Skip to main content
SpringerLink
Log in

Adsorption of iso-/n-butane on an anatase thin film: a molecular beam scattering and TDS study

  • Published:
Catalysis Letters Aims and scope Submit manuscript

Abstract

Binding energies and adsorption probabilities have been determined for n/iso-butane adsorption on an anatase thin film grown on SrTiO3(001) by means of thermal desorption spectroscopy (TDS) and molecular beam scattering. The sample has been characterized by X-ray diffraction (XRD) and Auger electrons spectroscopy (AES).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Figure 1
Figure 2
Figure 3
Figure 4

Similar content being viewed by others

References

  1. Goepel W., Hesse J., Zeinel J.N. (1991) Sensors a comprehensive survey. VCH, Weiheim

    Google Scholar 

  2. Regan B.O., Graetzel M. (1991) Nature 353:737

    Article  Google Scholar 

  3. Huang S.Y., Kavan L., Exnar I., Graetzel M. (1995) J. Electrochem. Soc. 142:L142

    Article  CAS  Google Scholar 

  4. Haruta M. (1997) Catal. Today 36:153

    Article  CAS  Google Scholar 

  5. Parvulescu V.I., Grange P., Delmon B. (1998) Catal. Today 46:233

    Article  CAS  Google Scholar 

  6. Kavan L., Gratzel M., Gilbert S.E., Klemenz C., Scheel H.J. (1996) J. Am. Chem. Soc. 118:6716

    Article  CAS  Google Scholar 

  7. Satterfiled C.N. (1991) Heterogeneous Catalysis in Industrial Practice. McGraw-Hill, Inc., New York

    Google Scholar 

  8. Thompson T.L., Yates J.T. (2006) Chem. Rev. 106:4428

    Article  CAS  Google Scholar 

  9. Chambers A., Wang C.W., Thevuthasan S., Droubay I., Mccready D.E., Lea A.S., Shutthanandan V., Windisch C.F. (2002) Thin Solid Films 418:197

    Article  CAS  Google Scholar 

  10. Martra G. (2000) Appl. Catal. A Gen. 200:275

    Article  CAS  Google Scholar 

  11. Fujishima A., Honda K. (1972) Nature 238:37

    Article  CAS  Google Scholar 

  12. Herman G.S., Sievers M.R., Gao Y. (2000) Phys. Rev. Lett. 84:3354

    Article  CAS  Google Scholar 

  13. Lazzeri M., Vittadini A., Selloni A. (2001) Phys. Rev. B 63:155409

    Article  CAS  Google Scholar 

  14. Ghicov A., Macak J.M., Tsuchiya H., Kunze J., Haeublein V., Frey L., Schmuki P. (2006) Nano Lett. 6:1080

    Article  CAS  Google Scholar 

  15. S. Funk, B. Hokkanen, U. Burghaus, A. Ghicov and P. Schmuki, Nano Lett. xx (2007) xx.

  16. Z. Bing, S. Hermans and G.A. Somorjai, (eds.) Nanotechnology in Catalysis, Springer series: nanostructure science and technology (2004) ISBN 0-306-48323-8

