Abstract
The present study proposed and demonstrated the feasibility of the fiber-based LIBS technique for the analysis of pulverized coal. A hollow-core fiber was employed to replace the air medium in the conventional LIBS setup for the delivery of high-power laser pulses to the target. It was observed that the hollow-core fiber could effectively deliver the laser energy for target ablation with a transmission efficiency of 50–60%. The LIBS spectra captured using the fiber LIBS technique prove that the addition of hollow-core fiber can upgrade the conventional LIBS technique into a remote characterization unit. Convincing results were obtained in terms of quantitative carbon measurement using the proposed approach.
Similar content being viewed by others
References
L.D. Smoot, Fundamentals of Coal Combustion for Clean and Efficient Use (Elsevier, Amsrerdam, 1993)
J.G. Speight, Coal-Fired Power Generation Handbook (John Wiley & Sons, New Jersey, 2021)
C. E. Romero et al., Development and demonstration of laser-induced breakdown spectroscopy for in-situ, on-line coal analysis. In: International Pittsburgh Coal Conference, pp. 912–915 (2011)
S.J. Rehse, H. Salimnia, A.W. Miziolek, Laser-induced breakdown spectroscopy (LIBS): an overview of recent progress and future potential for biomedical applications. J. Med. Eng. Technol. 36(2), 77–89 (2012)
R. Hemalaxmi, N.J. Vasa, S. Seshadri, LIBS technique combined with blow gas and vacuum suction to remove particle cloud and enhance emission intensity during characterization of powder samples. Spectrochim. Acta Part B 181, 106215 (2021)
L.-B. Guo et al., Improvement of spectral intensity and resolution with fiber laser for on-stream slurry analysis in laser-induced breakdown spectroscopy. Spectrochim. Acta, Part B 152, 38–43 (2019)
M. Saeki et al., Development of a fiber-coupled laser-induced breakdown spectroscopy instrument for analysis of underwater debris in a nuclear reactor core. J. Nucl. Sci. Technol. 51(7–8), 930–938 (2014)
S. Sasazawa, S. Kakino, Y. Matsuura, Optical-fiber-based laser-induced breakdown spectroscopy for detection of early caries. J. Biomed. Opt. 20(6), 65002 (2015)
N. Farid, S. Bashir, K. Mahmood, Effect of ambient gas conditions on laser-induced copper plasma and surface morphology. Phys. Scr. 85(1), 15702 (2011)
H. Rajavelu, N.J. Vasa, S. Seshadri, Effect of ambiance on the coal characterization using laser-induced breakdown spectroscopy (LIBS). Appl. Phys. A 126, 1–10 (2020)
H. Rajavelu, N.J. Vasa, S. Seshadri, Laser-induced breakdown spectroscopy combined with temporal plasma analysis of C2 molecular emission for carbon analysis in coal. Appl. Spectrosc. 75, 893–900 (2021)
Funding
The authors are thankful to BHEL, Trichy, India, for providing coal samples for the analysis. Part of this work was supported under the UAY 21-105/2015-TS.II/TC.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
The authors have no conflicts of interest to declare that are relevant to the content of this article.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Rajavelu, H., Vasa, N.J. & Seshadri, S. Hollow-core optical fiber-based laser-induced breakdown spectroscopy technique for the elemental analysis of pulverized coal. Appl. Phys. A 128, 868 (2022). https://doi.org/10.1007/s00339-022-06007-9
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s00339-022-06007-9