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Efficient Baeyer–Villiger Oxidation Catalysed by Silver Nanoparticles Stabilized on Modified Montmorillonite

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Abstract

Silver nanoparticles supported on modified montmorillonite clay (Ag-NPs@mont), were utilized as catalyst for the Baeyer–Villiger oxidation of various ketones with hydrogen peroxide as an oxidant under solvent free condition at room temperature. The modification of Montmorillonite K10 clay was carried out with HCl under controlled conditions for generating a high surface area porous matrix which acts as support for the in situ generation of Silver nanoparticles. The synthesized nanocomposite material was characterized by UV–Visible spectroscopy, powder XRD, SEM-EDX, TEM and N2 adsorption–desorption analysis. The catalyst can be recycled and reused several times without significant loss of their catalytic activity.

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Acknowledgements

The authors gratefully acknowledge SAIF, NEHU for the TEM analysis.

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Authors and Affiliations

  1. Department of Chemistry, Gauhati University, Guwahati, Assam, 781 014, India

    Subrat Jyoti Borah & Diganta Kumar Das

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  1. Subrat Jyoti Borah
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  2. Diganta Kumar Das
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Correspondence to Subrat Jyoti Borah.

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Borah, S.J., Das, D.K. Efficient Baeyer–Villiger Oxidation Catalysed by Silver Nanoparticles Stabilized on Modified Montmorillonite. Catal Lett 148, 3669–3677 (2018). https://doi.org/10.1007/s10562-018-2566-2

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  • DOI: https://doi.org/10.1007/s10562-018-2566-2

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