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Synthesis and Spectroscopic Characterization of Water Soluble Triazene Dyes Based on Glyco-conjugated Pyrazolone Derivatives Catalyzed by an Acidic Ionic Liquid Supported on Silica-Coated Magnetite Nanoparticles

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Abstract

Novel water soluble triazene dyes based on glyco-conjugated pyrazolone amines were synthetized by using N-propyl-2-pyrrolidonium hydrogen sulfate supported on silica-coated magnetite nanoparticle as acid catalyst. This organic–inorganic hybrid composite showed an excellent catalytic activity toward diazotization reaction of pyrazolone amines performing triazene dyes under solvent-free conditions in high yields. The spectroscopic properties confirmed the tendency of these dyes to exist in their hydrazo-keto tautomer forms. The study of the solubility of these dyes in water showed that their water solubility requires a minimum percentage weight of 50% of the carbohydrate part.

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Authors and Affiliations

  1. Faculté des Sciences & Techniques d’Al Hoceima, Laboratoire R&D en sciences de l’ingénieur, BP 34, 32003, Ajdir, Morocco

    Jalal Isaad

  2. Université Abdelmalek Essaâdi, Quartier M’haneche II, Avenue Palestine, B.P. 2117, Tétouan, Morocco

    Jalal Isaad

  3. Engineering and Textile Materials Laboratory, Lille, Lille Nord de France University, 2 Allée Louise et Victor Champier, 59100, Roubaix, France

    Ahmida El Achari

Authors
  1. Jalal Isaad
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  2. Ahmida El Achari
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Correspondence to Jalal Isaad.

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Isaad, J., El Achari, A. Synthesis and Spectroscopic Characterization of Water Soluble Triazene Dyes Based on Glyco-conjugated Pyrazolone Derivatives Catalyzed by an Acidic Ionic Liquid Supported on Silica-Coated Magnetite Nanoparticles. Chemistry Africa 3, 889–899 (2020). https://doi.org/10.1007/s42250-020-00186-9

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  • DOI: https://doi.org/10.1007/s42250-020-00186-9

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