Skip to main content
SpringerLink
Log in

Hydrophobization of multilayered film containing layer-by-layer assembled nanoparticle by Nafion adsorption

  • Published:
Polymer Bulletin Aims and scope Submit manuscript

Summary

The multilayered film on a glass substrate, assembled from cationic poly(ethyleneimine) (PEI), anionic nano-sized polystyrene (PS) latex particle and cationic PEI or poly(allylamine hydrochloride) (PAH) layer was prepared by using the layer-by-layer (LbL) technique. Hydrophobization was carried out by immersing the film in Nafion solution. The hydrophobicity with high contact angle value was achieved by adjusting deposition ionic strength and ratio of water/ethanol of Nafion solution. The existence of PS particles in the LbL film significantly enhanced hydrophobicity of the film surface.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Gu ZZ, Uetsuka H, Takahashi K, Nakajima R, Onishi H, Fujishima A, Sato O (2003) Angew Chem 115: 922

  2. Barthlott W, Neinhuis C (1997) Planta 202: 1

    Google Scholar 

  3. Neinhuis C, Barthlott W (1997) Ann Bot 79: 667

  4. Zhai L, Cebeci FÇ, Cohen RE, Rubner MF (2004) Nano Lett 4: 1349

  5. Lau KKS, Bico J, Teo KBK, Chhowalla M, Amaratunga GAJ, Milne WI, McKinley GH, Gleason KK (2003) Nano Lett 3: 1701

  6. Bico J, Marzolin C, Quéré D (1996) Europhys Lett 47: 220

  7. Nakajima A, Hashimoto K, Watanabe T, Takai K, Yamauchi G, Fujishima A (2000) Langmuir 16: 7044

  8. Woodward I, Schofield WCE, Roucoules V, Badyal JPS (2003) Langmuir 19: 3432

    Google Scholar 

  9. DeLongchamp DM, Hammond PT (2003) Chem Mater 15: 1165

  10. Kawano Y, Wang Y, Palmer RA, Aubuchon SR (2002) Polimeros: Ciênciae Tecnologia 12: 96

  11. Hozumi A, Takai O (1997) Thin Solid Films 303: 222

    Google Scholar 

  12. Xu H, Goedel WA (2003) Langmuir 19: 4950

  13. Decher G (2003) Polyelectrolyte multilayers, an overview. In: Decher G, Schlenoff JB (ed) Multilayer thin films. Wiley-VCH, Federal Republic

  14. Decher G (1997) Science 277: 1232

    Google Scholar 

  15. Zhang X, Shi F, Yu X, Liu H, Fu Y, Wang Z, Jiang L, Li X (2004) J Am Chem Soc 126: 3064

  16. Wang X, Boya B, Sudol D, El-Aasser MS (2001) Macromolecules 34: 8907

    Google Scholar 

  17. García-Salinas MJ, de las Nieves FJ (2000) Langmuir 16: 7150

  18. Kampes A, Tieka B (1999) Mater Sci Eng C 8-9: 195

  19. Schmitt J, Mächtle P, Eck D, Möhwald H, Helm CA (1999) Langmuir 15: 3256

    Google Scholar 

  20. Clark SL, Handy ES, Rubner MF, Hammond PT (1999) Adv Mater 11: 1031

  21. Thünemann AF, Beyermann J (2000) Macromolecules 33: 6878

    Google Scholar 

  22. Coupe B, Evanglista ME, Yeung RM, Chen W (2001) Langmuir 17: 1956

  23. Vishnyakov A, Neimark AV (2001) J Phys Chem B 105: 7830

    Google Scholar 

  24. Rivin D, Kendrick CE, Gibson PW, Schneider NS (2001) Polymer 42: 623

    Google Scholar 

  25. Yamamoto S, Hyodo SA (2003) Polymer J 35: 519

  26. Elliott JA, Hanna S, Elliott AMS, Cooley GE (2001) Polymer 42: 2251

    Google Scholar 

  27. Schneider NS, Rivin D (2004) Polymer 45: 6309

    Google Scholar 

  28. Li H, Schlick S (1995) Polymer 36: 1141

  29. Kurth DG, Volkmer D, Klitzing Rv (2003) Multilayers on solid planar substrates: from structure to function. In: Decher G, Schlenoff JB (ed) Multilayer thin films. Wiley-VCH, Federal Republic

  30. Bertrand P, Jonas A, Laschewsky A, Legras R (2000) Macromol Rapid Commun 21: 319

    Google Scholar 

  31. Yoo D, Shiratori SS, Rubner MF (1998) Macromolecules 31: 4309

    Google Scholar 

  32. Cho J, Char K (2004) Langmuir 20: 4011

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Mahidol University, Rama 6 Road, Phyathai, Bangkok, 10400, Thailand

    Supaporn Sangribsub & Pramuan Tangboriboonrat

  2. Institut Charles Sadron (CNRS-ULP), 6 rue Boussingault, 67083, Strasbourg cedex, France

    Tha Pith & Gero Decher

Authors
  1. Supaporn Sangribsub
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Pramuan Tangboriboonrat
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Tha Pith
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Gero Decher
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Pramuan Tangboriboonrat.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sangribsub, S., Tangboriboonrat, P., Pith, T. et al. Hydrophobization of multilayered film containing layer-by-layer assembled nanoparticle by Nafion adsorption. Polym. Bull. 53, 425–434 (2005). https://doi.org/10.1007/s00289-005-0353-x

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00289-005-0353-x

Keywords

Search

Navigation