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Volumetric Properties of the Ionic Liquid, 1-Butyl-3-methylimidazolium Tetrafluoroborate, in Organic Solvents at T =  298.15K

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Abstract

Apparent molar volumes, \(V_\phi\) , and compressibilities, \(\kappa _\phi\) , of 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIm][BF4]) have been determined from precise density and speed-of-sound measurements in organic solvents, methanol (MeOH), acetonitrile (MeCN), tetrahydrofuran (THF), N,N-dimethylacetamide (DMA), and dimethylsulfoxide (DMSO) in the dilute region of the ionic liquid. Corresponding values at infinite dilution are estimated by the Redlich–Mayer and Pitzer equations. The results have been interpreted by the interaction of the [BMIm][BF4] in the organic solvents. Results show that the structure and dielectric constant of the organic solvents play an important role for the ion–solvent interactions in these mixtures. It was found that the strength of interaction between [BMIm][BF4] with the studied organic solvents has the order DMSO > DMA > MeOH > MeCN > THF.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, University of Mohaghegh Ardabili, P.O. Box 179, Ardabil, Iran

    Hemayat Shekaari

  2. Department of Physical Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz, Iran

    Mohammed Taghi Zafarani-Moattar

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  1. Hemayat Shekaari
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  2. Mohammed Taghi Zafarani-Moattar
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Correspondence to Hemayat Shekaari.

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Shekaari, H., Zafarani-Moattar, M.T. Volumetric Properties of the Ionic Liquid, 1-Butyl-3-methylimidazolium Tetrafluoroborate, in Organic Solvents at T =  298.15K. Int J Thermophys 29, 534–545 (2008). https://doi.org/10.1007/s10765-008-0395-z

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  • DOI: https://doi.org/10.1007/s10765-008-0395-z

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