Abstract
Densities of the binary systems of 3-methylbutyl ethanoate (isoamyl acetate) with ethyl acrylate, butyl acrylate, methyl methacrylate, and styrene have been measured as a function of composition at 25°C and atmospheric pressure using an Anton Paar DMA 5000 oscillating U-tube densimeter. The calculated excess volumes were correlated with the Redlich–Kister equation and with a series of Legendre polynomials. The excess volumes are positive for the binary systems of 3-methylbutyl ethanoate with each of the three acrylate monomers and negative for the system with styrene. The 3-methylbutyl ethanoate + butyl acrylate system exhibits near-ideal behavior.
Similar content being viewed by others
References
R.D. Peralta R. Infante G. Cortez L. Villarreal J. Wisniak (2002) Thermochim. Acta 390 47
R.D. Peralta R. Infante G. Cortez J.R. Torres-Lubián J. Wisniak (2003) Thermochim. Acta 402 247
R.D. Peralta R. Infante G. Cortez A. Cisneros J. Wisniak (2002) Thermochim. Acta 398 39 Occurrence Handle10.1016/S0040-6031(02)00393-3
R.D. Peralta R. Infante G. Cortez O. Rodríguez J. Wisniak (2002) J. Solution Chem. 31 175 Occurrence Handle10.1023/A:1015895807777
R.D. Peralta R. Infante G. Cortez R.G. López J. Wisniak (2003) Int. J. Thermophys. 24 173 Occurrence Handle10.1023/A:1022314332705
R.D. Peralta R. Infante G. Cortez R.R Ramírez J. Wisniak (2003) J. Chem. Thermodynamics 35 239 Occurrence Handle10.1016/S0021-9614(02)00313-0
R.D. Peralta R. Infante G. Cortez L.F. Ramos J. Wisniak (2003) Phys. Chem. Liq. 41 361 Occurrence Handle10.1080/0031910031000122052
H.C. Van Ness M.M. Abbott (1982) Classical Thermodynamics of Nonelectrolyte Solutions McGraw-Hill New York
O. Redlich A.T. Kister (1948) Ind. Eng. Chem. 40 345 Occurrence Handle10.1021/ie50458a036
J. Tomiska (1981) CALPHAD 5 93 Occurrence Handle10.1016/0364-5916(81)90034-1
J. Tomiska (1984) CALPHAD 8 283 Occurrence Handle10.1016/0364-5916(84)90032-4
J. Wisniak A. Polishuk (1999) Fluid Phase Equilib. 164 61 Occurrence Handle10.1016/S0378-3812(99)00246-0
S.A. Karpushina M.T. Khimenko Yu. N. Surov (1990) Zh. Fiz. Khim. 64 368
N.V. Sastry M.K. Valand (2000) Phys. Chem. Liq. 3 61
L. Beichen S.E.M Hamam B.C.-Y Lu (1986) J. Chem. Thermodyn. 18 1043 Occurrence Handle10.1016/0021-9614(86)90018-2
TRC Thermodynamic Tables, extant 2002. Hydrocarbons, Thermodynamics Research Center, The Texas A&M University System, College Station, Texas; table a-4490, styrene (1989).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Peralta, R.D., Infante, R., Cortez, G. et al. Volumetric Properties of 3-Methylbutyl Ethanoate with Ethyl Acrylate, Butyl Acrylate, Methyl Methacrylate, and Styrene at 25°C. Int J Thermophys 26, 679–692 (2005). https://doi.org/10.1007/s10765-005-5571-9
Received:
Issue Date:
DOI: https://doi.org/10.1007/s10765-005-5571-9