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Selective Allylic oxidation of Cyclohexene by a Magnetically Recoverable Cobalt Oxide Catalyst

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Abstract

In this work, we prepared a new magnetically recoverable CoO catalyst through the deposition of the catalytic active metal nanoparticles of 2–3 nm on silica-coated magnetite nanoparticles to facilitate the solid separation from liquid media. The catalyst was fully characterized and presented interesting properties in the oxidation of cyclohexene, as for example, selectivity to the allylic oxidation product. It was also observed that CoO is the most active species when compared to Co2+, Co3O4 and Fe3O4 in the catalytic conditions studied.

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References

  1. Yin C, Yang Z, Li B, Zhang F, Wang J, Ou E (2009) Catal Lett 131:440

    Article  CAS  Google Scholar 

  2. Murphy EF, Mallat T, Baiker A (2000) Catal Today 57:115

    Article  CAS  Google Scholar 

  3. Alvarez LX, Christ ML, Sorokin AB (2007) Appl Catal A 325:303

    Article  CAS  Google Scholar 

  4. Wang RM, Zhang ZL, Lou JF, Wang YP, Song PF, Xia CG (2004) Polym Adv Technol 15:48

    Article  CAS  Google Scholar 

  5. Baricelli PJ, Sanchez VJ, Pardey AJ, Moya SA (2000) J Mol Catal A Chem 164:77

    Article  CAS  Google Scholar 

  6. Yang ZW, Kang QX, Ma HC, Li CL, Lei ZQ (2004) J Mol Catal A Chem 213:169

    Article  CAS  Google Scholar 

  7. Chakrabarty R, Das BK, Clark JH (2007) Green Chem 9:845

    Article  CAS  Google Scholar 

  8. Chattopadhyay T, Das D (2009) J Coord Chem 62:845

    Article  CAS  Google Scholar 

  9. Mukherjee S, Samanta S, Bhaumik A, Ray BC (2006) Appl Catal B 68:12

    Article  CAS  Google Scholar 

  10. Sun B, Chen JR, Hu JY, Li XJ (2006) J Inorg Biochem 100:1308

    Article  CAS  Google Scholar 

  11. Farzaneh F, Sadeghi S, Turkian L, Ghandi M (1998) J Mol Catal A Chem 132:255

    Article  CAS  Google Scholar 

  12. Lau SH, Caps V, Yeung KW, Wong KY, Tsang SC (1999) Microporous Mesoporous Mater 32:279

    Article  CAS  Google Scholar 

  13. Maayan G, Fish RH, Neumann R (2003) Org Lett 5:3547

    Article  CAS  Google Scholar 

  14. Betzemeier B, Lhermitte F, Knochel P (1998) Tetrahedron Lett 39:6667

    Article  CAS  Google Scholar 

  15. Bordoloi A, Sahoo S, Lefebvre F, Halligudi SB (2008) J Catal 259:232

    Article  CAS  Google Scholar 

  16. Maksimchuk NV, Meigunov MS, Chesalov YA, Mrowlec-Bialon J, Jarzebski AB, Kholdeeva OA (2007) J Catal 246:241

    Article  CAS  Google Scholar 

  17. Serwicka EM, Poltowicza J, Bahranowski KT, Olejniczak Z, Jones W (2004) Appl Catal A 275:9

    Article  CAS  Google Scholar 

  18. Zhang Y, Li Z, Sun W, Xia CG (2008) Catal Commun 10:237

    Article  CAS  Google Scholar 

  19. Polshettiwar V, Varma RS (2009) Org Biomol Chem 7:37

    Article  CAS  Google Scholar 

  20. Jacinto MJ, Santos O, Jardim RF, Landers R, Rossi LM (2009) Appl Catal A 360:177

    Article  CAS  Google Scholar 

  21. Menini L, Pereira MC, Parreira LA, Fabris JD, Gusevskaya EV (2008) J Catal 254:355

    Article  CAS  Google Scholar 

  22. Ghosh M, Sampathkumaran EV, Rao CNR (2005) Chem Mater 17:2348

    Article  CAS  Google Scholar 

  23. Jacinto MJ, Kiyohara PK, Masunaga SH, Jardim RF, Rossi LM (2008) Appl Catal A 338:52

    Article  CAS  Google Scholar 

  24. Carson GA, Nassir MH, Langell MA (1996) J Vac Sci Technol A 14:1637

    Article  CAS  Google Scholar 

  25. Podraza KF (1991) Org Prep Proced Int 23:217

    Article  CAS  Google Scholar 

  26. Luque R, Badamali SK, Clark JH, Fleming M, Macquarrie DJ (2008) Appl Catal A 341:154

    Article  CAS  Google Scholar 

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Acknowledgments

The authors are grateful to the Brazilian agencies FAPESP and CNPq, and to the INCT-Catalise for financial support. The electron microscopy work has been performed with the JEM-3010 ARP microscope at LNLS—Brazilian Synchrotron Light Laboratory/MCT (Campinas, Brazil).

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Authors and Affiliations

  1. Institute of Chemistry, University of São Paulo, São Paulo, Brazil

    Fernanda P. Silva, Marcos J. Jacinto & Liane M. Rossi

  2. Institute of Physics, UNICAMP, Campinas, Brazil

    Richard Landers

Authors
  1. Fernanda P. Silva
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  2. Marcos J. Jacinto
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  3. Richard Landers
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  4. Liane M. Rossi
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Corresponding author

Correspondence to Liane M. Rossi.

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Silva, F.P., Jacinto, M.J., Landers, R. et al. Selective Allylic oxidation of Cyclohexene by a Magnetically Recoverable Cobalt Oxide Catalyst. Catal Lett 141, 432–437 (2011). https://doi.org/10.1007/s10562-010-0512-z

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  • DOI: https://doi.org/10.1007/s10562-010-0512-z

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