Skip to main content
Log in

Volumetric Properties of 3-Methylbutyl Ethanoate with Ethyl Acrylate, Butyl Acrylate, Methyl Methacrylate, and Styrene at 25°C

  • Published:
International Journal of Thermophysics Aims and scope Submit manuscript

Abstract

Densities of the binary systems of 3-methylbutyl ethanoate (isoamyl acetate) with ethyl acrylate, butyl acrylate, methyl methacrylate, and styrene have been measured as a function of composition at 25°C and atmospheric pressure using an Anton Paar DMA 5000 oscillating U-tube densimeter. The calculated excess volumes were correlated with the Redlich–Kister equation and with a series of Legendre polynomials. The excess volumes are positive for the binary systems of 3-methylbutyl ethanoate with each of the three acrylate monomers and negative for the system with styrene. The 3-methylbutyl ethanoate + butyl acrylate system exhibits near-ideal behavior.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. R.D. Peralta R. Infante G. Cortez L. Villarreal J. Wisniak (2002) Thermochim. Acta 390 47

    Google Scholar 

  2. R.D. Peralta R. Infante G. Cortez J.R. Torres-Lubián J. Wisniak (2003) Thermochim. Acta 402 247

    Google Scholar 

  3. R.D. Peralta R. Infante G. Cortez A. Cisneros J. Wisniak (2002) Thermochim. Acta 398 39 Occurrence Handle10.1016/S0040-6031(02)00393-3

    Article  Google Scholar 

  4. R.D. Peralta R. Infante G. Cortez O. Rodríguez J. Wisniak (2002) J. Solution Chem. 31 175 Occurrence Handle10.1023/A:1015895807777

    Article  Google Scholar 

  5. R.D. Peralta R. Infante G. Cortez R.G. López J. Wisniak (2003) Int. J. Thermophys. 24 173 Occurrence Handle10.1023/A:1022314332705

    Article  Google Scholar 

  6. R.D. Peralta R. Infante G. Cortez R.R Ramírez J. Wisniak (2003) J. Chem. Thermodynamics 35 239 Occurrence Handle10.1016/S0021-9614(02)00313-0

    Article  Google Scholar 

  7. R.D. Peralta R. Infante G. Cortez L.F. Ramos J. Wisniak (2003) Phys. Chem. Liq. 41 361 Occurrence Handle10.1080/0031910031000122052

    Article  Google Scholar 

  8. H.C. Van Ness M.M. Abbott (1982) Classical Thermodynamics of Nonelectrolyte Solutions McGraw-Hill New York

    Google Scholar 

  9. O. Redlich A.T. Kister (1948) Ind. Eng. Chem. 40 345 Occurrence Handle10.1021/ie50458a036

    Article  Google Scholar 

  10. J. Tomiska (1981) CALPHAD 5 93 Occurrence Handle10.1016/0364-5916(81)90034-1

    Article  Google Scholar 

  11. J. Tomiska (1984) CALPHAD 8 283 Occurrence Handle10.1016/0364-5916(84)90032-4

    Article  Google Scholar 

  12. J. Wisniak A. Polishuk (1999) Fluid Phase Equilib. 164 61 Occurrence Handle10.1016/S0378-3812(99)00246-0

    Article  Google Scholar 

  13. S.A. Karpushina M.T. Khimenko Yu. N. Surov (1990) Zh. Fiz. Khim. 64 368

    Google Scholar 

  14. N.V. Sastry M.K. Valand (2000) Phys. Chem. Liq. 3 61

    Google Scholar 

  15. L. Beichen S.E.M Hamam B.C.-Y Lu (1986) J. Chem. Thermodyn. 18 1043 Occurrence Handle10.1016/0021-9614(86)90018-2

    Article  Google Scholar 

  16. TRC Thermodynamic Tables, extant 2002. Hydrocarbons, Thermodynamics Research Center, The Texas A&M University System, College Station, Texas; table a-4490, styrene (1989).

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to R. D. Peralta.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Peralta, R.D., Infante, R., Cortez, G. et al. Volumetric Properties of 3-Methylbutyl Ethanoate with Ethyl Acrylate, Butyl Acrylate, Methyl Methacrylate, and Styrene at 25°C. Int J Thermophys 26, 679–692 (2005). https://doi.org/10.1007/s10765-005-5571-9

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10765-005-5571-9

Keywords

Navigation