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Complex and liquid hydrides for energy storage

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Abstract

The research on complex hydrides for hydrogen storage was initiated by the discovery of Ti as a hydrogen sorption catalyst in NaAlH4 by Boris Bogdanovic in 1996. A large number of new complex hydride materials in various forms and combinations have been synthesized and characterized, and the knowledge regarding the properties of complex hydrides and the synthesis methods has grown enormously since then. A significant portion of the research groups active in the field of complex hydrides is collaborators in the International Energy Agreement Task 32. This paper reports about the important issues in the field of complex hydride research, i.e. the synthesis of borohydrides, the thermodynamics of complex hydrides, the effects of size and confinement, the hydrogen sorption mechanism and the complex hydride composites as well as the properties of liquid complex hydrides. This paper is the result of the collaboration of several groups and is an excellent summary of the recent achievements.

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Acknowledgments

Financial support from the Federal Office of Energy in Switzerland for the Project No. SI/500597 “Advanced Complex Hydrides (ACH)” and the IEA Task 32 participation are acknowledged. This work was financially supported by CCEM research through the HyTech project and the SCCER “Heat & Electricity Storage” programme. The work was supported by the Danish National Research Foundation, Center for Materials Crystallography (DNRF93), the Danish Council for Strategic Research (project HyFill-Fast) and the Danish Research Council for Nature and Universe (Danscatt). We are grateful to the Carlsberg Foundation and Energistyrelsen, EUDP.

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Authors and Affiliations

  1. Laboratory of Materials for Renewable Energy (LMER), Institute of Chemical Sciences and Engineering (ISIC), École polytechnique fédérale de Lausanne, EPFL Valais/Wallis, Sion, Switzerland

    Elsa Callini & Andreas Züttel

  2. EMPA Materials Science and Technology, Überlandstrasse 129, 8600, Sion, Switzerland

    Elsa Callini, Zuleyha Özlem Kocabas Atakli & Andreas Züttel

  3. Physics Department, Institute for Energy Technology, Kjeller, Norway

    Bjørn C. Hauback

  4. Department of Chemistry and NIS, University of Turin, Turin, Italy

    Marcello Baricco

  5. Department of Chemistry, Center for Materials Crystallography, Interdisciplinary Nanoscience Center, Aarhus University, Langelandsgade 140, 8000, Aarhus C, Denmark

    Mark Paskevicius & Torben R. Jensen

  6. Debye Institute for Nanomaterials Science, Utrecht University, Universiteitsweg 99, 3584 CG, Utrecht, The Netherlands

    Petra de Jongh

  7. Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023, China

    Ping Chen

  8. Pacific Northwest National Laboratory, 902 Battelle Boulevard, P.O. Box 999, Richland, WA, 99352, USA

    Mark E. Bowden & Thomas S. Autrey

  9. Future Convergence Research Division, High Temperature Energy Materials Research Center, Korea Institute of Science and Technology, Hwarangno 14-gil 5, Seongbuk-gu, Seoul, 136-791, Republic of Korea

    Young Whan Cho

  10. Department of Nanotechnology, Materials Technology, Helmholtz-Zentrum Geesthacht, Geesthacht, Germany

    Martin Dornheim

  11. University Park, Nottingham, NG7 2RD, UK

    David Grant

  12. WPI Advanced Institute for Materials Research (WPI-AIMR), Institute for Materials Research, Tohoku University, Sendai, Japan

    Shin-ichi Orimo

  13. Department of Chemistry, University of Hawaii at Manoa, 2545 The Mall, Honolulu, HI, 96822-2275, USA

    Craig Jensen

  14. Department of Physics and Astronomy, Materials Physics, Box 516, 751 20, Uppsala, Sweden

    Bjørgvin Hjörvarsson

  15. Department of Heterogeneous Catalysis, Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470, Mülheim an der Ruhr, Germany

    Claudia Weidenthaler

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  1. Elsa Callini
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Callini, E., Atakli, Z.Ö.K., Hauback, B.C. et al. Complex and liquid hydrides for energy storage. Appl. Phys. A 122, 353 (2016). https://doi.org/10.1007/s00339-016-9881-5

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