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Thermodynamic Properties of Methanol in the Critical and Supercritical Regions

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Abstract

The isochoric heat capacity of pure methanol in the temperature range from 482 to 533 K, at near-critical densities between 274.87 and 331.59 kg· m−3, has been measured by using a high-temperature and high-pressure nearly constant volume adiabatic calorimeter. The measurements were performed in the single- and two-phase regions including along the coexistence curve. Uncertainties of the isochoric heat capacity measurements are estimated to be within 2%. The single- and two-phase isochoric heat capacities, temperatures, and densities at saturation were extracted from experimental data for each measured isochore. The critical temperature (T c = 512.78±0.02K) and the critical density (ρc = 277.49±2 kg · m−3) for pure methanol were derived from the isochoric heat-capacity measurements by using the well-established method of quasi-static thermograms. The results of the C V VT measurements together with recent new experimental PVT data for pure methanol were used to develop a thermodynamically self-consistent Helmholtz free-energy parametric crossover model, CREOS97-04. The accuracy of the crossover model was confirmed by a comprehensive comparison with available experimental data for pure methanol and values calculated with various multiparameter equations of state and correlations. In the critical and supercritical regions at 0.98Tc≤ T ≤ 1.5Tc and in the density range 0.35ρc ≤ ρ leq 1.65 ρc, CREOS97-04 represents all available experimental thermodynamic data for pure methanol to within their experimental uncertainties.

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  1. Institute for Geothermal Problems of the Dagestan Scientific Center of the Russian Academy of Sciences, Shamilya Street 39-A, 367003, Makhachkala, Dagestan, Russia

    I. M. Abdulagatov & A. Abdurashidova

  2. Institute of Physics of the Dagestan Scientific Center of the Russian Academy of Sciences, YaragskogoStreet 94, 367005, Makhachkala, Dagestan, Russia

    I. M. Abdulagatov & N. G. Polikhronidi

  3. Chemical Engineering Department, Colorado School of Mines, Golden, Colorado, 80401-1887, U.S.A

    S. B. Kiselev & J. F. Ely

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  1. I. M. Abdulagatov
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Abdulagatov, I.M., Polikhronidi, N.G., Abdurashidova, A. et al. Thermodynamic Properties of Methanol in the Critical and Supercritical Regions. Int J Thermophys 26, 1327–1368 (2005). https://doi.org/10.1007/s10765-005-8091-8

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