  17. Paserba K.R., Gellman A.J. (2001) Phys. Rev. Lett. 86:4338

    Article  CAS  Google Scholar 

  18. Slayton R.M., Aubuchon C.M., Camis T.L., Noble A.R., Tro N.J. (1995) J. Phys. Chem. 99:2151

    Article  CAS  Google Scholar 

  19. Wang J., Hokkanen B., Burghaus U. (2005) Surf. Sci. 577:158

    Article  CAS  Google Scholar 

  20. Salmeron M., Somorjai G.A. (1981) J. Phys. Chem. 85:3835

    Article  CAS  Google Scholar 

  21. Brand J.L., Arena M.V., Deckert A.A., George S.M. (1990) J. Chem. Phys. 92:5136

    Article  CAS  Google Scholar 

  22. Lei R.Z., Gellman A.J., Koel B.E. (2004) Surf. Sci. 554:125

    Article  CAS  Google Scholar 

  23. Funk S., Hokkanen B., Wang J., Burghaus U., Bozzolo G.H., Garces J.E. (2006) Surf. Sci. 600:583

    Article  CAS  Google Scholar 

  24. Ding J., Burghaus U., Weinberg W.H. (2000) Surf. Sci. 446:46

    Article  CAS  Google Scholar 

  25. Fichthorn K.A., Miron R.A. (2002) Phys. Rev. Lett. 89:196103

    Article  CAS  Google Scholar 

  26. Wang J., Hokkanen B., Burghaus U. (2006) Surf. Sci. 600:4855

    Article  CAS  Google Scholar 

  27. Burghaus U. (2001) Surf. Rev. Lett. 8:353

    CAS  Google Scholar 

  28. Wang J., Burghaus U. (2005) J. Chem.Phys. 122:044705

    Article  CAS  Google Scholar 

  29. Xu C., Koel B.E., Paffett M.T. (1994) Langmuir 10:166

    Article  CAS  Google Scholar 

  30. Tait S.L., Dohnalek Z., Campbell C.T., Kay B.D. (2005) J. Chem. Phys. 122:164707

    Article  CAS  Google Scholar 

  31. Funk S., Nurkic T., Burghaus U. (2007) Appl. Surf. Sci. 253:4860

    Article  CAS  Google Scholar 

  32. Kondo T., Mori D., Okada R., Sasaki M., Yamamoto S. (2005) J. Chem. Phys. 123:114712

    Article  CAS  Google Scholar 

  33. Hu Z.P., Ogletree D.F., Van Hove M.A., Somorjai G.A. (1987) Surf. Sci. 180:433

    Article  CAS  Google Scholar 

  34. Darling G.R., Holloway S. (1995) Rep. Prog. Phys. 58:1595

    Article  CAS  Google Scholar 

  35. Vattuone L., Valbusa U., Rocca M. (1999) Phys. Rev. Lett. 82:4878

    Article  CAS  Google Scholar 

  36. Gerbi A., Savio L., Vattuone L., Pirani F., Cappelletti D., Rocca M. (2006) Angew. Chem. Int. Ed. 45:6655

    Article  CAS  Google Scholar 

  37. U. Burghaus, J. Stephan, J.M. Rogowska and L. Vattuone, A practical guide to Monte Carlo simulations and classical molecular dynamics simulations—An example book, NOVA science (2006) (New York, US), ISBN 1-59454-531-6

  38. Stephan J., Burghaus U. (2002) Surf. Sci. 507–510:736

    Article  Google Scholar 

Download references

Acknowledgments

Financial support by the DoE-EPSCoR (DE-FG02-06ER46292, state grant) and from ND NSF-EPSCoR IIP seed (EPS-047679) is acknowledged. Work was also performed in the Environmental Molecular Sciences Laboratory, a national scientific user facility sponsored by the Department of Energy (DoE).

Author information

Author notes

  1. Z. Q. Yu

    Present address: Department of Chemistry, Nanjing Normal University, Nanjing, China

Authors and Affiliations

  1. Department of Chemistry, North Dakota State University, Fargo, ND, USA

    J. Goering, E. Kadossov & U. Burghaus

  2. Pacific Northwest National Laboratory, Richland, WA, USA

    Z. Q. Yu, S. Thevuthasan & L. V. Saraf

Authors
  1. J. Goering
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. Kadossov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. U. Burghaus
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Z. Q. Yu
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. S. Thevuthasan
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. L. V. Saraf
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to U. Burghaus.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Goering, J., Kadossov, E., Burghaus, U. et al. Adsorption of iso-/n-butane on an anatase thin film: a molecular beam scattering and TDS study. Catal Lett 116, 9–14 (2007). https://doi.org/10.1007/s10562-007-9121-x

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10562-007-9121-x

Keywords

Search

Navigation