

The authors are thankful to research council of Hakim Sabzevari University for financial support.

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Authors and Affiliations

  1. Department of Chemistry, Hakim Sabzevari University, PO Box 397, Sabzevar, Iran

    Behrooz Maleki, Zeinalabedin Sepehr, Mina Kermanian & Reza Tayebee

  2. Basic Science Department, Jundi Shapur University of Technology, Dezful, Iran

    Shahram Barzegar

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  1. Behrooz Maleki
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  2. Shahram Barzegar
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Correspondence to Behrooz Maleki.

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Maleki, B., Barzegar, S., Sepehr, Z. et al. A novel polymeric catalyst for the one-pot synthesis of xanthene derivatives under solvent-free conditions. J IRAN CHEM SOC 9, 757–765 (2012). https://doi.org/10.1007/s13738-012-0092-5

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