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Hydrogen Bonds with Chalcogens: Looking Beyond the Second Row of the Periodic Table

  • Review Article
  • Published:
Journal of the Indian Institute of Science Aims and scope

Abstract

Compared to conventional hydrogen bonds like (O–H···N, N–H···O, O–H···O, N–H···N), hydrogen bonds involving heavier chalcogens like sulfur, selenium, and tellurium have been considered weaker owing to less electronegativity of these elements. However, various instances exist to prove that these hydrogen bonds (H bonds) are of similar strength of conventional hydrogen bonds, although the nature of hydrogen bonding could be different depending on a combination of electronegativity, polarizability, and dispersion effects. We have presented a plethora of such H bonds that have been investigated over past several decades through high-resolution laser spectroscopy, microwave spectroscopy, and quantum chemical calculations. These H bonds not only play important roles in biological systems, but are increasingly being tuned in nature and strength to construct artificial models that can aid our mechanistic understanding of non-covalent interactions and also help in modulation of activity, detection, and combat of diseases. We have discussed how these interactions could be exploited for applications in crystal engineering, superconductivity, gas capture, and field-effect transistor studies.

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Adapted with permission from Ref.99 Copyright 2010 American Chemical Society.

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Reproduced from Ref.56 with permission from Royal Society of Chemistry via Copyright Clearance Centre.

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Reprinted with permission from ref 26 Copyright 2009 American Chemical Society.

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Acknowledgements

The authors acknowledge financial support from Department of Atomic Energy and Department of Science and Technology (Project File No: CRG/20l8/000892), Government of India. The authors express their gratitude towards their group members Dr. Venkateswara Rao Mundlapati and Dipak Kumar Sahoo, Prof. Sanjay Wategaonkar, and his group as well as other authors of the cited references for their valuable contributions on hydrogen bonding.

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  1. School of Chemical Sciences, National Institute of Science Education and Research (NISER), PO-Bhimpur-Padanpur, Via-Jatni, District-Khurda, Bhubaneswar, 752050, India

    Apramita Chand & Himansu S. Biswal

  2. Homi Bhabha National Institute, Training School Complex, Anushakti Nagar, Mumbai, 400094, India

    Apramita Chand & Himansu S. Biswal

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Chand, A., Biswal, H.S. Hydrogen Bonds with Chalcogens: Looking Beyond the Second Row of the Periodic Table. J Indian Inst Sci 100, 77–100 (2020). https://doi.org/10.1007/s41745-019-00140-w

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